ChemicalBook > CAS DataBase List > ε-Caprolactone

ε-Caprolactone

Product Name
ε-Caprolactone
CAS No.
502-44-3
Chemical Name
ε-Caprolactone
Synonyms
CAPROLACTONE;2-OXEPANONE;oxepan-2-one;EPSILON-CAPROLACTONE;E-CAPROLACTONE;Oxepanone;6-HEXANOLACTONE;Polycaprolactone Polyol;6-CAPROLACTONE;6-Hydroxyhexan-6-olide
CBNumber
CB1362738
Molecular Formula
C6H10O2
Formula Weight
114.14
MOL File
502-44-3.mol
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ε-Caprolactone Property

Melting point:
-1 °C
Boiling point:
96-97.5 °C10 mm Hg(lit.)
Density 
1.03 g/mL at 25 °C(lit.)
vapor density 
3.9 (vs air)
vapor pressure 
0.01 mm Hg ( 20 °C)
refractive index 
n20/D 1.463(lit.)
Flash point:
229 °F
storage temp. 
Store below +30°C.
solubility 
Chloroform, Ethyl Acetate
form 
Liquid
color 
Clear colorless, yellowing on aging
explosive limit
1.2-9%(V)
Water Solubility 
>1000 MG/L (20 ºC)
BRN 
106919
InChIKey
PAPBSGBWRJIAAV-UHFFFAOYSA-N
LogP
0.32 at 20℃
CAS DataBase Reference
502-44-3(CAS DataBase Reference)
NIST Chemistry Reference
2-Oxepanone(502-44-3)
EPA Substance Registry System
2-Oxepanone (502-44-3)
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Safety

Hazard Codes 
Xi
Risk Statements 
37/38-41-36/38
Safety Statements 
26-39-37/39
WGK Germany 
2
RTECS 
MO8400000
Autoignition Temperature
204 °C
TSCA 
Yes
HS Code 
29322090
Hazardous Substances Data
502-44-3(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: > 2000 mg/kg LD50 dermal Rabbit 5990 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
704067
Product name
ω-Caprolactone
Purity
97%
Packaging
100g
Price
$42.8
Updated
2024/03/01
Sigma-Aldrich
Product number
8.02801
Product name
ε-Caprolactone
Purity
for synthesis
Packaging
250ML
Price
$60.3
Updated
2024/03/01
Sigma-Aldrich
Product number
704067
Product name
ω-Caprolactone
Purity
97%
Packaging
500g
Price
$141
Updated
2024/03/01
TCI Chemical
Product number
C0702
Product name
epsilon-Caprolactone
Purity
>99.0%(GC)
Packaging
25mL
Price
$17
Updated
2024/03/01
TCI Chemical
Product number
C0702
Product name
epsilon-Caprolactone
Purity
>99.0%(GC)
Packaging
500mL
Price
$41
Updated
2024/03/01
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ε-Caprolactone Chemical Properties,Usage,Production

Chemical Properties

Clear colorless liquid, yellowing on ageing

Uses

Intermediate in adhesives, urethane coatings, and elastomers; solvent; diluent for epoxy resins; synthetic fibers; organic synthesis.

Uses

ε-Caprolactone is widely used as a monomer in the manufacturing of highly specialized polymers. It is mainly utilized as a precursor to caprolactam. It finds an application in the synthesis of polyglecaprone, which is used as a suture material in surgery.

Uses

ε-caprolactone is popularly used in the preparation of poly caprolactone (PCL).

Definition

ChEBI: A epsilon-lactone that is oxepane substituted by an oxo group at position 2.

Synthesis Reference(s)

Journal of the American Chemical Society, 80, p. 4079, 1958 DOI: 10.1021/ja01548a063
The Journal of Organic Chemistry, 61, p. 4560, 1996 DOI: 10.1021/jo952237x
Tetrahedron Letters, 17, p. 2455, 1976 DOI: 10.1016/0040-4039(76)90018-6

General Description

ε-caprolactone is a cyclic ester. Ring opening polymerization of ε-caprolactone initiated by, tributylin n butoxide, ethyl magnesium bromide, or samarium acetate or heteropolyacid, leads to the formation of poly caprolactone (PCL).

Flammability and Explosibility

Not classified

ε-Caprolactone Preparation Products And Raw materials

Raw materials

Preparation Products

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ε-Caprolactone Suppliers

Wuhan Rongcan Biotechnology Co., Ltd
Tel
18327024450
Fax
183-27024450
Email
2130026275@qq.com
Country
China
ProdList
4590
Advantage
58
Shandong Jiuyue Biological Technology Co., LTD
Tel
15553348166
Email
m15553348166@163.com
Country
China
ProdList
3468
Advantage
58
Shenzhen Xingkaiyue Biotechnology Co. , Ltd.
Tel
0755-18589069862 18589069862
Email
1158168052@qq.com
Country
China
ProdList
1000
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Henan yingchuang
Tel
0370-3678455 16650708709
Fax
qq:778660296
Email
hnyingchuang@163.com
Country
China
ProdList
3963
Advantage
58
Hubei SVETO New Material Technology Co., Ltd
Tel
13277095679
Fax
027-65662438
Email
1375175909@qq.com
Country
China
ProdList
610
Advantage
58
Wuhan ShuEr Biology Technology Co.,Ltd
Tel
15827133616 15827133616
Fax
QQ 1799696397
Email
1799696397@qq.com
Country
China
ProdList
2806
Advantage
58
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15848
Advantage
69
future industrial shanghai co., ltd
Tel
400-0066400 13621662912
Fax
021-55660885
Email
sales@jonln.com
Country
China
ProdList
1998
Advantage
65
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View Lastest Price from ε-Caprolactone manufacturers

Ouhuang Engineering Materials (Hubei) Co., Ltd
Product
6-Hexanolactone 502-44-3
Price
US $1.00/KG
Min. Order
1KG
Purity
99.91%
Supply Ability
200000
Release date
2024-04-25
Henan Fengda Chemical Co., Ltd
Product
ε-Caprolactone 502-44-3
Price
US $35.00-1.40/kg
Min. Order
1kg
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-03-27
Hebei Kingfiner Technology Development Co. , Ltd.
Product
ε-Caprolactone 502-44-3
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
200000
Release date
2024-03-21

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