ChemicalBook > CAS DataBase List > 4-Chlorobenzylamine
4-Chlorobenzylamine
- Product Name
- 4-Chlorobenzylamine
- CAS No.
- 104-86-9
- Chemical Name
- 4-Chlorobenzylamine
- Synonyms
- (4-Chlorophenyl)methanamine;4-Chlorbenzylamine;RARECHEM AL BW 0027;TIMTEC-BB SBB004154;P-CHLOROBENZYLAMINE;4-CHLOROBENZYLAMINE;Chlorobenzylamine,97%;Benzylamine, p-chloro-;LABOTEST-BB LTBB000701;4-ChlorobenzylaMine 98%
- CBNumber
- CB1270950
- Molecular Formula
- C7H8ClN
- Formula Weight
- 141.6
- MOL File
- 104-86-9.mol
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4-Chlorobenzylamine Property
- Melting point:
- 277-278 °C(Solv: N,N-dimethylformamide (68-12-2))
- Boiling point:
- 215 °C (lit.)
- Density
- 1.164 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.558(lit.)
- Flash point:
- 195 °F
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- form
- Liquid
- pka
- 8.85±0.10(Predicted)
- color
- Clear slightly yellow
- Water Solubility
- Not miscible in water.
- Sensitive
- Air Sensitive
- BRN
- 507949
- CAS DataBase Reference
- 104-86-9(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzenemethanamine, 4-chloro-(104-86-9)
- EPA Substance Registry System
- Benzenemethanamine, 4-chloro- (104-86-9)
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Safety
- Hazard Codes
- Xi,C
- Risk Statements
- 36/37/38-34-52-21/22
- Safety Statements
- 26-36-45-36/37/39
- RIDADR
- 2735
- WGK Germany
- 3
- F
- 9-23
- TSCA
- Yes
- HazardClass
- 8
- PackingGroup
- III
- HS Code
- 29214990
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- C27409
- Product name
- 4-Chlorobenzylamine
- Purity
- 98%
- Packaging
- 5g
- Price
- $43
- Updated
- 2025/07/31
Sigma-Aldrich
- Product number
- C27409
- Product name
- 4-Chlorobenzylamine
- Purity
- 98%
- Packaging
- 25g
- Price
- $71.6
- Updated
- 2025/07/31
TCI Chemical
- Product number
- C1090
- Product name
- 4-Chlorobenzylamine
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $77
- Updated
- 2025/07/31
TRC
- Product number
- C367755
- Product name
- 4-Chlorobenzylamine
- Packaging
- 50g
- Price
- $180
- Updated
- 2021/12/16
Frontier Specialty Chemicals
- Product number
- JK150750
- Product name
- 4-Chlorobenzylamine
- Purity
- 98%
- Packaging
- 5g
- Price
- $22
- Updated
- 2021/12/16
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4-Chlorobenzylamine Chemical Properties,Usage,Production
Chemical Properties
clear slightly yellow liquid
Uses
4-Chlorobenzylamine is used as pharmaceutical intermediate.
Synthesis
623-03-0
104-86-9
General procedure for the synthesis of p-chlorobenzylamine from p-chlorobenzonitrile: Ruthenium(II) complex (1 M) and 2-butanol (5 mL) were added to a 25 mL flask under argon protection and stirred for 5 min at room temperature. Subsequently, KOtBu (0.05 mM) was added and stirring was continued for 5 minutes. Next, p-chlorobenzonitrile (0.5 mM) was added and the reaction mixture was heated on a hot plate at 120°C for 30 minutes. Upon completion of the reaction, the catalyst was separated from the reaction mixture by the addition of petroleum ether, followed by filtration. The filtrate was neutralized with 1 M HCl. The ether layer was purified by short path silica gel column chromatography. Hexadecane was added to the purified filtrate as an internal standard and the yield of the product p-chlorobenzylamine was determined by gas chromatography (GC).
References
[1] Chemistry - A European Journal, 2016, vol. 22, # 14, p. 4991 - 5002
[2] Journal of the American Chemical Society, 2015, vol. 137, # 28, p. 8888 - 8891
[3] Journal of Coordination Chemistry, 2015, vol. 68, # 2, p. 321 - 334
[4] Synlett, 2001, # 10, p. 1623 - 1625
[5] Catalysis Letters, 2016, vol. 146, # 10, p. 2149 - 2156
4-Chlorobenzylamine Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-Chlorobenzylamine manufacturers
Hebei Chuanghai Biotechnology Co., Ltd
- Product
- 4-Chlorobenzylamine 104-86-9
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 mt
- Release date
- 2024-12-09
Anhui Dexinjia Biopharm Co., Ltd
- Product
- 4-Chlorobenzylamine 104-86-9
- Price
- US $200.00-150.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20tons
- Release date
- 2024-05-20
Zhuozhou Wenxi import and Export Co., Ltd
- Product
- 4-Chlorobenzylamine 104-86-9
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-08-11
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