ChemicalBook > CAS DataBase List > Benzyl 2-bromoethyl ether

Benzyl 2-bromoethyl ether

Product Name
Benzyl 2-bromoethyl ether
CAS No.
1462-37-9
Chemical Name
Benzyl 2-bromoethyl ether
Synonyms
Benzyloxyethyl Bromide;UMECLIDIUM intermediate;2-Bromoethylbenzyl ether;2- benzyloxy bromoethane;Benzyl 2-bromoethyl ethe;2-BENZYLOXY-1-BROMOETHANE;1-BENZYLOXY-2-BROMOETHANE;1-BROMO-2-BENZYLOXYETHANE;BENZYL 2-BROMOETHYL ETHER;bromoethyl-2-benzyl ether
CBNumber
CB1393800
Molecular Formula
C9H11BrO
Formula Weight
215.09
MOL File
1462-37-9.mol
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Benzyl 2-bromoethyl ether Property

Boiling point:
254 °C(lit.)
Density 
1.36 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.541(lit.)
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Slightly), Ethyl Acetate (Slightly)
form 
liquid
color 
colorless to yellow
Water Solubility 
Slightly soluble in water
InChI
InChI=1S/C9H11BrO/c10-6-7-11-8-9-4-2-1-3-5-9/h1-5H,6-8H2
InChIKey
FWOHDAGPWDEWIB-UHFFFAOYSA-N
SMILES
C1(COCCBr)=CC=CC=C1
CAS DataBase Reference
1462-37-9
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Safety

Hazard Codes 
Xn
Risk Statements 
22
Safety Statements 
24/25
RIDADR 
UN 3334
WGK Germany 
3
TSCA 
No
HS Code 
29093090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
474819
Product name
Benzyl 2-bromoethyl ether
Purity
97%
Packaging
1g
Price
$25.46
Updated
2025/07/31
Sigma-Aldrich
Product number
474819
Product name
Benzyl 2-bromoethyl ether
Purity
97%
Packaging
10g
Price
$245.1
Updated
2025/07/31
TCI Chemical
Product number
B2817
Product name
Benzyl 2-Bromoethyl Ether
Purity
>97.0%(GC)
Packaging
5g
Price
$34
Updated
2025/07/31
TCI Chemical
Product number
B2817
Product name
Benzyl 2-Bromoethyl Ether
Purity
>97.0%(GC)
Packaging
25g
Price
$134
Updated
2025/07/31
TRC
Product number
B684680
Product name
[(2-Bromoethyloxy)methyl]benzene
Packaging
5G
Price
$95
Updated
2021/12/16
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Benzyl 2-bromoethyl ether Chemical Properties,Usage,Production

Chemical Properties

Clear colorless to pale yellow liquid

Uses

Benzyl 2-broMoethyl ether is a reactant used in the preparation of muscarinic antagonist.

Uses

Alkylation reagent for synthesis of a macrocyclic antifungal antibiotic. Building block used to prepare a copper phthalocyanine discotic liquid crystal.

General Description

Benzyl 2-bromoethyl ether is an organic building block. Its enthalpy of vaporization at boiling point (527.15K) has been reported to be 46.499kjoule/mol.

Synthesis

622-08-2

1462-37-9

Step 2: To a stirred solution of 2-benzyloxyethanol (17.0 g, 111.884 mmol) and triphenylphosphine (35.0 g, 134.21 mmol) in dichloromethane (170 mL) was slowly added N-bromosuccinimide (23.88 g, 134.21 mmol) in batches at a temperature between -10°C and -5°C, keeping the reaction temperature at -10 °C to -5 °C. After the addition was completed, the reaction mixture was continued to be stirred at room temperature for 1 hour until complete consumption of the feedstock was confirmed by thin layer chromatography (TLC) analysis. Upon completion of the reaction, the mixture was concentrated and the crude product was purified by column chromatography (CC) using a petroleum ether solution of 5% ethyl acetate as eluent to afford benzyl 2-bromoethyl ether (13.5 g, 56.2% yield) as a light yellow liquid (TLC conditions: petroleum ether solution of 30% ethyl acetate; Rf value: 0.7).

References

Martin W. M. Fijten.; Claudia Haensch.; Bart M. van Lankvelt.; Richard Hoogenboom.; Ulrich S. Schubert. Clickable Poly(2-Oxazoline)s as Versatile Building Blocks. Macromolecular Chemistry and Physics. 2008, 209 (18),1887-1895. DOI:10.1002/MACP.200800226
Britt A. Minch.; Wei Xia.; Carrie L. Donley.; Ryan M. Hernandez.; Chet Carter.; Michael D. Carducci.; Alice Dawson.; David F. O'Brien.; Neal R. Armstrong. Octakis(2-benzyloxyethylsulfanyl) Copper (II) Phthalocyanine: A New Liquid Crystalline Discotic Material with Benzyl-Terminated, Thioether-Linked Side Chains. Chem. Mater.2005,17 (7),1618-1627. DOI:10.1021/CM0483745
Org. Lett. 5, 4049-4052, (2003) 2. Chem. Mater. 17, 1618, (2005)

Benzyl 2-bromoethyl ether Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Benzyl 2-bromoethyl ether manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
BENZYL 2-BROMOETHYL ETHER 1462-37-9
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-12-04
Henan Aochuang Chemical Co.,Ltd.
Product
2-Benzyloxy-1-bromoethane 1462-37-9
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-30
Hebei Yanxi Chemical Co., Ltd.
Product
Benzyl 2-bromoethyl ether 1462-37-9
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
100tons
Release date
2023-09-12

1462-37-9, Benzyl 2-bromoethyl etherRelated Search:

BENZYL 6-BROMOHEXYL ETHER BENZYL 5-BROMOPENTYL ETHER Benzyl 2-bromoethyl ether 2,3,4,6-TETRA-O-BENZOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE BROMUCONAZOLE TEREPHTHALIC ACID MONO(2-BROMOETHYL) ESTER 4-NITROBENZYL BROMOACETATE 2-Bromoethyl benzoate Benzyl 2-bromoacetate BENZOYL BROMIDE Bromoethane BENZYL 2,3-DIBROMOPROPANOATE 3,4-DIBROMO-5-PHENYL-2(5H)-FURANONE 2 3 5-TRI-O-BENZOYL-ALPHA-D-ARABINO-FURA (4S)-4-BROMOMETHYL-2-PHENYL-1,3-DIOXANE Benzyl 2,4-dibromobutanoate 7-BROMOMETHYL-5,9-DIHYDRO-6,8-DIOXA-BENZOCYCLOHEPTENE 5,6-DIBROMO-2-(2,4-DICHLOROPHENYL)-1,3-DIOXEPANE

  • BENZYL 2-BROMOETHYL ETHER
  • 1-BROMO-2-BENZYLOXYETHANE
  • 1-BENZYLOXY-2-BROMOETHANE
  • 2-BENZYLOXY-1-BROMOETHANE
  • Benzyl 2-bromoethyl ether, 97 % (GC)
  • (2-Bromoethoxymethyl)benzene
  • Benzyloxyethyl Bromide
  • Benzene, [(2-broMoethoxy)Methyl]-
  • (2-Bromoethoxymethyl)benzene Benzyloxyethyl Bromide
  • Benzyl 2-bromoethyl ether,97%
  • 2-(Benzyloxy)ethyl bromide
  • 2-Bromoethylbenzyl ether
  • [2-broMo-3-(2-broMo-3-phenylpropoxy)propyl]benzene
  • [(2-Bromoethyloxy)methyl]benzene
  • UMECLIDIUM intermediate
  • 1-((2-bromoethoxy)methyl)benzene
  • 1- bromine -2- benzyl oxide
  • Benzyl 2-bromoethyl ether 97%
  • Benzyl 2-bromoethyl ether Or 2-Benzyloxy-1-bromoethane
  • Benzyl2-BromoethylEther&gt
  • bromoethyl-2-benzyl ether
  • 2- benzyloxy bromoethane
  • Benzyl 2-bromoethyl ethe
  • 1462-37-9
  • C6H5CH2OCH2CH2Br
  • Building Blocks
  • Oxygen Compounds
  • Organic Building Blocks
  • Ethers
  • alkyl bromide
  • Building Blocks
  • C9
  • Chemical Synthesis
  • Organic Building Blocks
  • Oxygen Compounds
  • Protection & Derivatization Reagents (for Synthesis)
  • Synthetic Organic Chemistry
  • Ethers
  • Organic Building Blocks
  • Oxygen Compounds
  • 1462-37-9