Tetrabutylammonium tetrafluoroborate

Product Name: Tetrabutylammonium tetrafluoroborate
CAS No.: 429-42-5
Chemical Name: Tetrabutylammonium tetrafluoroborate
Synonyms: tetrabutylammonium tetrafluoborate;TETRA-N-BUTYLAMMONIUM TETRAFLUOROBORATE;SKL1461;SKL1624;N4,4,4,4BF4;ammonium TetrafL;Tetrabutylammonium fluoborate;TETRABUTYLAMMONIUM FLUOROBORATE;TETRA-N-BUTYLAMMONIUM FLUOROBORATE;Tetrabutylazanium tetrafluoroborate
CBNumber: CB1273128
Molecular Formula: C16H36BF4N
Formula Weight: 329.27
MOL File: 429-42-5.mol

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Tetrabutylammonium tetrafluoroborate Property

Melting point:: 155-161 °C(lit.)
Flash point:: >93℃
storage temp.: −20°C
solubility: methanol: 0.1 g/mL, clear, colorless
form: Crystalline Powder
color: White
Water Solubility: Slightly soluble
Sensitive: Hygroscopic
BRN: 3577508
InChIKey: DWWRDPSMLREDKW-UHFFFAOYSA-M
CAS DataBase Reference: 429-42-5(CAS DataBase Reference)
NIST Chemistry Reference: Tetrabutylammonium tetrafluoroborate(429-42-5)
EPA Substance Registry System: 1-Butanaminium, N,N,N-tributyl-, tetrafluoroborate(1-) (429-42-5)

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Safety

Hazard Codes: Xi,T,Xn
Risk Statements: 36/37/38-41-37/38-22
Safety Statements: 26-36-37/39-39
RIDADR: UN 1759 8/PG III
WGK Germany: 3
Hazard Note: Irritant/Hygroscopic
TSCA: Yes
HazardClass: TOXIC, HYGROSCOPIC
PackingGroup: III
HS Code: 29239000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 217964
Product name: Tetrabutylammonium tetrafluoroborate
Purity: 99%
Packaging: 5g
Price: $41.1
Updated: 2024/03/01

Sigma-Aldrich

Product number: 217964
Product name: Tetrabutylammonium tetrafluoroborate
Purity: 99%
Packaging: 25g
Price: $189
Updated: 2024/03/01

TCI Chemical

Product number: T0914
Product name: Tetrabutylammonium Tetrafluoroborate
Purity: >98.0%(N)
Packaging: 25g
Price: $29
Updated: 2024/03/01

TCI Chemical

Product number: T0914
Product name: Tetrabutylammonium Tetrafluoroborate
Purity: >98.0%(N)
Packaging: 100g
Price: $73
Updated: 2024/03/01

Alfa Aesar

Product number: A16688
Product name: Tetra-n-butylammonium tetrafluoroborate
Purity: 99%
Packaging: 5g
Price: $33.65
Updated: 2024/03/01

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Tetrabutylammonium tetrafluoroborate Chemical Properties,Usage,Production

Chemical Properties

WHITE FINE CRYSTALLINE POWDER

Uses

Tetrabutylammonium tetrafluoroborate may be used in the following studies:

As supporting electrolyte in the voltammetric determination of Δ(9)-tetrahydrocannabinol (Δ(9)-THC).
Synthesis of biologically relevant macrolactones, Sansalvamide A.
As supporting electrolyte in the determination of the oxidation and reduction potentials of 5,10,15,20-tetra[3-(3-trifluoromethyl)phenoxy]porphyrin by cyclic voltammetry.
Preparation of 1:1 adduct with 1,10-phenanthroline.
Used to prepare other tetrabutylammonium salts in aqueous solutions.
As electrolyte additive in the synthesis of conducting poly(thiophenes).

Uses

TBATFB has been used as an electrolyte to understand the paraffin graphite powder modified with sweet potato tissue (PCPET) electrode response.

General Description

Tetrabutylammonium tetrafluoroborate (TBATFB) is a phase transfer catalyst. It can be synthesized by the reaction between 30% aqueous solution of tetrafluoroboric acid and 40% aqueous solution of tetrabutylamonium hydroxide. Tetrabutylammonium tetrafluoroborate acts as an electrolyte and inhibits the self-assembly of alkylthiosulfate on gold.

Purification Methods

Recrystallise it from H2O, aqueous EtOH or from EtOAc by cooling in Dry-ice. Also recrystallise it from ethyl acetate/pentane or dry acetonitrile. Dry it at 80o under vacuum. [Detty & Jones J Am Chem Soc 109 5666 1987, Hartley & Faulkner J Am Chem Soc 107 3436 1985.] The acetate has m 118±2o (from BuCl), the bromide has m 118o (from EtOAc) and the nitrate has m 120o (from *C6H6). [Witschonka & Kraus J Am Chem Soc 69 2472 1947, Wheeler & Sandstedt J Am Chem Soc 77 2024 1955, Beilstein 4 IV 558.]

Tetrabutylammonium tetrafluoroborate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Tetrabutylammonium tetrafluoroborate manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Tetrabutylammonium tetrafluoroborate 429-42-5
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-01-12

Hebei Weibang Biotechnology Co., Ltd

Product: Tetrabutylammonium tetrafluoroborate 429-42-5
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2023-03-08

Hebei Weibang Biotechnology Co., Ltd

Product: Tetrabutylammonium tetrafluoroborate 429-42-5
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2023-02-13

429-42-5, Tetrabutylammonium tetrafluoroborateRelated Search:

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TETRABUTYLAMMONIUM TETRAFLUOROBORATETETRABUTYLAMMONIUM TETRAFLUOROBORATETETRABUTYLAMMONIUM TETRAFLUOROBORATETETRABUTYLAMMONIUM TETRAFLUOROBORATE

Tetrabutylammonium tetrafluoroborate, 98%, for synthesis

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429-42-5

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CH3CH2CH2CH24NBF4

C16H36NBF4

Quaternary Ammonium Compounds

B (Classes of Boron Compounds)

Ammonium Polyhalides, etc. (Quaternary)

Tetrafluoroborates

Phase Transfer Catalysts

Synthetic Reagents

Ammonium Salts

halometallate salts

Ammonium SaltsAnalytical Reagents

Electrochemistry

Greener Alternatives: Catalysis

Phase Transfer Catalysts

Supporting Electrolytes for Electrochemistry

Ammonium Polyhalides, etc. (Quaternary)

B (Classes of Boron Compounds)

Quaternary Ammonium Compounds

Tetrafluoroborates