FMOC-HYDRAZIDE HCL

Product Name: FMOC-HYDRAZIDE HCL
CAS No.: 35661-51-9
Chemical Name: FMOC-HYDRAZIDE HCL
Synonyms: FMOC-NHNH2;(9H-fluoren-9-yl)Methyl hydrazinecarboxylate;9-Fluorenylmethyl carbazate;N-(9-Fluorenylmethoxycarbonyl) hydrazine (FMOC hydrazine);FMOC-NHNH2 HCL;FMOC-HYDRAZIDE HCL;9-FluorenylmethylCarbazate>9-Fluorenylmethyl carbazate, >=99%;Carbazic Acid 9-Fluorenylmethyl Ester;9H-fluoren-9-ylmethyl N-aminocarbamate
CBNumber: CB1210174
Molecular Formula: C15H14N2O2
Formula Weight: 254.28
MOL File: 35661-51-9.mol

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FMOC-HYDRAZIDE HCL Property

Melting point:: ~170 °C (dec.)
Boiling point:: 485.8±14.0 °C(Predicted)
Density: 1.259±0.06 g/cm3(Predicted)
storage temp.: Inert atmosphere,2-8°C
form: powder to crystal
pka: 10.21±0.20(Predicted)
color: White to Almost white
BRN: 2470262
InChI: InChI=1S/C15H14N2O2/c16-17-15(18)19-9-14-12-7-3-1-5-10(12)11-6-2-4-8-13(11)14/h1-8,14H,9,16H2,(H,17,18)
InChIKey: YGCGPEUVGHDMLO-UHFFFAOYSA-N
SMILES: N(C(OCC1C2=C(C=CC=C2)C2=C1C=CC=C2)=O)N
CAS DataBase Reference: 35661-51-9

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38-38-37-36
Safety Statements: 26-36
WGK Germany: 3
F: 3-10
HS Code: 29280000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 46917
Product name: 9-Fluorenylmethyl carbazate
Purity: for HPLC derivatization, LiChropur?, ≥99.0%
Packaging: 250MG
Price: $101
Updated: 2022/05/15

TCI Chemical

Product number: F0872
Product name: 9-Fluorenylmethyl Carbazate
Purity: >98.0%(HPLC)(T)
Packaging: 5g
Price: $55
Updated: 2025/07/31

TCI Chemical

Product number: F0872
Product name: 9-Fluorenylmethyl Carbazate
Purity: >98.0%(HPLC)(T)
Packaging: 25g
Price: $144
Updated: 2025/07/31

TRC

Product number: F632050
Product name: 9-Fluorenylmethyl Carbazate
Packaging: 500mg
Price: $95
Updated: 2021/12/16

AK Scientific

Product number: J90939
Product name: 9-Fluorenylmethyl Carbazate
Packaging: 5g
Price: $30
Updated: 2021/12/16

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FMOC-HYDRAZIDE HCL Chemical Properties,Usage,Production

Chemical Properties

white powder

Uses

9-Fluorenylmethyl Carbazate is a reagent for the sensitive fluorogenic derivatization of carbohydrates.

Synthesis

28920-43-6

35661-51-9

General procedure for the synthesis of 9-fluorenylmethylhydrazinyl formate from 9-fluorenylmethylhydrazinyl formate as chloroformic acid methyl ester (FmocCl): to a well-stirred solution of hydrazine hydrate (19 g, 386 mmol) dissolved in 150 mL of CH3CN/H2O (1:1, v/v) at 0 °C, FmocCl (10 g, 38.65 mmol) dissolved in a solution of 600 mL of CH3CN. The reaction mixture was then warmed to room temperature and stirring was continued for 12 hours. Upon completion of the reaction, the mixture was concentrated in vacuum to about 150 mL and filtered to give the white solid product 9-fluorenylmethylhydrazinyl formate. The product was washed sequentially with water and hexane, dried to constant weight, and finally obtained under vacuum as 9.74 g (99% yield) of a pure product with a melting point of 172-173 °C. The structure of the product was confirmed by 1H NMR and 13C NMR: 1H NMR (DMSO) δ 4.08 (brs, 2H), 4.21 (t, J = 7.2 Hz, 1H), 4.28 (d, J = 7.2 Hz, 2H), 7.32 (t, J = 7.4 Hz, 2H), 7.42 (t, J = 7.4 Hz, 2H), 7.69 ( d, J = 7.4 Hz, 2H), 7.89 (d, J = 7.4 Hz, 2H), 8.36 (brs, 1H); 13C NMR (DMSO) δ 47.7, 66.7, 121.1 (2C), 126.3 (2C), 128.1 (2C), 128.7 (2C), 141.7 (2C), 144.9 (2C), 159.2. 159.2.

References

[1] Journal of Organic Chemistry, 2012, vol. 77, # 12, p. 5271 - 5278
[2] Patent: US9115171, 2015, B2. Location in patent: Page/Page column 43
[3] Patent: EP2182974, 2015, B1. Location in patent: Paragraph 0093
[4] Patent: CN108178739, 2018, A. Location in patent: Paragraph 0032; 0033; 0034
[5] Tetrahedron, 2011, vol. 67, # 42, p. 8187 - 8194

FMOC-HYDRAZIDE HCL Preparation Products And Raw materials

Raw materials

Preparation Products

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FMOC-HYDRAZIDE HCL Suppliers

Americas 1 China 127 Europe 1 Germany 1 India 2 Japan 3 South Korea 1 Switzerland 1 United States 13 Global 150

Suzhou Highfine Biotech Co., Ltd

Tel: 0512-69209928 18796809688
Email: zhouyingxiang@highfine.com
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J & K SCIENTIFIC LTD.

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Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
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Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006356688 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
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Advantage: 62

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

ShangHai DEMO Chemical Co.,Ltd

Tel: 400-021-7337 2355568890
Fax: 0086-21-50182339
Email: sales@demochem.com
Country: China
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Beijing HwrkChemical Technology Co., Ltd

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Fax: 010-89508210
Email: sales.bj@hwrkchemical.com
Country: China
ProdList: 9400
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Energy Chemical

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Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
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Beijing Ouhe Technology Co., Ltd

Tel: 010-010-82967028 13522913783
Fax: +86-10-82967029
Email: 2355560935@qq.com
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ProdList: 12000
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Accela ChemBio Co.,Ltd.

Tel: 021-50795510 4000665055
Fax: 021-50795055
Email: sales@accelachem.com
Country: China
ProdList: 11035
Advantage: 64

Nanjing Chemlin Chemical Co., Ltd

Tel: 025-83697070
Fax: +86-25-83453306
Email: info@chemlin.com.cn
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ProdList: 15883
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View Lastest Price from FMOC-HYDRAZIDE HCL manufacturers

Henan Aochuang Chemical Co.,Ltd.

Product: FMOC-HYDRAZIDE HCL 35661-51-9
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1ton
Release date: 2022-09-26

Zhuozhou Wenxi import and Export Co., Ltd

Product: FMOC-HYDRAZIDE HCL 35661-51-9
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

Zhuozhou Wenxi import and Export Co., Ltd

Product: FMOC-HYDRAZIDE HCL 35661-51-9
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-08

35661-51-9, FMOC-HYDRAZIDE HCLRelated Search:

Hydrazine dihydrochloride Acethydrazide Methyl carbazate Formylhydrazine Methyl 4-amino-2-methoxybenzoate Ethyl 3-indoleacetate Hydrazine acetate Methylhydrazine 4-(FMOC-HYDRAZINO)-BENZOIC ACID FMOC-HYDRAZIDE HCL 6-FMOC-HYDRAZINONICOTINIC ACID 4-FMOC-HYDRAZINOBENZOYL AM NOVAGEL(TM) 2-N-(TERT-BUTOXYCARBONYL)-AMINO-3-(2-N-FMOC-AMINO-PYRROLIDINYL)PROPIONIC ACID RARECHEM GF HN 0001 AKOS 91273 SUCCINIMIDYL 6-FMOC-HYDRAZINONICOTINATE RARECHEM GF HN 0003 FMOC-1-AMINO-4-(2-HYDROXYETHYL)PIPERAZINE

FMOC-HYDRAZIDE HCL

FMOC-NHNH2

FMOC-NHNH2 HCL

N-9-FLUORENYLMETHOXYCARBONYL-CARBAZATE HYDROCHLORIDE

N-(9-FLUORENYLMETHOXYCARBONYL)-HYDRAZIDE HYDROCHLORIDE

9-Fluorenylmethyl carbazate

9-fluorenylmethylchloroformatehydrazine

N-(9-Fluorenylmethoxycarbonyl) hydrazine (FMOC hydrazine)

Fmoc-hydrazide 9-Fluorenylmethyl carbazate

(9H-fluoren-9-yl)Methyl hydrazinecarboxylate

9-FluorenylMethyl carbazate, derivatization grade

9-Fluorenylmethyl carbazate, 98%, derivatization grade

9-Fluorenylmethyl carbazate, >=99%

Fmoc-Hydrazine 9-Fluorenylmethyl carbazate

2-amino-2-oxoacetic acid (phenylmethyl) ester

Carbazic Acid 9-Fluorenylmethyl Ester

N-(9-fluorenylmethyloxycarbonyl)hydrazine

9-FluorenylmethylCarbazate&gt

Hydrazinecarboxylic acid, 9H-fluoren-9-ylmethyl ester

[(9H-Fluoren-9-ylmethoxy)carbonyl]hydrazine

9H-fluoren-9-ylmethyl N-aminocarbamate

35661-51-9

Fluorescent Probes, Labels, Particles and Stains

Detection

Biochemicals and Reagents

BioChemical