5-BROMO-2-METHYL-3-NITROPHENYL METHYLCARBOXYLATE

Product Name: 5-BROMO-2-METHYL-3-NITROPHENYL METHYLCARBOXYLATE
CAS No.: 220514-28-3
Chemical Name: 5-BROMO-2-METHYL-3-NITROPHENYL METHYLCARBOXYLATE
Synonyms: SW-37;SWF-37;5-broMo-2-Methyl-3-nitrophenyl acetate;Methyl 5-Bromo-2-methyl-3-nitrobenzoate;2-Methyl-5-BroMo-3-nitrobenzoicacidMethylester;5-BROMO-2-METHYL-3-NITROPHENYL METHYLCARBOXYLATE;5-Bromo-2-methyl-3-nitrobenzoic Acid Methyl Ester;Benzoic acid, 5-broMo-2-Methyl-3-nitro-, Methyl ester;5-BROMO-2-METHYL-3-NITROPHENYL METHYLCARBOXYLATE ISO 9001：2015 REACH
CBNumber: CB1309168
Molecular Formula: C9H8BrNO4
Formula Weight: 274.07
MOL File: 220514-28-3.mol

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5-BROMO-2-METHYL-3-NITROPHENYL METHYLCARBOXYLATE Property

Melting point:: 51.0 to 55.0 °C
Boiling point:: 329.6±37.0 °C(Predicted)
Density: 1.596±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
form: powder to crystal
color: White to Light yellow
InChI: InChI=1S/C9H8BrNO4/c1-5-7(9(12)15-2)3-6(10)4-8(5)11(13)14/h3-4H,1-2H3
InChIKey: UPBDNPCJIJAMPI-UHFFFAOYSA-N
SMILES: C(OC)(=O)C1=CC(Br)=CC([N+]([O-])=O)=C1C

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Safety

HS Code: 2916.39.7900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical

Product number: M2845
Product name: Methyl 5-Bromo-2-methyl-3-nitrobenzoate
Purity: >98.0%(GC)
Packaging: 1g
Price: $26
Updated: 2025/07/31

TCI Chemical

Product number: M2845
Product name: Methyl 5-Bromo-2-methyl-3-nitrobenzoate
Purity: >98.0%(GC)
Packaging: 5g
Price: $76
Updated: 2025/07/31

ChemScene

Product number: CS-M1279
Product name: Methyl 5-Bromo-2-methyl-3-nitrobenzoate
Packaging: 10g
Price: $51
Updated: 2021/12/16

AK Scientific

Product number: W4550
Product name: Methyl 5-Bromo-2-methyl-3-nitrobenzoate
Packaging: 1g
Price: $73
Updated: 2021/12/16

ChemScene

Product number: CS-M1279
Product name: Methyl 5-Bromo-2-methyl-3-nitrobenzoate
Packaging: 25g
Price: $104
Updated: 2021/12/16

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5-BROMO-2-METHYL-3-NITROPHENYL METHYLCARBOXYLATE Chemical Properties,Usage,Production

Synthesis

67-56-1

107650-20-4

220514-28-3

The general procedure for the synthesis of methyl 5-bromo-2-methyl-3-nitrobenzoate from methanol and 2-methyl-3-nitro-5-bromobenzoic acid was as follows: 2-methyl-3-nitro-5-bromobenzoic acid (21.2 g, 81.5 mmol) was dissolved in SOCl2 (100 mL), and the mixture was heated to reflux until it clarified (ca. 1.5 h). After the reaction was complete, the mixture was cooled and concentrated in vacuum. The residue was added to 250 mL of methanol in batches and the resulting mixture was stirred overnight under reflux conditions. Upon completion of the reaction, the mixture was cooled and concentrated. The residue was dissolved in 300 mL of ethyl acetate, washed sequentially with saturated aqueous NaHCO3 and brine, dried over MgSO4 and concentrated. The residue was purified by silica gel column chromatography (eluent: petroleum ether:ethyl acetate=20:1, v:v) to afford methyl 5-bromo-2-methyl-3-nitrobenzoate (21.2 g, yield: 95%) as a light yellow solid.

References

[1] Patent: WO2014/18866, 2014, A1. Location in patent: Paragraph 00181; 00183
[2] Patent: US2018/265517, 2018, A1. Location in patent: Paragraph 0318-0321
[3] Patent: US2017/8904, 2017, A1. Location in patent: Paragraph 0422; 0424
[4] Patent: US2018/177750, 2018, A1. Location in patent: Paragraph 1235-1239
[5] Patent: CN105481790, 2016, A. Location in patent: Paragraph 0198; 0199; 0200; 0204

5-BROMO-2-METHYL-3-NITROPHENYL METHYLCARBOXYLATE Preparation Products And Raw materials

Raw materials

Preparation Products

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5-BROMO-2-METHYL-3-NITROPHENYL METHYLCARBOXYLATE Suppliers

Americas 1 China 126 Europe 1 India 10 Japan 1 United Kingdom 2 United States 13 Global 154

Shanghai Haozhu Pharmaceutical Technology Co. , Ltd.

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View Lastest Price from 5-BROMO-2-METHYL-3-NITROPHENYL METHYLCARBOXYLATE manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: Methyl 5-bromo-2-methyl-3-nitrobenzoate 220514-28-3
Price: US $5.90-3.90/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2025-06-13

Qingdao RENAS Polymer Material Co., Ltd.

Product: methyl 5-bromo-2-methyl-3-nitrobenzoate 220514-28-3
Price: US $0.00/kg
Min. Order: 20kg
Purity: 99%
Supply Ability: 20 tons
Release date: 2025-05-07

Zhuozhou Wenxi import and Export Co., Ltd

Product: 5-BROMO-2-METHYL-3-NITROPHENYL METHYLCARBOXYLATE 220514-28-3
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

220514-28-3, 5-BROMO-2-METHYL-3-NITROPHENYL METHYLCARBOXYLATERelated Search:

(2R,5S)-tert-butyl 4-benzyl-2,5-diMethylpiperazine-1-carboxylate 5-Bromoindazole Pyrrolidine-3-carboxaMide hydrochloride 1H-Pyrrolo[2,3-b]pyridine, 2-methyl-1-(phenylsulfonyl)-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)- 2,4-dichloro-7H-Pyrrolo[2,3-d]pyriMidine-7-carboxylic acid 1,1-diMethylethyl ester 1-METHYL-5-NITRO-1H-INDAZOLE 5-METHYL-4,5,6,7-TETRAHYDRO[1,3]THIAZOLO[5,4-C]PYRIDIN-2-AMINE rac-4-(6-chloro-2-oxo-2,3-dihydro-1H-indol-3-yl)-piperidine-1-carboxylic acid tert-butyl No Chinese name (6-Methylpyridazin-3-yl)MethanaMine dihydrochloride tert-butyl 4-(4-broMothiazol-2-yl)piperazine-1-carboxylate 2-cyclopylcyclopropane-1-carboxylic acid 4-FLUORO-2-HYDROXYBENZALDEHYDE 4-CYANO-7-AZAINDOLE 5-Bromoindole (+/-)-BOC-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER 1-Boc-4-(Hydroxymethyl)-4-methyl-piperidine 4-CYANOPYRAZOLE

5-BROMO-2-METHYL-3-NITROPHENYL METHYLCARBOXYLATE

Methyl 5-Bromo-2-methyl-3-nitrobenzoate

2-Methyl-5-BroMo-3-nitrobenzoicacidMethylester

5-broMo-2-Methyl-3-nitrophenyl acetate

Benzoic acid, 5-broMo-2-Methyl-3-nitro-, Methyl ester

5-Bromo-2-methyl-3-nitrobenzoic Acid Methyl Ester

5-BROMO-2-METHYL-3-NITROPHENYL METHYLCARBOXYLATE ISO 9001：2015 REACH

SWF-37

SW-37

220514-28-3