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1,5-Dibromopentane

Product Name
1,5-Dibromopentane
CAS No.
111-24-0
Chemical Name
1,5-Dibromopentane
Synonyms
Br(CH2)5Br;1,5-Dibrompentan;1,5-DIBROMPENTANE;1,5-DIBROMOPENTANE;1,5-dibromo-pentan;Dibromo-1,5 pentane;Pentan-1,5-dibromid;Pentane,1,5-dibromo-;PENTANE-1,5-DIBROMIDE;1,5-PENTANE DIBROMIDE
CBNumber
CB1317884
Molecular Formula
C5H10Br2
Formula Weight
229.94
MOL File
111-24-0.mol
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1,5-Dibromopentane Property

Melting point:
-34 °C (lit.)
Boiling point:
110 °C/15 mmHg (lit.)
Density 
1.688 g/mL at 25 °C (lit.)
vapor density 
8 (vs air)
refractive index 
n20/D 1.512(lit.)
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform, Methanol (Sparingly)
form 
Liquid
color 
Clear colorless to yellow-brown
Water Solubility 
insoluble
BRN 
1209245
InChIKey
IBODDUNKEPPBKW-UHFFFAOYSA-N
CAS DataBase Reference
111-24-0(CAS DataBase Reference)
NIST Chemistry Reference
Pentane, 1,5-dibromo-(111-24-0)
EPA Substance Registry System
1,5-Dibromopentane (111-24-0)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/38-22
Safety Statements 
23-26-36-37/39
WGK Germany 
3
RTECS 
SA0320000
TSCA 
Yes
HS Code 
29033036
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
128007
Product name
1,5-Dibromopentane
Purity
97%
Packaging
100g
Price
$42.9
Updated
2024/03/01
Sigma-Aldrich
Product number
128007
Product name
1,5-Dibromopentane
Purity
97%
Packaging
500g
Price
$126
Updated
2024/03/01
TCI Chemical
Product number
D0198
Product name
1,5-Dibromopentane
Purity
>98.0%(GC)
Packaging
25g
Price
$18
Updated
2024/03/01
TCI Chemical
Product number
D0198
Product name
1,5-Dibromopentane
Purity
>98.0%(GC)
Packaging
100g
Price
$40
Updated
2024/03/01
Alfa Aesar
Product number
A18465
Product name
1,5-Dibromopentane, 98%
Packaging
100g
Price
$40.1
Updated
2024/03/01
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1,5-Dibromopentane Chemical Properties,Usage,Production

Chemical Properties

clear colorless to yellow-brownish liquid and has an aromatic odor.. soluble in benzene and chloroform, insoluble in water.

Uses

1,5-Dibromopentane is used in the preparation of 1,5-di-Grignard reagent and novel spirocyclic pyrrolidones. It acts as a growth supplement for Yarrowia lipolytica 3589, a tropical marine yeast. It is involved in the synthesis of N-alkylated piperidine as well as tetrydrothiopyran (thiane) by reaction with primary amine and sodium sulfide respectively.

Uses

1,5-Dibromopentane can be used to prepare:
Derivatives of 5-pyrazolones.
O-alkylated phloroglucinol derivatives, which forms the core of poly(alkyl aryl ether) dendrimers.
Intermediate for dezocine viz, (R)-(+)-1-(5-bromopentyl)-1-methyl-7-methoxy-2-tetralone using 1-methyl-7-methoxy-2-tetralone.

Preparation

1,5-Dibromopentane was obtained by ring-opening bromination of tetrahydropyran. In a 500ml flask, add 250g of 48% hydrobromic acid, 75g of concentrated sulfuric acid, 21.5g of redistilled tetrahydropyran (86.5-87.5°C fraction) in turn to a reflux condenser and heat the brown mixture gently to reflux for 3h. After cooling to room temperature, partition the lower layer of dibromide and wash each with saturated sodium carbonate solution and water once. Dried with anhydrous calcium chloride. Distill under reduced pressure and collect the 104-106°C (2.53 kPa) fraction as 1,5-dibromopentane in 46-47 g yield and 80-82% yield.

1,5-Dibromopentane synthesis route

Synthesis Reference(s)

Organic Syntheses, Coll. Vol. 3, p. 692, 1955
The Journal of Organic Chemistry, 48, p. 1678, 1983 DOI: 10.1021/jo00158a018

General Description

1,5-Dibromopentane is a growth supplement for Yarrowia lipolytica 3589, a tropical marine yeast.

1,5-Dibromopentane Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 1,5-Dibromopentane manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
1,5-Dibromopentane 111-24-0
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-01-10
Hebei Miaoyin Technology Co.,Ltd
Product
1,5-Dibromopentane 111-24-0
Price
US $10.00/kg
Min. Order
1kg
Purity
99.9%
Supply Ability
10000
Release date
2023-04-14
hebei hongtan Biotechnology Co., Ltd
Product
1,5-Dibromopentane 111-24-0
Price
US $30.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
2000kg
Release date
2024-05-15

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