ChemicalBook > CAS DataBase List > ETHOXY-IMINO-ACETIC ACID ETHYL ESTER

ETHOXY-IMINO-ACETIC ACID ETHYL ESTER

Product Name
ETHOXY-IMINO-ACETIC ACID ETHYL ESTER
CAS No.
816-27-3
Chemical Name
ETHOXY-IMINO-ACETIC ACID ETHYL ESTER
Synonyms
Ethyl 2-ethoxy-2-iminoacetate;2-ethoxy-2-iminoacetate;Ethyl ethoxyiminoacetate;Ethyl 2-ethoxy-iminoacetate;Ethyl carboethoxyformidimate;Ethyl 1-carbethoxyformimidate;Ethyl ethoxycarbonylformimidate;ETHOXY-IMINO-ACETIC ACID ETHYL ESTER;Acetic acid, ethoxyimino-, ethyl ester;2-Ethoxy-2-iminoacetic acid ethyl ester
CBNumber
CB1351899
Molecular Formula
C6H11NO3
Formula Weight
145.16
MOL File
816-27-3.mol
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ETHOXY-IMINO-ACETIC ACID ETHYL ESTER Property

Boiling point:
151℃
Density 
1.08
refractive index 
n20/D1.426
Flash point:
45℃
storage temp. 
-20°C
pka
3.21±0.70(Predicted)
form 
liquid
color 
Clear, light yellow
InChI
InChI=1S/C6H11NO3/c1-3-9-5(7)6(8)10-4-2/h7H,3-4H2,1-2H3
InChIKey
DSHWMBCJDOGPTB-UHFFFAOYSA-N
SMILES
C(OCC)(=O)C(OCC)=N
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Safety

Hazard Codes 
Xn
Risk Statements 
22
WGK Germany 
3
HS Code 
2922500090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
790419
Product name
Ethyl 2-ethoxy-2-iminoacetate
Packaging
500mg
Price
$116.2
Updated
2025/07/31
TRC
Product number
E917918
Product name
Ethyl 2-ethoxy-2-iminoacetate
Packaging
100mg
Price
$60
Updated
2021/12/16
SynQuest Laboratories
Product number
4156-1-80
Product name
Ethyl 2-ethoxy-2-iminoacetate
Packaging
500mg
Price
$72
Updated
2021/12/16
SynQuest Laboratories
Product number
4156-1-80
Product name
Ethyl 2-ethoxy-2-iminoacetate
Packaging
1g
Price
$120
Updated
2021/12/16
Matrix Scientific
Product number
087166
Product name
Ethyl ethoxyiminoacetate
Purity
95%
Packaging
5g
Price
$264
Updated
2021/12/16
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ETHOXY-IMINO-ACETIC ACID ETHYL ESTER Chemical Properties,Usage,Production

Synthesis

64-17-5

623-49-4

816-27-3

Ethyl cyanoacetate (40 g, 404 mmol) was dissolved in dichloromethane (200 mL) and cooled to 0°C under nitrogen protection. An ethanol solution of 45 wt.% hydrochloric acid (27.3 mL, 404 mmol) was added slowly and dropwise over 15 min with stirring. The reaction mixture was stirred continuously at 0 °C for 3 h, followed by standing overnight at -5 °C to -3 °C. The following day, dichloromethane (250 mL) was added to the reaction mixture and kept at 0 °C. A solution of triethylamine (113 mL, 807 mmol) in dichloromethane (50 mL) was added dropwise over 30 minutes. After the dropwise addition, the mixture was continued to be stirred at 0°C for 30 minutes. Subsequently, water (100 mL) was added and stirred for 5 minutes. The organic layer was separated, dried over anhydrous sodium sulfate and concentrated under reduced pressure. Diethyl ether (50 mL) was added to the residue and the solid was removed by filtration. The filtrate was dried to give ethyl 2-ethoxy-2-iminoacetate as a light yellow liquid (31.0 g, 214 mmol, 52.9% yield). NMR hydrogen spectrum (400 MHz, CDCl3) δ 8.78 (s, 1H), 4.36-4.28 (m, 4H), 1.40-1.35 (m, 6H).

References

[1] Synthesis, 1997, # 3, p. 301 - 304
[2] Patent: WO2018/154520, 2018, A1. Location in patent: Page/Page column 92
[3] Helvetica Chimica Acta, 1989, vol. 72, p. 825 - 837
[4] Helvetica Chimica Acta, 1989, vol. 72, p. 825 - 837
[5] Patent: WO2009/155121, 2009, A2. Location in patent: Page/Page column 106

ETHOXY-IMINO-ACETIC ACID ETHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from ETHOXY-IMINO-ACETIC ACID ETHYL ESTER manufacturers

Shaanxi Dideu New Materials Co. Ltd
Product
ETHOXY-IMINO-ACETIC ACID ETHYL ESTER 816-27-3
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
10000KGS
Release date
2025-07-04
Wuhan Topule Biopharmaceutical Co., Ltd
Product
ethyl 2-ethoxy-2-iminoacetate 816-27-3
Price
US $20.00/g
Min. Order
1g
Purity
98%HPLC
Supply Ability
20kg
Release date
2023-06-13
Career Henan Chemical Co
Product
ETHOXY-IMINO-ACETIC ACID ETHYL ESTER 816-27-3
Price
US $1.00/KG
Min. Order
1KG
Purity
95-99%
Supply Ability
500kg/month
Release date
2019-08-01

816-27-3, ETHOXY-IMINO-ACETIC ACID ETHYL ESTERRelated Search:


  • (1-Ethoxyformimidoyl)formic acid ethyl ester
  • Ethyl 1-carbethoxyformimidate
  • ETHOXY-IMINO-ACETIC ACID ETHYL ESTER
  • 2-Ethoxy-2-iminoacetic acid ethyl ester
  • Ethyl 2-ethoxy-2-iminoacetate
  • Ethyl carboethoxyformidimate
  • Ethyl ethoxycarbonylformimidate
  • Ethyl ethoxyiminoacetate
  • 2-ethoxy-2-iminoacetate
  • Acetic acid, ethoxyimino-, ethyl ester
  • Acetic acid, ethoxyimino-, ethyl ester (9CI, ACI)
  • Ethyl 2-ethoxy-iminoacetate
  • 816-27-3