1,3-Dibromoadamantane
- Product Name
- 1,3-Dibromoadamantane
- CAS No.
- 876-53-9
- Chemical Name
- 1,3-Dibromoadamantane
- Synonyms
- NSC 102289;1,3-Dibromoadamantan;Carazolol Impurity 5;1,3-DIBROMOADAMANTANE;Dibromoadamantane,97%;Memantine Impurity 44;Memantine Impurity 46;1,3-DIBROMO- ADAMANTINE;Adamantane, 1,3-dibromo-;1,3-Dibromoadamantane>
- CBNumber
- CB2770189
- Molecular Formula
- C10H14Br2
- Formula Weight
- 294.03
- MOL File
- 876-53-9.mol
1,3-Dibromoadamantane Property
- Melting point:
- 108-110 °C (lit.)
- Boiling point:
- 287.6±13.0 °C(Predicted)
- Density
- 1.864±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- Chloroform (Slightly), Ethyl Acetate (Slightly)
- form
- Solid
- color
- White to Pale Gray
- InChI
- InChI=1S/C10H14Br2/c11-9-2-7-1-8(4-9)5-10(12,3-7)6-9/h7-8H,1-6H2
- InChIKey
- HLWZKLMEOVIWRK-UHFFFAOYSA-N
- SMILES
- C12(Br)CC3CC(CC(Br)(C3)C1)C2
- CAS DataBase Reference
- 876-53-9(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 403083
- Product name
- 1,3-Dibromoadamantane
- Purity
- 99%
- Packaging
- 1g
- Price
- $47.5
- Updated
- 2025/07/31
- Product number
- D5654
- Product name
- 1,3-Dibromoadamantane (purified by sublimation)
- Purity
- min. 99.0 %
- Packaging
- 5G
- Price
- $258
- Updated
- 2025/07/31
- Product number
- D2480
- Product name
- 1,3-Dibromoadamantane
- Purity
- >97.0%(GC)
- Packaging
- 5g
- Price
- $46
- Updated
- 2025/07/31
- Product number
- D2480
- Product name
- 1,3-Dibromoadamantane
- Purity
- >97.0%(GC)
- Packaging
- 25g
- Price
- $108
- Updated
- 2025/07/31
- Product number
- D5654
- Product name
- 1,3-Dibromoadamantane (purified by sublimation)
- Packaging
- 1G
- Price
- $77
- Updated
- 2025/07/31
1,3-Dibromoadamantane Chemical Properties,Usage,Production
Chemical Properties
White Solid
Uses
1,3-Dibromoadamantane may be used in the preparation of 1,3-bis(phenyldimethylsilyl)adamantine.
General Description
1,3-Dibromoadamantane is reported to react with diphenylphosphide ions (Ph2P-) under photostimulation by the SRN1 mechanism. The viscosity-dependent retarding effect of 1,3-dibromoadamantane in highly viscous polymeric chlorotrifluoroethene has been studied by 13C NMR relaxation measurements. Preparation of 1,3-dibromoadamantane via dibromination of adamantine has been reported.
Synthesis
281-23-2
768-90-1
876-53-9
Reactions were carried out in 20 mL glass ampoules or 17 mL stainless steel pressure microreactors with consistent results from parallel experiments. Under argon protection, 0.3 mmol of tris(acetylacetonato)iron(III) [Fe(acac)3], 10 mmol of adamantane, 10 mmol of carbon tetrabromide (CBr4), and 150 mmol of dibromomethane (CH2Br2) were added to the microreactor (or ampoule). The reactor (or ampoule) was sealed and heated under stirring conditions. After completion of the reaction, the reactor (or ampoule) was cooled to room temperature, opened and the solvent was removed by distillation and the residue was purified by crystallization with hexane or ethanol. The conversion of adamantane and the yield of its derivatives were determined by gas chromatography (GLC) using decene as an internal standard with correction factors of 1.09 and 1.53 for adamantane and bromoadamantane, respectively.The structures of the resulting compounds were confirmed by comparison with known samples and literature data.
References
[1] Russian Journal of Organic Chemistry, 2015, vol. 51, # 2, p. 184 - 187
[2] Zh. Org. Khim., 2015, vol. 51, # 2, p. 196 - 199
[3] Tetrahedron Letters, 1986, vol. 27, # 12, p. 1399 - 1402
[4] Journal of Organic Chemistry USSR (English Translation), 1984, vol. 20, p. 2041
[5] Zhurnal Organicheskoi Khimii, 1984, vol. 20, # 10, p. 2239 - 2240
1,3-Dibromoadamantane Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 1,3-Dibromoadamantane manufacturers
- Product
- 1,3-Dibromoadamantane 876-53-9
- Price
- US $5.00-0.50/KG
- Min. Order
- 1KG
- Purity
- 99% hplc
- Supply Ability
- 500TONS
- Release date
- 2025-05-30
- Product
- 1,3-Dibromoadamantane 876-53-9
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 5tons
- Release date
- 2024-12-02
- Product
- 1,3-Dibromoadamantane 876-53-9
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1ton
- Release date
- 2022-10-12