4-CYANO-7-AZAINDOLE

Product Name: 4-CYANO-7-AZAINDOLE
CAS No.: 344327-11-3
Chemical Name: 4-CYANO-7-AZAINDOLE
Synonyms: SW-42;SWF-42;4-CYANO-7-AZAINDOLE;4-Cyano-7-azaindole 97%;7-Azaindole-4-carbonitrile;4-Cyano-1H-pyrrolo[2,3-b]pyridine;4-CYANO-7-AZAINDOLE ISO 9001：2015 REACH;1H-PYRROLO[2,3-B]PYRIDINE-4-CARBONITRILE;1H-Pyrrolo[2,3-b]pyridine-4-carbonitrile(9CI)
CBNumber: CB3186086
Molecular Formula: C8H5N3
Formula Weight: 143.15
MOL File: 344327-11-3.mol

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4-CYANO-7-AZAINDOLE Property

Melting point:: 195-197℃
Density: 1.29
storage temp.: Sealed in dry,Room Temperature
pka: 12.05±0.40(Predicted)
form: solid
color: Yellow

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 22-37/38-41
Safety Statements: 26-39
WGK Germany: 3
HazardClass: IRRITANT
HS Code: 29339900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 706426
Product name: 7-Azaindole-4-carbonitrile
Purity: 97%
Packaging: 250mg
Price: $124
Updated: 2023/06/20

TRC

Product number: B529810
Product name: 1H-Pyrrolo[2,3-b]pyridine-4-carbonitrile
Packaging: 50mg
Price: $60
Updated: 2021/12/16

AK Scientific

Product number: W5603
Product name: 4-Cyano-7-azaindole
Packaging: 250mg
Price: $76
Updated: 2021/12/16

Frontier Specialty Chemicals

Product number: JK210688
Product name: 4-Cyano-7-azaindole
Purity: 97%
Packaging: 250mg
Price: $127
Updated: 2021/12/16

Matrix Scientific

Product number: 026237
Product name: 1H-Pyrrolo[2,3-b]pyridine-4-carbonitrile
Packaging: 150mg
Price: $25
Updated: 2021/12/16

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4-CYANO-7-AZAINDOLE Chemical Properties,Usage,Production

Chemical Properties

White solid

Synthesis Reference(s)

The Journal of Organic Chemistry, 71, p. 4021, 2006 DOI: 10.1021/jo0602571

Synthesis

557-21-1

55052-28-3

344327-11-3

Step 1: To degassed N,N-dimethylacetamide (200 mL), 4-chloro-7-azaindole (30.0 g, 196.7 mmol), zinc cyanide (23.1 g, 196.7 mmol), zinc powder (1.28 g, 19.67 mmol), tris(dibenzylideneacetone)dipalladium (3.6 g, 3.93 mmol) and diphenylphosphino ferrocene (4.36 g, 7.86 mmol). The reaction mixture was heated at 120 °C for 18 hours. After completion of the reaction, it was cooled to room temperature and the mixture was poured into crushed ice (1.5 kg) and the solid product was collected by filtration. The solid product was washed with ethyl acetate (2 x 1500 mL) and filtered after stirring for 0.5 h at a time. The filtrates were combined, concentrated and crystallized from ethyl acetate to give 1H-pyrrolo[2,3-b]pyridine-4-carbonitrile (22.0 g, 78% yield).1H NMR (400 MHz, DMSO-d6): δ 12.20 (br s, 1H), 8.41 (d, J = 4.8 Hz, 1H), 7.84 (s, 1H), 7.56 (d, J = 4.8 Hz, 1H), 6.65 (d, J = 1.6 Hz, 1H).

References

[1] Patent: WO2012/127506, 2012, A1. Location in patent: Page/Page column 64
[2] Patent: WO2011/23081, 2011, A1. Location in patent: Page/Page column 52

4-CYANO-7-AZAINDOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-CYANO-7-AZAINDOLE Suppliers

China 171 China Hong Kong 1 Europe 1 Germany 2 India 3 United Kingdom 1 United States 14 Global 193

J & K SCIENTIFIC LTD.

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View Lastest Price from 4-CYANO-7-AZAINDOLE manufacturers

Dideu Industries Group Limited

Product: 4-CYANO-7-AZAINDOLE 344327-11-3
Price: US $1.10/g
Min. Order: 1g
Purity: 99.00%
Supply Ability: 100 Tons Min
Release date: 2021-10-25

Career Henan Chemical Co

Product: 4-CYANO-7-AZAINDOLE 344327-11-3
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100kg
Release date: 2019-07-11

344327-11-3, 4-CYANO-7-AZAINDOLERelated Search:

tert-butyl 4-(4-broMothiazol-2-yl)piperazine-1-carboxylate (6-Methylpyridazin-3-yl)MethanaMine dihydrochloride No Chinese name rac-4-(6-chloro-2-oxo-2,3-dihydro-1H-indol-3-yl)-piperidine-1-carboxylic acid tert-butyl 5-METHYL-4,5,6,7-TETRAHYDRO[1,3]THIAZOLO[5,4-C]PYRIDIN-2-AMINE 1-METHYL-5-NITRO-1H-INDAZOLE 2,4-dichloro-7H-Pyrrolo[2,3-d]pyriMidine-7-carboxylic acid 1,1-diMethylethyl ester 5-BROMO-2-METHYL-3-NITROPHENYL METHYLCARBOXYLATE 1H-Pyrrolo[2,3-b]pyridine, 2-methyl-1-(phenylsulfonyl)-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)- Pyrrolidine-3-carboxaMide hydrochloride 5-Bromoindazole (2R,5S)-tert-butyl 4-benzyl-2,5-diMethylpiperazine-1-carboxylate 2-cyclopylcyclopropane-1-carboxylic acid 4-FLUORO-2-HYDROXYBENZALDEHYDE 5-Bromoindole (+/-)-BOC-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER 1-Boc-4-(Hydroxymethyl)-4-methyl-piperidine 4-CYANOPYRAZOLE

4-CYANO-7-AZAINDOLE

1H-PYRROLO[2,3-B]PYRIDINE-4-CARBONITRILE

4-Cyano-7-azaindole 97%

4-Cyano-1H-pyrrolo[2,3-b]pyridine

7-Azaindole-4-carbonitrile

1H-Pyrrolo[2,3-b]pyridine-4-carbonitrile(9CI)

4-CYANO-7-AZAINDOLE ISO 9001：2015 REACH

SWF-42

SW-42

344327-11-3

PYRIDINE

Azaindoles