2-Allylcyclohexanone

ChemicalBook > CAS DataBase List > 2-Allylcyclohexanone

2-Allylcyclohexanone

Product Name: 2-Allylcyclohexanone
CAS No.: 94-66-6
Chemical Name: 2-Allylcyclohexanone
Synonyms: TIMTEC-BB SBB006544;O-ALLYLCYCLOHEXANONE;2-ALLYLCYCLOHEXANONE;2-allylcyclohexan-1-one;Cyclohexanone, 2-allyl-;2-Allylcyclohexanone 97%;2-Allylcyclohexanone >2-Allylcyclohexanone, 97 %;2-(2-PROPENYL)CYCLOHEXANONE;2-(2-propenyl)-cyclohexanon
CBNumber: CB1182983
Molecular Formula: C9H14O
Formula Weight: 138.21
MOL File: 94-66-6.mol

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2-Allylcyclohexanone Property

Boiling point:: 94 °C/23 mmHg (lit.)
Density: 0.927 g/mL at 25 °C (lit.)
refractive index: n20/D 1.469(lit.)
Flash point:: >230 °F
form: clear liquid
color: Colorless to Light yellow to Light orange
Specific Gravity: 0.927
Water Solubility: Insoluble
CAS DataBase Reference: 94-66-6(CAS DataBase Reference)
NIST Chemistry Reference: Cyclohexanone, 2-(2-propenyl)-(94-66-6)
EPA Substance Registry System: Cyclohexanone, 2-(2-propenyl)- (94-66-6)

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 20/21/22-36/37/38
Safety Statements: 22-26-36/37/39-45-37/39
RIDADR: UN 3077
WGK Germany: 3
HS Code: 29142990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 405752
Product name: 2-Allylcyclohexanone
Purity: 97%
Packaging: 5g
Price: $257
Updated: 2024/03/01

Sigma-Aldrich

Product number: 405752
Product name: 2-Allylcyclohexanone
Purity: 97%
Packaging: 1g
Price: $61.8
Updated: 2023/06/20

TCI Chemical

Product number: A2230
Product name: 2-Allylcyclohexanone
Purity: >97.0%(GC)
Packaging: 5g
Price: $127
Updated: 2024/03/01

TCI Chemical

Product number: A2230
Product name: 2-Allylcyclohexanone
Purity: >97.0%(GC)
Packaging: 25g
Price: $421
Updated: 2024/03/01

TRC

Product number: A544445
Product name: 2-Allylcyclohexanone
Packaging: 50mg
Price: $45
Updated: 2021/12/16

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2-Allylcyclohexanone Chemical Properties,Usage,Production

Chemical Properties

clear light yellow liquid

Uses

2-Allylcyclohexanone may be used in the synthesis of the following:

bicyclo[3.3.1]non-2-en-9-one
R-(-)-epilachnene, an antipode of the defensive droplets from the Mexican bean beetle, Epilachna varivestis

Synthesis Reference(s)

Chemistry Letters, 13, p. 1721, 1984
Journal of the American Chemical Society, 85, p. 207, 1963 DOI: 10.1021/ja00885a021
The Journal of Organic Chemistry, 51, p. 421, 1986 DOI: 10.1021/jo00354a001

General Description

2-Allylcyclohexanone is a β,γ-unsaturated ketone. Selective oxidation of 2-allylcyclohexanone by benzonitrile-hydrogen peroxide has been reported. Asymmetric synthesis of 2-alkylcyclohexanones by alkylation of cyclohexanone enamines (III) of L-proline ester derivatives has been described. Oxidation of 2-allylcyclohexanone by 90% hydrogen peroxide catalyzed by arsonated polystyrene has been studied.

2-Allylcyclohexanone Preparation Products And Raw materials

Raw materials

Benzotrifluoride Potassium hydroxide

Preparation Products

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2-Allylcyclohexanone Suppliers

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View Lastest Price from 2-Allylcyclohexanone manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: 2-Allylcyclohexanone 94-66-6
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

Nanjing jinheyou Trading Co., Ltd.

Product: 2-Allylcyclohexanone 94-66-6
Price: US $0.00/g
Min. Order: 1g
Purity: 99.5%min
Supply Ability: 20kg/week
Release date: 2019-10-29

Nanjing jinheyou Trading Co., Ltd.

Product: 2-Allylcyclohexanone 94-66-6
Price: US $0.00/g
Min. Order: 1g
Purity: 99.5%min
Supply Ability: 20kg/week
Release date: 2019-10-31

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94-66-6

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KETONE

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