ChemicalBook > CAS DataBase List > Ir[dFppy]2(dtbbpy)PF6

Ir[dFppy]2(dtbbpy)PF6

Product Name
Ir[dFppy]2(dtbbpy)PF6
CAS No.
1072067-44-7
Chemical Name
Ir[dFppy]2(dtbbpy)PF6
Synonyms
-κC]iridium hexafL;Ir[dFppy]2(dtbbpy)PF6;[4,4'-Bis(1,1-dimethyL;(Ir[dFppy]2(dtbpy))PF6;C]iridium hexafluorophosphate, 97%;)-2,2'-bipyridine-κN,κN]bis[3,5-difL;2-(2,4-difluorobenzene-6-id-1-yl)pyridine;[Ir(dFppy)2(dtbbpy)]PF6;2,2'-Bis(4-tert-butylpyridine)]bis[2-(2,4-difluorophenyl)pyridine]iridium(III) hexafluorophosphate;4,4'-di-tert-butyl-2,2'-dipyridyl-bis[2-(2',4'-difluorophenyl)pyridine]iridium(III) hexafluorophosphate
CBNumber
CB13350695
Molecular Formula
C40H36F10IrN4P
Formula Weight
985.93
MOL File
1072067-44-7.mol
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Ir[dFppy]2(dtbbpy)PF6 Property

Melting point:
>300°C
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
powder or crystals
Appearance
Light yellow to yellow Solid
InChIKey
YTFMVASKFDAIDY-UHFFFAOYSA-N
SMILES
[P+5]([F-])([F-])([F-])([F-])([F-])[F-].FC1C=C(F)C=[C-]2[Ir+3]34(N5=CC=CC=C5C5=C(C=C(F)C=[C-]35)F)(N3=CC=C(C(C)(C)C)C=C3C3=CC(C(C)(C)C)=CC=N43)N3=CC=CC=C3C=12
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
901368
Product name
[Ir(dFppy)2(dtbbpy)]PF6
Packaging
100MG
Price
$125.61
Updated
2025/07/31
Strem Chemicals
Product number
77-0350
Product name
[4,4'-Bis(1,1-dimethylethyl)-2,2'-bipyridine-κN,κN]bis[3,5-difluoro-2-(2-pyridinyl-κN)phenyl-κC]iridium hexafluorophosphate, 97%
Purity
97%
Packaging
100mg
Price
$101
Updated
2024/03/01
Strem Chemicals
Product number
77-0350
Product name
[4,4'-Bis(1,1-dimethylethyl)-2,2'-bipyridine-κN,κN]bis[3,5-difluoro-2-(2-pyridinyl-κN)phenyl-κC]iridium hexafluorophosphate, 97%
Purity
97%
Packaging
500mg
Price
$402
Updated
2024/03/01
Ambeed
Product number
A757574
Product name
[2,2'-Bis(4-tert-butylpyridine)]bis[2-(2,4-difluorophenyl)pyridine]iridium(III)hexafluorophosphate
Purity
97%
Packaging
1g
Price
$475
Updated
2021/12/16
Ambeed
Product number
A757574
Product name
[2,2'-Bis(4-tert-butylpyridine)]bis[2-(2,4-difluorophenyl)pyridine]iridium(III)hexafluorophosphate
Purity
97%
Packaging
100mg
Price
$60
Updated
2021/12/16
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Ir[dFppy]2(dtbbpy)PF6 Chemical Properties,Usage,Production

Uses

This photocatalyst readily facilitates alkynylation of carboxylic acids as well as the decarboxylative cross-coupling of oxalates via metallaphotoredox catalysis.

reaction suitability

core: iridium
reagent type: catalyst
reaction type: Photocatalysis

Ir[dFppy]2(dtbbpy)PF6 Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Ir[dFppy]2(dtbbpy)PF6 manufacturers

Xian confluore Biological Technology Co., Ltd.
Product
(Ir[dFppy]2(dtbpy))PF6 1072067-44-7
Price
US $0.00/g
Min. Order
1g
Purity
>95.00%
Supply Ability
1g
Release date
2024-03-30

1072067-44-7, Ir[dFppy]2(dtbbpy)PF6Related Search:

Tris[2-(2-pyridinyl-κN)-5-(trifluoromethyl)phenyl-κC]iridium(III) Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III) Ir[dF(t-Bu)-ppy]3 (2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) Hexafluorophosphate Iridium [2,2'-bis (4-tert-butylpyridine)] bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate (2,2'-bipyridyl) bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate Tris (2- (4-tert-butylphenyl) pyridine) iridium Ir[dF(Me)ppy]2(dtbbpy)PF6 Ir(dFppy)3 (2,2'-Bipyridine)bis(2-phenylpyridinato)iridium(III) Hexafluorophosphate Ir[p-F(t-Bu)-ppy]3 [Ir{dFCF3ppy}2(bpy)]PF6 [Ir(dtbbpy)(ppy)2][PF6] Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [1,10-phenanthroline] iridium hexafluorophosphate hexafluorophosphate Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridinyl-κN]phenyl-κC]-,(OC-6-33)-,hexafluorophosphate(1-) Ir[p-F(Me)ppy]2(dtbbpy)PF6

  • C]iridium hexafluorophosphate, 97%
  • Ir[dFppy]2(dtbbpy)PF6
  • [2,2'-bis (4-tert-butylpyridine)] bis [2- (2,4-difluorophenyl) pyridine] iridium (III) hexafluorophosphate
  • (Ir[dFppy]2(dtbpy))PF6
  • [4,4'-Bis(1,1-dimethylethyl)-2,2'-bipyridine-κN,κN]bis[3,5-difluoro-2-(2-pyridinyl-κN)phenyl-κC]iridium hexafluorophosphate, 97%
  • [4,4'-Bis(1,1-dimethyL
  • -κC]iridium hexafL
  • )-2,2'-bipyridine-κN,κN]bis[3,5-difL
  • iridium(3+) ion bis(3,5-difluoro-2-(pyridin-2-yl)benzen-1-ide) 4-tert-butyl-2-(4-tert-butylpyridin-2-yl)pyridine hexafluoro-lambda5-phosphanuide
  • 2-(2,4-difluorobenzene-6-id-1-yl)pyridine
  • Ir[dFppy]2(dtbbpy)PF6,4,4'-Bis(1,1-dimethylethyl)-2,2'-bipyridine-κN,κN]bis[3,5-difluoro-2-(2-pyridinyl-κN)phenyl-κC]iridium hexafluorophosphate
  • 2,2'-Bis(4-tert-butylpyridine)]bis[2-(2,4-difluorophenyl)pyridine]iridium(III) hexafluorophosphate
  • [Ir(dFppy)<sub>2</sub>(dtbbpy)]PF<sub>6</sub>
  • 4,4'-di-tert-butyl-2,2'-dipyridyl-bis[2-(2',4'-difluorophenyl)pyridine]iridium(III) hexafluorophosphate
  • 1072067-44-7