Cyclopropyl carbinol

Description Referrence

Product Name: Cyclopropyl carbinol
CAS No.: 2516-33-8
Chemical Name: Cyclopropyl carbinol
Synonyms: CYCLOPROPYLMETHANOL;CYCLOPROPANEMETHANOL;CPMO;CP-CARBINOL;(HYDROXYMETHYL)CYCLOPROPANE;CPC-OL;Cyclopropylmethane;RARECHEM AK ML 0580;CYCLOPROPYL CARBINOL;CYCLPOPROPANEMETHANOL
CBNumber: CB1254806
Molecular Formula: C4H8O
Formula Weight: 72.11
MOL File: 2516-33-8.mol

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Cyclopropyl carbinol Property

Melting point:: -60 °C
Boiling point:: 123-124 °C738 mm Hg(lit.)
Density: 0.89 g/mL at 25 °C(lit.)
refractive index: n20/D 1.431(lit.)
Flash point:: 95 °F
storage temp.: Flammables area
solubility: Chloroform, Ethyl Acetate
pka: 15.10±0.10(Predicted)
form: Liquid
color: Clear colorless
Specific Gravity: 0.890
Water Solubility: miscible
BRN: 1846846
InChIKey: GUDMZGLFZNLYEY-UHFFFAOYSA-N
CAS DataBase Reference: 2516-33-8(CAS DataBase Reference)
NIST Chemistry Reference: Cyclopropyl carbinol(2516-33-8)
EPA Substance Registry System: Cyclopropanemethanol (2516-33-8)

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Safety

Hazard Codes: Xn,Xi,C,F
Risk Statements: 10-22-36-34
Safety Statements: 16-26-36-45-36/37/39
RIDADR: UN 1987 3/PG 3
WGK Germany: 1
RTECS: GZ2212250
Hazard Note: Irritant
TSCA: Yes
HazardClass: 3
PackingGroup: III
HS Code: 29061990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

H302Harmful if swallowed

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 482099
Product name: Cyclopropanemethanol
Purity: ≥99.5%
Packaging: 25ml
Price: $67.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: 482099
Product name: Cyclopropanemethanol
Purity: ≥99.5%
Packaging: 1l
Price: $384.6
Updated: 2024/03/01

TCI Chemical

Product number: C0982
Product name: Cyclopropanemethanol
Purity: >98.0%(GC)
Packaging: 5mL
Price: $20
Updated: 2024/03/01

TCI Chemical

Product number: C0982
Product name: Cyclopropanemethanol
Purity: >98.0%(GC)
Packaging: 25mL
Price: $37
Updated: 2024/03/01

Alfa Aesar

Product number: A12567
Product name: Cyclopropanemethanol, 98%
Packaging: 5g
Price: $27.65
Updated: 2024/03/01

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Cyclopropyl carbinol Chemical Properties,Usage,Production

Description

Cyclopropyl carbinol (also known as Cyclopropanemethanol) is an anaesthetic. Cyclopropyl Carbinol is used as an intermediate for pharmaceuticals, agrochemical, and other organic synthesis such as for the applications for electronics chemicals, polymer additives, coatings, adhesives, surfactants, and other applications3. It can also be used for the preparation of cyclopropanecarbaldehyde, cyclopropylmethylsulfonate and dibenzyl cyclopropylmethyl phosphate1. It is also quite useful to for stereoselective synthesis of cycloalkene-fused butyrolactones via cyclopropylcarbinol solvolysis.

Referrence

Marshall, James A., and R. H. Ellison. "Stereoselective synthesis of cycloalkene-fused butyrolactones via cyclopropylcarbinol solvolysis." Journal of Organic Chemistry 40.14(1975):2070-2073.

Chemical Properties

Clear colorless liquid

Uses

Cyclopropanemethanol is used as an organic chemical synthesis intermediate.

Uses

Cyclopropylmethanol used to increase selectivity of pyridyl-cinnoline phosphodiesterase 10A, inhibitors against phosphodiesterase 3 (PDE3). Also used in the synthesis of benzodiazapin-2-ones

Preparation

The preparation of Cyclopropyl carbinol is as follows:A 1L three-necked flask was charged with 100 g (1mol) of methyl cyclopropanoate. 57g (1.5mol) of sodium borohydride, 500 mL of methanol, and then cooled to 2°C, 66.67g (0.5mol) of aluminum trichloride was added in batches and reacted overnight. The reaction was quenched by the addition of a saturated aqueous solution of ammonium chloride, filtered, and the filtrate was concentrated and evaporated. The product was collected in a yield of 53.49g, a yield of 74.3%.

General Description

Cyclopropanemethanol (Cyclopropyl carbinol, CPMO), a cycloalkanemethanol, is an anaesthetic. The coupling reaction of cyclopropanemethanol with alkynes to form substituted allylic alcohols has been reported. The microwave spectrum of CPMO has been recorded. Its rotational constants and dipole moment have been determined.

Cyclopropyl carbinol Preparation Products And Raw materials

Raw materials

Diazomethane Diiodomethane ZINC-COPPER COUPLE Allyl alcohol

Preparation Products

Cyclopropanecarboxaldehyde Cyclobutanol

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Cyclopropyl carbinol Suppliers

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View Lastest Price from Cyclopropyl carbinol manufacturers

Hebei Weibang Biotechnology Co., Ltd

Product: Cyclopropyl carbinol 2516-33-8
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 mt
Release date: 2024-10-28

Henan Fengda Chemical Co., Ltd

Product: Cyclopropyl carbinol 2516-33-8
Price: US $100.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-26

Hebei Mojin Biotechnology Co., Ltd

Product: Cyclopropyl carbinol 2516-33-8
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-07-24

2516-33-8, Cyclopropyl carbinolRelated Search:

Allyl chloride Propylthiouracil Cyclopropanesulfonyl chloride methylol cellulose Methyl 2-hydroxyethyl cellulose Tris(hydroxymethyl)nitromethane Tris(hydroxymethyl)aminomethane Cyclopropyl bromide Cyclopropyl acetylene Cyclopropane Cyclopropanecarbonitrile (Bromomethyl)cyclopropane Trimethylolpropane 2-Hydroxyethyl methacrylate N,N-Diisopropylethylamine Cyclopropyl methyl ketone Methanol Dicyclopropane methylamine

Cyclopropylmethanol for synthesis

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CYCLPOPROPANEMETHANOL

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cyclopropanemethylalcohol

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cyclopropylmethylalcohol

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CYCLOPROPYLMETHANOL, 99.5+%

Hydroxymethylcydopropane

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Cyclopropanemethanol ,99%

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Cyclopropylmethane

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Cyclopropane-1-methanol（CPM)

Cyclopropanemethanol &gt

Cyclopropyl carbinol ISO 9001：2015 REACH

Cyclopropanemethanol 99%

Cyclopropanemethanol (6CI, 7CI, 8CI, 9CI, ACI)

Methyl Cyclopropyl Methanol/ Methyl Cyclopro Commercial

Methyl Cyclopropyl Methanol/ Methyl Cyclopro

2516-33-8

2516-33-9

C3H5CH2OH

Cyclopropanes

Simple 3-Membered Ring Compounds

Oxygen Compounds

Organic Building Blocks

C2 to C6

Alcohols

Building Blocks

Alcohols

Building Blocks

C2 to C6

Chemical Synthesis

Organic Building Blocks

Oxygen Compounds

Cyclopropanes

Simple 3-Membered Ring Compounds

Cycloalkanes