3-Buten-1-ol

ChemicalBook > CAS DataBase List > 3-Buten-1-ol

Description

Product Name: 3-Buten-1-ol
CAS No.: 627-27-0
Chemical Name: 3-Buten-1-ol
Synonyms: 3-Butenol;3-BUTENE-1-OL;3-Butenyl alcohol;Homoallyl alcohol;NSC 60194;3-Buten-1-O1;3-buten-1-0l;1-Buten-4-ol;3-BUTEN-1-OL;3-butene-1-0l
CBNumber: CB1172076
Molecular Formula: C4H8O
Formula Weight: 72.11
MOL File: 627-27-0.mol

Less

3-Buten-1-ol Property

Melting point:: -31.44°C (estimate)
Boiling point:: 112-114 °C (lit.)
Density: 0.838 g/mL at 25 °C (lit.)
refractive index: n20/D 1.421(lit.)
Flash point:: 90 °F
storage temp.: Sealed in dry,Store in freezer, under -20°C
solubility: soluble in Chloroform, Methanol
pka: 15.04±0.10(Predicted)
form: Liquid
color: Clear colorless to slightly yellow
Specific Gravity: 0.843
explosive limit: 2-28%(V)
Water Solubility: SOLUBLE
BRN: 1633504
Stability:: Stable. Incompatible with acids, acid chlorides, acid anhydrides, oxidizing agents. Flammable.
InChIKey: ZSPTYLOMNJNZNG-UHFFFAOYSA-N
LogP: 0.679 (est)
CAS DataBase Reference: 627-27-0(CAS DataBase Reference)
NIST Chemistry Reference: 3-Buten-1-ol(627-27-0)
EPA Substance Registry System: 3-Buten-1-ol (627-27-0)

Less

Safety

Hazard Codes: Xi
Risk Statements: 10-36/37/38
Safety Statements: 16-26-36
RIDADR: UN 1987 3/PG 3
WGK Germany: 3
TSCA: Yes
HazardClass: 3
PackingGroup: II
HS Code: 29052990

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 19170
Product name: 3-Buten-1-ol
Purity: purum, ≥98.0% (GC)
Packaging: 25ml
Price: $154
Updated: 2024/03/01

Sigma-Aldrich

Product number: 19170
Product name: 3-Buten-1-ol
Purity: purum, ≥98.0% (GC)
Packaging: 5ml
Price: $62.1
Updated: 2023/06/20

TCI Chemical

Product number: B0236
Product name: 3-Buten-1-ol
Purity: >98.0%(GC)
Packaging: 10mL
Price: $48
Updated: 2024/03/01

TCI Chemical

Product number: B0236
Product name: 3-Buten-1-ol
Purity: >98.0%(GC)
Packaging: 25mL
Price: $82
Updated: 2024/03/01

Alfa Aesar

Product number: L00767
Product name: 3-Buten-1-ol, 98+%
Packaging: 5g
Price: $33.65
Updated: 2024/03/01

Less

3-Buten-1-ol Chemical Properties,Usage,Production

Description

3-Buten-1-ol(627-27-0) is a homoallyl alcohol. It is employed in a study of the Mn-catalyzed hydrohydrazination of olefins. It is also used in a study of the conversion of propargylic acetates to ethers catalyzed by ferric chloride¹. It can also be used as a starting reagent in asymmetric total synthesis of natural seimatopolide B. It was also used in the synthesis of catalytic bimetallic nanoparticles².

Chemical Properties

liquid

Uses

3-Buten-1-ol is an aliphatic primary alcohol used as a reagent in organic synthesis.

Uses

3-Buten-1-ol is employed in a study of the Mn-catalyzed hydrohydrazination of olefins. Also used in a study of the conversion of propargylic acetates to ethers catalyzed by ferric chloride.

Uses

Employed in a study of the Mn-catalyzed hydrohydrazination of olefins. Also used in a study of the conversion of propargylic acetates to ethers cataylzed by ferric chloride.

Definition

ChEBI: 3-Buten-1-ol is a primary alcohol.

General Description

3-Buten-1-ol is a homoallyl alcohol that can be prepared by the dehydration of 1,4-butanediol using cerium catalyst. The intramolecular hydrogen bonding of 3-buten-1-ol has been studied using FT-IR and ¹H NMR spectroscopic data. Its microwave spectrum has been recorded and analyzed. The alkylation reaction of 3-buten-1-ol using titanium-organoaluminum system has been studied. Its gas-phase enthalpy of formation has been reported to be -147.3 ± 1.8kJ mol^-1.

Hazard

3-Buten-1-ol is strongly irritating to the skin and eyes. it may cause respiratory irritation. it is toxic to aquatic organisms and has long lasting effects.

Synthesis

The synthesis of 3-Buten-1-ol is as follows:After adding 24.3 g (1 mol) of magnesium turnings, 50 g of diethyl ether and 1 ml of dibromoethane in a 500 mL four-necked flask,A solution of 62.5 g of vinyl chloride (1 mol) dissolved in 200 g of diethyl ether was added dropwise to magnesium and diethyl ether, and the micro reflux was controlled, and the dropwise addition was completed, and the mixture was kept under a micro reflux for 2 hours, and the temperature was lowered to -5 °C;Then 44 g (1 mol) of ethylene oxide was dissolved in 60 g of diethyl ether. Ethylene oxide is added dropwise to the vinylmagnesium chloride solution prepared above, control the temperature -5-5 degrees, and stir at this temperature for 1 hour. Sampling gas phase analysis until the reaction is complete; pour the reaction solution into a 1000 mL beaker, Add 200mL of ice water and add ammonium chloride until the residual magnesium disappears. Control the temperature 0-10 ° C, stir for 1 hour after the addition, add salt to saturation, static layering. The organic layer was separated and washed twice with 100 ml of saturated brine, and a polymerization inhibitor was added. The product is subjected to rectification to obtain 53 g of 3-buten-1-ol, and the content is 99.2%. The yield was 73.6%.

3-Buten-1-ol Preparation Products And Raw materials

Raw materials

Preparation Products

Less

3-Buten-1-ol Suppliers

Americas 1 Belgium 1 Canada 3 China 347 Europe 4 Germany 7 India 9 Japan 8 Singapore 1 Slovakia 1 Switzerland 4 United Kingdom 10 United States 42 USA 1 Global 439

NINGBO SYNTAME BIOTECH CO LTD

Tel: 18668283131 座机0574-28802872
Email: sales@syntame.com
Country: China
ProdList: 100
Advantage: 58

Shanghai Jinsai Pharmaceutical and Chemical Co., Ltd.

Tel: 21-57362983 13301713911
Fax: 021-57362993
Email: parkbe@hotmail.com
Country: China
ProdList: 12
Advantage: 58

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40240
Advantage: 62

Suzhou Sino Rare Chemical Co., Ltd.

Tel: 0512-62857507
Fax: +86-512-62857507
Email: sales@sinorarechem.com
Country: China
ProdList: 981
Advantage: 58

Shanghai Jinsai Biotechnology Co., LTD

Tel: 13681638167 13681638167
Email: zouxiao8466@163.com
Country: China
ProdList: 23
Advantage: 58

ChengDu TongChuangYuan Pharmaceutical Co.Ltd

Tel: 28-83379370 13880556291
Fax: 028-87747383
Email: tcy@tcypharm.com
Country: China
ProdList: 511
Advantage: 57

Shanghai Fred Chemical Co. Ltd.

Tel: 021-54450827 021-54450828
Email: sales@fwdchem.com
Country: China
ProdList: 995
Advantage: 58

Zhejiang Asun Chemical Industry Co., Ltd.

Tel: 0571-26267133
Email: olina@asunchem.com
Country: China
ProdList: 26
Advantage: 58

China Langchem Inc.

Tel: 021-58956006 15800617331
Fax: 021-58956100
Email: sales@langchem.com
Country: China
ProdList: 211
Advantage: 57

Huai'an Xinsheng New Materials Technology Co., Ltd

Tel: 13952383698
Email: czg_123@126.com
Country: China
ProdList: 24
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 94838
Advantage: 76

3B Pharmachem (Wuhan) International Co.,Ltd.

Tel: 821-50328103-801 18930552037
Fax: 86-21-50328109
Email: 3bsc@sina.com
Country: China
ProdList: 15848
Advantage: 69

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30132
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24539
Advantage: 81

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44751
Advantage: 61

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Email: sales@capotchem.com
Country: China
ProdList: 18217
Advantage: 66

Beijing Ouhe Technology Co., Ltd

Tel: 010-82967028 13552068683
Fax: +86-10-82967029
Email: 2355560935@qq.com
Country: China
ProdList: 12458
Advantage: 60

JinYan Chemicals(ShangHai) Co.,Ltd.

Tel: 13817811078
Fax: 86-021-50426522,50426273
Email: sales@jingyan-chemical.com
Country: China
ProdList: 9984
Advantage: 60

Jia Xing Isenchem Co.,Ltd

Tel: 0573-85285100 18627885956
Fax: 0573-85285100
Email: isenchem@163.com
Country: China
ProdList: 9551
Advantage: 66

Accela ChemBio Co.,Ltd.

Tel: 021-50795510 4000665055
Fax: 021-50795055
Email: sales@accelachem.com
Country: China
ProdList: 11660
Advantage: 64

Shanghai Longsheng chemical Co.,Ltd.

Tel: 021-58099652-8005 13585536065
Fax: 021-58099609
Email: bin.wu@shlschem.com
Country: China
ProdList: 9816
Advantage: 59

Nanjing Chemlin Chemical Co., Ltd

Tel: 025-83697070
Fax: +86-25-83453306
Email: info@chemlin.com.cn
Country: China
ProdList: 17989
Advantage: 64

Shanghai Hanhong Scientific Co.,Ltd.

Tel
Country: China
ProdList: 42982
Advantage: 64

Chemsky（shanghai）International Co.,Ltd.

Tel: 021-50135380
Email: shchemsky@sina.com
Country: China
ProdList: 32344
Advantage: 50

XiaoGan ShenYuan ChemPharm co,ltd

Tel: 15527768850
Email: 1791901229@qq.com
Country: China
ProdList: 8849
Advantage: 52

Zhejiang Qiming Pharmaceutical Co., Ltd.

Tel: +86-571-87163895 +86-571-87163893
Fax: +86-571-87163816
Email: sales@qimingpharm.com
Country: China
ProdList: 87
Advantage: 65

RYSS TECH LTD

Tel: 400-188-0725 +86 21 34310725 13611771617
Fax: +86 21 34311076
Country: China
ProdList: 2002
Advantage: 57

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400 638 7771
Email: sales@heowns.com
Country: China
ProdList: 14443
Advantage: 57

Wuhan Kemi-Works Chemical Co., Ltd

Tel: 027-85736489
Fax: 86-27-85736485
Email: info@kemiworks.net
Country: China
ProdList: 542
Advantage: 57

Nanjing King-pharm Co.,LTD.

Tel: 025-58748998 19951791336
Email: elsa@chemsigma.com
Country: China
ProdList: 117
Advantage: 65

Shanghai Sunway Pharmaceutical Technology Co., Ltd

Tel: +8613162137806 18575662672
Fax: 021 51613951
Email: mzeng@3wpharm.com
Country: China
ProdList: 9746
Advantage: 57

Aemon Chemical

Tel: 0086-755-86198205
Email: acinfo@aemonchem.com
Country: China
ProdList: 1937
Advantage: 57

Maya High Purity Chemicals

Tel: +86 (573) 82222445 (0)18006601000 452520369
Fax: +86 (573) 82222643
Email: sales@maya-r.com
Country: China
ProdList: 11714
Advantage: 57

Shanghai Youd Chemical Technology Co., Ltd.

Tel: 15821801668
Fax: 021-37910267
Email: cong44@126.com
Country: China
ProdList: 292
Advantage: 58

Shanghai civi chemical technology co.,Ltd

Tel: 86-21-34053660
Fax: 86-21-34053661
Email: sale@labgogo.com
Country: China
ProdList: 9872
Advantage: 52

Suzhou Sibian Chemical Technology Co.,Ltd.

Tel: 0512-65617459 18915409046
Fax: 0512-65617459
Email: sales@sibian-chem.com
Country: China
ProdList: 1927
Advantage: 55

Thermo Fisher Scientific

Tel: 800-810-5118
Fax: +86-10-84193589
Email: cnchemical@thermofisher.com
Country: China
ProdList: 17779
Advantage: 75

Beijing innoChem Science & Technology Co.,Ltd.

Tel: 400-810-7969 010-59572699
Fax: 010-59572688
Email: ningzi.li@inno-chem.com.cn
Country: China
ProdList: 6139
Advantage: 55

Shanghai Topbiochem Technology Co., Ltd

Tel: 021-58170097
Email: info@topbiochem.com
Country: China
ProdList: 9452
Advantage: 58

Shanghai T&W Pharmaceutical Co., Ltd.

Tel: +86 21 61551611
Fax: +86 21 50676805
Country: China
ProdList: 9901
Advantage: 58

Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.

Tel: 025-66099280 17798518460
Fax: (1)02557626880
Email: cfzhang@aikonchem.com
Country: China
ProdList: 19918
Advantage: 55

Shanghai Jian Chao Chemical Technology Co., Ltd.

Tel: 18017383231 18017383231
Fax: qq：2817624287
Email: lyh_antaeus@163.com
Country: China
ProdList: 9352
Advantage: 55

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 18216
Advantage: 56

Shanghai Aladdin Bio-Chem Technology Co.,LTD

Tel: 18521735133 18521732826;
Fax: 021-50323701
Email: market@aladdin-e.com
Country: China
ProdList: 25015
Advantage: 65

Shanghai Yolne Chemical Co., Ltd.

Tel: 021-62960152
Fax: 021-52212593
Email: 934678158@qq.com
Country: China
ProdList: 9906
Advantage: 55

Anichem Inc.

Tel: 0512-69369885
Fax: 0512-69369880
Email: sales@anichem.com.cn
Country: China
ProdList: 497
Advantage: 55

Chengdu AstaTech Trading Co., Ltd./AstaTech (Chengdu) Pharma. Co., Ltd.

Tel: +86-28-85122536 85324413
Fax: +86-28-85326443
Email: market@astatech.cn
Country: China
ProdList: 8033
Advantage: 55

Quzhou Juhua Friendship Co., Ltd

Tel: 0570-3066667
Fax: 0570-3063388
Country: China
ProdList: 3933
Advantage: 58

Beijing Universal Century Technology Co., Ltd.

Tel: 400-8706899
Fax: 400-8706899
Email: hysj_bj.com
Country: China
ProdList: 3585
Advantage: 55

Hubei XinyuanShun Chemical Co., Ltd.

Tel: 13971561712, 13995564702, 027-50664929
Fax: 027-50664927
Email: hbeixys2001@163.com
Country: China
ProdList: 3123
Advantage: 55

Less

View Lastest Price from 3-Buten-1-ol manufacturers

Zibo Wei Bin Import & Export Trade Co. Ltd.

Product: 3-Buten-1-ol 627-27-0
Price: US $280.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 10t
Release date: 2023-07-21

Henan Fengda Chemical Co., Ltd

Product: 3-Buten-1-ol 627-27-0
Price: US $100.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-24

Hebei Duling International Trade Co. LTD

Product: 3-Buten-1-ol 627-27-0
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 5000 Ton
Release date: 2023-01-11

627-27-0, 3-Buten-1-olRelated Search:

CIS-BUTENEDIOIC ANHYDRIDE Allyl glycidyl ether 3-SULFOLENE Allyl chloride Methanol Fumaric acid Allyl bromide Polybutene 1-BUTENE Maleic acid 3-(2-AMINOETHYL)ANILINE 2HCL 2,4-Diamino-6-hydroxypyrimidine 4-[2’-(7’’-Deazaguanine)ethyl]benzoic Acid N-Hydroxysuccinimide Ester Methyl 4-(4-oxobutyl)benzoate N-[4-[3-(2,6-DiaMino-1,4-dihydro-4-oxo-5-pyriMidinyl)-3-oxopropyl]benzoyl]-L-glutaMic Acid 4-[2-(2-Amino-4,7-dihydro-4-oxo-1H-pymol[2,3-d]pyrimodin-5-yl)ethyl]benzoic acid PeMetrexed IMpurity D PeMetrexed EP IMpurity C

1-Buten-4-ol

3-buten-1-0l

3-Buten-1-O1

3-butene-1-0l

3-Butenol

3-Butenyl alcohol

BUTEN-(3)-O1-(L)

CH2=CHCH2CH2OH

Vinylethyl alcohol

3-BUTEN-1-OL (1-4)

3-BUTEN-1-OL 96+%

3-BUTEN-1-OL 98+%

3-BUTEN-1-OL 99+%

3-BUTENE-1-OL

3-BUTEN-1-OL

4-HYDROXY-1-BUTENE

ALLYLCARBINOL

3-Buten-1-ol, 96% 100ML

3-Buten-1-ol, 96% 25ML

b-Vinylethanol

2-Vinylethanol

Homoallyl alcohol

1-HYDROXY-3-BUTENE

NSC 60194

β-Vinylethanol

3-Buten-1-ol 50g

3-Buten-1-ol puruM, >=98.0% (GC)

3-Buten-1-ol, 98.0%(GC)

3-MOMC EG-2201 2-mme CAS NO.627-27-0

Pemetrexed Impurity 17

3-Buten-1-ol 96%

3-Butene-1-ol Allyl carbinol

homoalylic alcohol

3-BUTEN-1-OL, 98%3-BUTEN-1-OL, 98%3-BUTEN-1-OL, 98%

3-Buten-1-ol &gt

3-Buten-1-ol ISO 9001：2015 REACH

3-Buten-1-ol (7CI, 8CI, 9CI, ACI)

627-27-0

15231-91-7

622-27-0

H2CCHCH2CH2OH

Organic Building Blocks

蠅-Unsaturated Alkanols

蠅-Functional Alkanols, Carboxylic Acids, Amines & Halides

Building Blocks

Acyclic

Alkenes

Pharmaceutical intermediates

Acyclic

Alkenes

Building Blocks

Chemical Synthesis

Organic Building Blocks

omega-Unsaturated Alkanols

omega-Functional Alkanols, Carboxylic Acids, Amines & Halides

pharmaceutical industry

Alcohol& Phenol& Ethers

API intermediates