4-IODOBUTYL ACETATE
- Product Name
- 4-IODOBUTYL ACETATE
- CAS No.
- 40596-44-9
- Chemical Name
- 4-IODOBUTYL ACETATE
- Synonyms
- 4-IODOBUTYL ACETATE;1-ACETOXY-4-IODOBUTANE;4-iodobutyl acetate 96%;4-ACETOXY-BUTAN-1-IODIDE;4-iodo-1-butanol acetate;1-Butanol, 4-iodo-, 1-acetate;4-Iodobutylacetate, 85%, tech.;4-Iodobutyl acetate, 97%, stab;ACETIC ACID 4-IODO-BUTYL ESTER;4-IODOBUTYL ACETATE, TECH., 85%
- CBNumber
- CB1210301
- Molecular Formula
- C6H11IO2
- Formula Weight
- 242.05
- MOL File
- 40596-44-9.mol
4-IODOBUTYL ACETATE Property
- Boiling point:
- 94-95 °C5.5 mm Hg(lit.)
- Density
- 1.61 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.497(lit.)
- Flash point:
- 195 °F
- solubility
- Difficult to mix.
- form
- liquid
- color
- Light green turbid
- Sensitive
- Light Sensitive
- CAS DataBase Reference
- 40596-44-9(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
- WGK Germany
- 3
- HS Code
- 29153900
N-Bromosuccinimide Price
- Product number
- H31826
- Product name
- 4-Iodobutyl acetate, 96%, stab. with copper
- Packaging
- 10g
- Price
- $63.65
- Updated
- 2024/03/01
- Product number
- H31826
- Product name
- 4-Iodobutyl acetate, 96%, stab. with copper
- Packaging
- 50g
- Price
- $196.65
- Updated
- 2024/03/01
- Product number
- 2123-H-02
- Product name
- 4-Iodobutyl acetate
- Packaging
- 10g
- Price
- $141
- Updated
- 2021/12/16
- Product number
- HCH0023951
- Product name
- 4-IODOBUTYLACETATE
- Purity
- 95.00%
- Packaging
- 10G
- Price
- $166.32
- Updated
- 2021/12/16
- Product number
- 2123-H-02
- Product name
- 4-Iodobutyl acetate
- Packaging
- 50g
- Price
- $312
- Updated
- 2021/12/16
4-IODOBUTYL ACETATE Chemical Properties,Usage,Production
Chemical Properties
CLEAR DARK BROWN LIQUID
Uses
4-Iodobutyl acetate is used in the preparation of tricyclohexyl(acetoxybutyl))phosphonium iodide, tri-n-hexyl(acetoxybutyl))phosphonium iodide
Synthesis Reference(s)
Synthetic Communications, 24, p. 951, 1994 DOI: 10.1080/00397919408020770
Synthesis
The synthesis of 4-IODOBUTYL ACETATE is as follows:Acetic acid (0.30mmol, 1.0 equivalent), CuI (0.03mmol, 10.0mol%, 5.7mg) and NaI (0.60mmol, 2.0 equivalent, 89.9mg) were added to a 10mL Schlenk tube equipped with a magnetic stirring device. Vacuum the flask with a pump and backfill it three times with nitrogen. Then, 1.0 mL tetrahydrofuran (12.30 mmol, 41.0 equivalence, 1 mL, c=0.30 M), deionized water (0.45 mmol, 1.5 equivalence) and TMSCF3 (0.36 mmol, 1.2 equivalence) were added under N2 atmosphere. The mixture is stirred at 150°C (thermostatic oil bath pot) for 12 hours. After cooling to room temperature, dilute the mixture with ethyl acetate (15 mL), wash with water and brine, and dry on anhydrousNa2SO4. After Extraction by EtOAc (5 mL x 3), the combined organic layer was dehydrated with anhydrousNa2SO4 and concentrated under reduced pressure. The crude product is purified by rapid chromatography on silica gel to obtain alkyl iodide.
4-IODOBUTYL ACETATE Preparation Products And Raw materials
Raw materials
Preparation Products
4-IODOBUTYL ACETATE Suppliers
- Tel
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- Country
- Switzerland
- ProdList
- 6896
- Advantage
- 91
View Lastest Price from 4-IODOBUTYL ACETATE manufacturers
- Product
- 4-IODOBUTYL ACETATE 40596-44-9
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2023-07-27
- Product
- 4-IODOBUTYL ACETATE 40596-44-9
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-08-11