methyl 3-bromo-5-fluoro-2-methylbenzoate

Product Name: methyl 3-bromo-5-fluoro-2-methylbenzoate
CAS No.: 1187318-53-1
Chemical Name: methyl 3-bromo-5-fluoro-2-methylbenzoate
Synonyms: methyl 3-bromo-5-fluoro-2-methylbenzoate;3-BROMO-5-FLUORO-2-METHYL-BENZOIC ACID METHYL ESTER;Benzoic acid, 3-bromo-5-fluoro-2-methyl-, methyl ester
CBNumber: CB13033143
Molecular Formula: C9H8BrFO2
Formula Weight: 247.06
MOL File: 1187318-53-1.mol

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methyl 3-bromo-5-fluoro-2-methylbenzoate Property

Boiling point:: 262.9±40.0 °C(Predicted)
Density: 1.506±0.06 g/cm3(Predicted)
storage temp.: 2-8°C
Appearance: Colorless to light yellow Solid-Liquid Mixture

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Safety

HS Code: 2916399090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B679560
Product name: 3-Bromo-5-fluoro-2-methyl-benzoicAcidMethylEster
Packaging: 500mg
Price: $330
Updated: 2021/12/16

ChemScene

Product number: CS-0061182
Product name: Methyl3-bromo-5-fluoro-2-methylbenzoate
Packaging: 100mg
Price: $54
Updated: 2021/12/16

ChemScene

Product number: CS-0061182
Product name: Methyl3-bromo-5-fluoro-2-methylbenzoate
Packaging: 250mg
Price: $94
Updated: 2021/12/16

Apolloscientific

Product number: PC510281
Product name: Methyl 3-Bromo-5-fluoro-2-methylbenzoate
Packaging: 250mg
Price: $108
Updated: 2021/12/16

ChemScene

Product number: CS-0061182
Product name: Methyl3-bromo-5-fluoro-2-methylbenzoate
Packaging: 1g
Price: $206
Updated: 2021/12/16

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methyl 3-bromo-5-fluoro-2-methylbenzoate Chemical Properties,Usage,Production

Synthesis

67-56-1

1187318-52-0

1187318-53-1

At room temperature, 2-methyl-3-bromo-5-fluorobenzoic acid (4.2 g, crude) was dissolved in methanol (16 mL) and thionyl chloride (2.5 mL) was added slowly. The reaction mixture was heated to 70 °C with continuous stirring for 3 hours. Upon completion of the reaction, the mixture was cooled to room temperature and the solvent was removed under reduced pressure by rotary evaporator to give the crude product. The crude product was purified by silica gel column chromatography with the eluent of petroleum ether/ethyl acetate (50:1, v/v) to afford methyl 3-bromo-5-fluoro-2-methylbenzoate (2.3 g, 51% yield) as a yellow oil.

References

[1] Patent: WO2017/201069, 2017, A1. Location in patent: Paragraph 0516

methyl 3-bromo-5-fluoro-2-methylbenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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methyl 3-bromo-5-fluoro-2-methylbenzoate Suppliers

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1187318-53-1, methyl 3-bromo-5-fluoro-2-methylbenzoateRelated Search:

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methyl 3-bromo-5-fluoro-2-methylbenzoate

3-BROMO-5-FLUORO-2-METHYL-BENZOIC ACID METHYL ESTER

Benzoic acid, 3-bromo-5-fluoro-2-methyl-, methyl ester

1187318-53-1