Benzoin
- Product Name
- Benzoin
- CAS No.
- 119-53-9
- Chemical Name
- Benzoin
- Synonyms
- 2-HYDROXY-2-PHENYLACETOPHENONE;BENZOIN SUMATRA;Benzoin, 99.5%;2-HYDROXY-1,2-DIPHENYLETHANONE;FEMA 2132;Benzoin, AR;BENZOIN GUM;A-HYDROXYBENZYL PHENYL KETONE;A-HYDROXY-A-PHENYLACETOPHENONE;2-Hydroxy-1,2-diphenylethan-1-on
- CBNumber
- CB1359956
- Molecular Formula
- C14H12O2
- Formula Weight
- 212.24
- MOL File
- 119-53-9.mol
Benzoin Property
- Melting point:
- 134-138 °C(lit.)
- Boiling point:
- 194 °C12 mm Hg(lit.)
- Density
- 1.31
- vapor pressure
- 1.3 hPa (136 °C)
- FEMA
- 2132 | BENZOIN
- Flash point:
- 181
- storage temp.
- Store below +30°C.
- solubility
- 0.3g/l
- form
- Powder
- pka
- 12.28±0.20(Predicted)
- color
- Off-white to very slightly yellow
- Odor
- agreeable vanilla-like odor
- Odor Type
- balsamic
- Water Solubility
- Soluble in chlorine. Slightly soluble in water, ethanol and ether.
- Sensitive
- Moisture Sensitive
- Merck
- 14,1093
- JECFA Number
- 836
- BRN
- 391839
- Stability:
- Stable. Combustible. Incompatible with strong oxidizing agents.
- InChIKey
- ISAOCJYIOMOJEB-UHFFFAOYSA-N
- LogP
- 1.84-2.13 at 25℃
- CAS DataBase Reference
- 119-53-9(CAS DataBase Reference)
- NIST Chemistry Reference
- Ethanone, 2-hydroxy-1,2-diphenyl-(119-53-9)
- EPA Substance Registry System
- Benzoin (119-53-9)
Safety
- Hazard Codes
- Xn
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 24/25-36-26
- WGK Germany
- 2
- RTECS
- DI1590000
- TSCA
- Yes
- HS Code
- 29144090
- Hazardous Substances Data
- 119-53-9(Hazardous Substances Data)
- Toxicity
- LD50 orally in Rabbit: 10000 mg/kg LD50 dermal Rabbit 8870 mg/kg
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 8.01776
- Product name
- Benzoin
- Purity
- for synthesis
- Packaging
- 250g
- Price
- $43.4
- Updated
- 2024/03/01
- Product number
- 8.01776
- Product name
- Benzoin
- Purity
- for synthesis
- Packaging
- 1kg
- Price
- $111
- Updated
- 2024/03/01
- Product number
- 399396
- Product name
- Benzoin
- Purity
- purified by sublimation, ≥99.5%
- Packaging
- 5g
- Price
- $77
- Updated
- 2024/03/01
- Product number
- 80024
- Product name
- Benzoin
- Purity
- analytical standard
- Packaging
- 100mg
- Price
- $58.6
- Updated
- 2022/05/15
- Product number
- B0079
- Product name
- Benzoin
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $23
- Updated
- 2024/03/01
Benzoin Chemical Properties,Usage,Production
Chemical Properties
light yellow powder or crystals with a camphor-like odour
Chemical Properties
Benzoin has a faint, sweet, balsamic odor.
Occurrence
Benzoin is a resin from the trees of genus Styrax.
Uses
Benzoin is used as a flavor, antiseptic and photopolymerization catalyst. It is also used as a raw material in organic syntheses. It serves as a precursor to benzil, which is a photoinitiator. Further, it is used as degassing agent for powder coatings. In addition to this, it is used as an additive and in powder coating to remove the pinhole phenomenon.
Uses
Degassing for powder coatings
Uses
benzoin is a fragrant essential oil with bactericidal, anti-irritation, and anti-itching properties. It is considered a good ingredient for reducing skin redness and is a preservative of fats. Although its primary constituent is benzoic acid, it also contains canillin and an oily aromatic liquid. This balsamic resin is extracted by cutting deeply into the trunks of trees that grow primarily in Indonesia and Thailand.
Definition
ChEBI: A ketone that consists of acetophenone bearing hydroxy and phenyl substituents at the alpha-position. The parent of the class of benzoins.
Definition
benzoin: A colourless crystallinecompound, C6H5CHOHCOC6H5; m.p.137°C. It is a condensation product ofbenzenecarbaldehyde (benzaldehyde),made by the action of sodiumcyanide on benzenecarbaldehyde inalcoholic solution. It also occurs naturallyas the resin of a tropical tree. Itis both a secondary alcohol and a ketone,and gives reactions characteristicof both types of compound.
Taste threshold values
Taste characteristics at 25 ppm: spicy, balsamic, resinous, fruity with an herbal nuance.
General Description
Off-white to yellow-white crystalline solid with an odor of camphor. Slightly acrid taste. When broken the fresh surfaces have a milky-white color.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
2-Hydroxy-2-phenylacetophenone is sensitive to heat and light. 2-Hydroxy-2-phenylacetophenone is incompatible with oxidizers. 2-Hydroxy-2-phenylacetophenone reduces Fehling's solution.
Hazard
Highly toxic.
Fire Hazard
Flash point data for 2-Hydroxy-2-phenylacetophenone are not available; however, 2-Hydroxy-2-phenylacetophenone is probably combustible.
Safety Profile
Slightly toxic by ingestion andskin contact. Mutation data reported. A flammable liquid.When heated to decomposition it emits acrid smoke andirritating fumes.
Synthesis
It may be prepared by condensation of benzaldehyde with an alkali cyanide and used in organic synthesis.
Purification Methods
Crystallise benzoin from CCl4, hot EtOH (8mL/g), or 50% acetic acid. Also crystallise it from high purity *benzene, then twice from high purity MeOH, to remove fluorescent impurities [Elliott & Radley Anal Chem 33 1623 1961]. It can be sublimed. [Beilstein 8 IV 1279.]
Benzoin Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Benzoin manufacturers
- Product
- Benzoin 119-53-9
- Price
- US $20.00-5.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 20 tons
- Release date
- 2023-09-28
- Product
- Benzoin 119-53-9
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2022-12-30
- Product
- Benzoin 119-53-9
- Price
- US $5.00-2.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000kg
- Release date
- 2023-04-24