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cryolite

Product Name
cryolite
CAS No.
15096-52-3
Chemical Name
cryolite
Synonyms
SYNTHETIC CRYOLITE;ALUMINUM SODIUM FLUORIDE;Sodium aluminium fluoride;icespar;icetone;kriolit;CRYOLITE;KRYOLITH;koyoside;kryocide
CBNumber
CB1300372
Molecular Formula
AlF6Na3
Formula Weight
209.94
MOL File
15096-52-3.mol
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cryolite Property

Melting point:
1012
Boiling point:
decomp
Density 
2.9 g/mL at 25 °C(lit.)
refractive index 
1.338
storage temp. 
2-8°C
Merck 
13,2634
CAS DataBase Reference
15096-52-3(CAS DataBase Reference)
EPA Substance Registry System
Cryolite (15096-52-3)
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Safety

Hazard Codes 
T,N
Risk Statements 
20/22-48/23/25-51/53-20
Safety Statements 
22-37-45-61
RIDADR 
UN 3077 9/PG 3
OEB
B
OEL
TWA: 2.5 mg/m3 [*Note: The REL also applies to other inorganic, solid fluorides (as F).]
WGK Germany 
1
RTECS 
BD0075000
TSCA 
Yes
HazardClass 
9
HS Code 
2826300000
Hazardous Substances Data
15096-52-3(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H332Harmful if inhaled

H372Causes damage to organs through prolonged or repeated exposure

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P314Get medical advice/attention if you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
01713
Product name
Cryolite
Purity
synthetic, ≥97.0% (from F)
Packaging
2.5KG-R
Price
$106
Updated
2024/03/01
Sigma-Aldrich
Product number
01713
Product name
Cryolite
Purity
synthetic, ≥97.0% (from F)
Packaging
6X2.5KG-R
Price
$416
Updated
2024/03/01
Sigma-Aldrich
Product number
01713
Product name
Cryolite
Purity
synthetic, ≥97.0% (from F)
Packaging
2.5kg
Price
$102
Updated
2023/01/07
Sigma-Aldrich
Product number
01713
Product name
Cryolite
Purity
synthetic, ≥97.0% (from F)
Packaging
6x2.5kg
Price
$400
Updated
2023/01/07
TRC
Product number
C827510
Product name
Sodium hexafluoroaluminate
Packaging
250g
Price
$45
Updated
2021/12/16
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cryolite Chemical Properties,Usage,Production

Description

Cryolite is an uncommon mineral salt of sodium, fluoride and aluminum that was first discovered on the west coast of Greenland. The supply was depleted by 1987, and synthetic cryolite is now produced from the common mineral fluorite. Cryolite is used at very high application rates of 5-30 kg/ha to control Lepidoptera and Coleoptera on certain fruits, vegetables and citrus. 92% of total cryolite applied in the U.S. is used on grapes in California.

Chemical Properties

Sodium aluminum fluoride is a snow-white crystalline solid, powder or vitreous mass. The crystalline solid (natural product (cryolite) may be colored reddish or brown or even black but loses this discoloration on heating); synthetic product is an amorphous powder. Odorless

Physical properties

Habit: massive, granular, pseudocubic euhedral crystals.
Color: snow white, gray, reddish white, or brownish white.
Diaphaneity: transparent to translucent.
Luster: vitreous, greasy.
Streak: white.
Cleavage: [001], [110], [101].
Fracture: uneven.
Occurrence: large bed in a granitic vein in gray gneiss.
Melting point: 1009°C.

Uses

Electrolyte in the reduction of alumina to aluminum; ceramics; insecticide; binder for abrasives; electric insulation; explosives; polishes.

Uses

Cryolite is commonly used as an electrolyte for aluminum electrolysis. Alumina is dissolved in molten cryolite is used to dissolve alumina during aluminium processing.

Definition

A natural fluoride of sodium and aluminum or made synthetically from fluorspar, sulfuric acid, hydrated alumina, and sodium carbonate.

General Description

An odorless white solid or powder. Mp: 1291°C. Density: 2.95 g cm-3. Dust irritates the eyes and skin; inhaled dust irriates the nose, mouth and lungs. Insoluble in water. Synthesized by fusion of sodium fluoride and aluminum fluoride as a electrolyte in the reduction of alumina to aluminum metal. Occurs in nature as the mineral cryolite. Aqueous suspensions of powdered sodium aluminum fluoride are used as insecticides.

Reactivity Profile

SODIUM ALUMINUM FLUORIDE is non-combustible. Emits toxic fumes when heated to decomposition. Incompatible with strong oxidizing agents and strong acids. Decomposed by bases, which can generate soluble fluorides. Soluble in concentrated sulfuric acid.

Agricultural Uses

Insecticide: Sodium aluminum fluoride is used as an insecticide on food crops and ornamentals, and also in aluminum refining and making ceramics, glass and polishes. Cryolite is used to control a variety of pests on cucurbits (melons, cantaloupe, water melon, pumpkins, all types of squash), fruiting vegetables (eggplant, pepper, broccoli, Brussels sprouts, cabbage, cauliflower, collards, head and leaf lettuce, kohlrabi), kiwi (in California only), pears, radish, cranberry and peaches, grapefruit, lemon, lime, orange, tangelo, tangerines, tomatoes, apples, potatoes, beans and grapes. Also on ornamental plants, woody shrubs and vines. Not listed for use in EU countries. Registered for use in the U.S

Trade name

KRYOCIDE®; CHIOLITE®; CRYOLITE 93®; ICE-SPAR®; ICETONE®; KOYOSIDE®; KRIOLIT®; PROKIL® Sodium aluminum fluoride; VILLIAUMITE®

Safety Profile

Poison by ingestion. Used as a pesticide. Mutation data reported.When heated to decomposition it emits toxic fumes of Fand NazO. See also FLUORIDES.

Potential Exposure

Sodium aluminum fluoride is used in making pesticides, ceramics, glass, and polishes; in refining reduction of aluminum, flux, glass, and enamel.

Shipping

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

Incompatibilities

Incompatible with strong acids such as sulfuric, strong oxidizers, hydrogen fluoride.

Waste Disposal

In accordance with 40CFR 165 recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

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View Lastest Price from cryolite manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
cryolite 15096-52-3
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10 mt
Release date
2024-12-04
Yujiang Chemical (Shandong) Co.,Ltd.
Product
Sodium fluoroaluminate 15096-52-3
Price
US $950.00/T
Min. Order
1T
Purity
99.5%
Supply Ability
200T
Release date
2024-06-12
Hebei Mojin Biotechnology Co., Ltd
Product
cryolite 15096-52-3
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-08-23

15096-52-3, cryoliteRelated Search:


  • ARTIFICAL CRYOLITE
  • KRYOLITH
  • CRYOLITE
  • CRYOLITE, NA3ALF6
  • CRYOLITE, SYNTHETIC
  • Cryolite synthetic, >=97.0% (from F)
  • ALUMINUM SODIUM FLUORIDE
  • SODIUM FLUOROALUMINATE
  • SODIUM HEXAFLUORO ALUMINUM
  • SODIUM ALUMINUM FLUORIDE
  • Sodium aluminium fluoride
  • SYNTHETIC CRYOLITE
  • cryolite(alna3f6)
  • cryolite,natural
  • ent24,984
  • greenlandspar
  • icespar
  • icetone
  • koyoside
  • kriolit
  • kryocide
  • natriumaluminiumfluorid
  • natriumhexafluoroaluminate
  • sodiumaluminofluoride
  • sodiumaluminumfluoride(as
  • High pure Cryolithe
  • Sodium aluminofluoroaluminate
  • risodium hexafluoroaluminate
  • sodiumaluminumfluoride(asf)
  • sodiumfluoaluminate
  • villiaumite
  • SODIUMALUMINIUMHEXAFLUORIDE
  • Sodium hexafluoroaluminate (Cryolite)
  • CRYOLITE, SYNTHETIC, POWDER
  • Cryolite (as fluorine)
  • Kryolith, Sodium hexafluoroaluminate
  • Trisodium hexafluoroaluminate
  • Cryolite, naturally occurring Mineral, grains, approxiMately 1.5-4.8MM (0.06-0.19in)
  • Cryrolite
  • cryolite Basic information
  • Cryolite,99.9%
  • High Quality Synthetic Cryolite/Cryolite Powder 15096-52-3
  • trisodium hexafluoridoaluminate
  • CRYOLITE Extra Pure
  • Cryolite 98% Extrapure
  • 15096-52-3
  • AlF63Na
  • Catalysis and Inorganic Chemistry
  • Aluminum
  • Inorganics
  • Fine chemical