tert-Butyl 3,6-diazabicyclo[3.1.1]heptane-6-carboxylate
- Product Name
- tert-Butyl 3,6-diazabicyclo[3.1.1]heptane-6-carboxylate
- CAS No.
- 869494-16-6
- Chemical Name
- tert-Butyl 3,6-diazabicyclo[3.1.1]heptane-6-carboxylate
- Synonyms
- tert-Butyl 3,6-diazabicyclo[3.1.1]heptane-6-carboxylate;DM1Impurity14;3,6-DiazabicycL;o[3.1.1]heptane-6-carboxyL;6-Boc-3,6-diaza-bicyclo[3.1.1]heptane;6-(tert-Butyloxycarbonyl)-3,6-diazabicyclo[3.1.1]heptane;tert-Butyl 3,6-diazabicyclo[3.1.1]heptane-6-carboxylate 97%;3,6-Diazbiclo[.1.1]heptane-6-carboxylic acid tert-butyl ester;tert-Butyl (1S,5R)-3,6-diazabicyclo[3.1.1]heptane-6-carboxylate;(1R,5S)-tert-butyl 3,6-diazabicyclo[3.1.1]heptane-6-carboxylate
- CBNumber
- CB12534807
- Molecular Formula
- C10H18N2O2
- Formula Weight
- 198.26
- MOL File
- 869494-16-6.mol
tert-Butyl 3,6-diazabicyclo[3.1.1]heptane-6-carboxylate Property
- Boiling point:
- 276℃
- Density
- 1.104
- Flash point:
- 121℃
- storage temp.
- 2-8°C(protect from light)
- pka
- 9.53±0.20(Predicted)
- form
- solid
- color
- White to off-white
- InChI
- InChI=1S/C10H18N2O2/c1-10(2,3)14-9(13)12-7-4-8(12)6-11-5-7/h7-8,11H,4-6H2,1-3H3
- InChIKey
- OUFBVDKNEWUFHP-UHFFFAOYSA-N
- SMILES
- C12CC(N1C(OC(C)(C)C)=O)CNC2
Safety
- HS Code
- 2933599590
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
N-Bromosuccinimide Price
- Product number
- B789735
- Product name
- tert-Butyl3,6-diazabicyclo[3.1.1]heptane-6-carboxylate
- Packaging
- 250mg
- Price
- $40
- Updated
- 2021/12/16
- Product number
- 263598
- Product name
- 6-Boc-3,6-diazabicyclo[3.1.1]heptane
- Packaging
- 50mg
- Price
- $509
- Updated
- 2021/12/16
- Product number
- FB29383
- Product name
- 6-Boc-3,6-diazabicyclo[3.1.1]heptane
- Packaging
- 500mg
- Price
- $400
- Updated
- 2021/12/16
- Product number
- FB29383
- Product name
- 6-Boc-3,6-diazabicyclo[3.1.1]heptane
- Packaging
- 1g
- Price
- $500
- Updated
- 2021/12/16
- Product number
- CHM0394022
- Product name
- TERT-BUTYL-3,6-DIAZABICYCLO[3.1.1]HEPTANE-6-CARBOXYLATE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $503.81
- Updated
- 2021/12/16
tert-Butyl 3,6-diazabicyclo[3.1.1]heptane-6-carboxylate Chemical Properties,Usage,Production
Synthesis
To a stirred solution of 3,6-Diazabicyclo[3.1.1]heptane-6-carboxylic acid, 3-[(2-nitrophenyl)sulfonyl]-, 1,1-dimethylethyl ester (400 mg, 1.04 mmol) in DMF (2.5 mL) were added dodecanethiol (500 μL, 2.09 mmol) and lithium hydroxide hydrate (88 mg, 2.09 mmol). The mixture was stirred at r.t. for 2 h. The mixture was diluted with hexanes-ethyl acetate (10 mL, 1:1). The mixture was extracted with aq. Hydrochloric acid (2 x 5.0 mL). The aq. layer was extracted with hexanes-ethyl acetate (10 mL, 1:1). The combined organic layers were discarded. The aq. layer was basified with NaOH (6.0 mL of 1.0 M solution) until pH=13. The aq. layer was extracted with methylene chloride-methanol (2 x 10 mL, 9:1). The organic layer was washed with brine, dried over anhydrous magnesium sulfate, filtered and concentrated in vacuo to afford tert-Butyl 3,6-diazabicyclo[3.1.1]heptane-6-carboxylate as a white solid; Yield, 167 mg (81percent)
tert-Butyl 3,6-diazabicyclo[3.1.1]heptane-6-carboxylate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from tert-Butyl 3,6-diazabicyclo[3.1.1]heptane-6-carboxylate manufacturers
- Product
- 3,6-Diazabicyclo[3.1.1]heptane-6-carboxylic acid tert-butyl ester 869494-16-6
- Price
- US $5.00-0.10/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-04-09
- Product
- 3,6-Diazabicyclo[3.1.1]heptane-6-carboxylic acid tert-butyl ester 869494-16-6
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-10-08
- Product
- 3,6-Diazabicyclo[3.1.1]heptane-6-carboxylic acid tert-butyl ester 869494-16-6
- Price
- US $9.80/KG
- Min. Order
- 1KG
- Purity
- ≥98%
- Supply Ability
- 20 tons
- Release date
- 2020-01-10