ChemicalBook > CAS DataBase List > 4'-Bromo-3'-nitroacetophenone

4'-Bromo-3'-nitroacetophenone

Product Name
4'-Bromo-3'-nitroacetophenone
CAS No.
18640-58-9
Chemical Name
4'-Bromo-3'-nitroacetophenone
Synonyms
NSC 111656;4-BROMO-3-NITROACETOPHENONE;3-Nitro-4-bromoacetophenone;4-bromo-3'-nitroacetophenone;4'-Bromo-3'-nitroacetophenone;Acetophenone, 4'-bromo-3'-nitro-;1-(4-BROMO-3-NITROPHENYL)ETHANONE;4'-Bromo-3'-nitroacetophenone 97%;4'-Bromo-3'-nitroacetophenone >4'-Bromo-3'-nitroacetophenone, 99+%
CBNumber
CB1465910
Molecular Formula
C8H6BrNO3
Formula Weight
244.04
MOL File
18640-58-9.mol
More
Less

4'-Bromo-3'-nitroacetophenone Property

Melting point:
117-121 °C(lit.)
Boiling point:
275.4℃
Density 
1.637
refractive index 
1.6090 (estimate)
Flash point:
120.4℃
storage temp. 
Sealed in dry,Room Temperature
form 
Amorphous Powder
color 
White to slightly yellow
BRN 
2050098
InChI
InChI=1S/C8H6BrNO3/c1-5(11)6-2-3-7(9)8(4-6)10(12)13/h2-4H,1H3
InChIKey
YFVOFFKNHQTQQE-UHFFFAOYSA-N
SMILES
C(=O)(C1=CC=C(Br)C([N+]([O-])=O)=C1)C
CAS DataBase Reference
18640-58-9(CAS DataBase Reference)
More
Less

Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22
Safety Statements 
24/25
WGK Germany 
3
HS Code 
29147000
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
553662
Product name
4′-Bromo-3′-nitroacetophenone
Purity
97%
Packaging
5g
Price
$50
Updated
2023/06/20
TCI Chemical
Product number
B3383
Product name
4'-Bromo-3'-nitroacetophenone
Purity
>98.0%(GC)
Packaging
1g
Price
$30
Updated
2024/03/01
TCI Chemical
Product number
B3383
Product name
4'-Bromo-3'-nitroacetophenone
Purity
>98.0%(GC)
Packaging
5g
Price
$90
Updated
2024/03/01
Alfa Aesar
Product number
B24469
Product name
4'-Bromo-3'-nitroacetophenone, 99%
Packaging
5g
Price
$65.65
Updated
2024/03/01
Alfa Aesar
Product number
B24469
Product name
4'-Bromo-3'-nitroacetophenone, 99%
Packaging
25g
Price
$210.65
Updated
2024/03/01
More
Less

4'-Bromo-3'-nitroacetophenone Chemical Properties,Usage,Production

Chemical Properties

white to slightly yellow amorphous powder

General Description

4′-Bromo-3′-nitroacetophenone is an electron deficient acetophenone derivative.

Synthesis

4'-Bromo-3'-nitroacetophenone is synthesised using 4'-Bromoacetophenone as a raw material by chemical reaction. The specific synthesis steps are as follows:
To fuming nitric acid (200 mL), l-(4- bromophenyl)-l-propanone (1-1) (40 g, 0.20 mol) was added while keeping the inside temperature of mixture at 5 to 10 0C. The reaction solution was stirred at this temperature for 30 minutes and then poured into ice. The precipitate was collected by filtration, washed with distilled water (25 mL x 2) and re-crystallized from methanol to give 1-2 (18 g, 37percent yield). 1H NMR (500 MHz, CDCl3) δ 8.38 (IH, d, J= 2.0 Hz), 7.99 (IH, dd, J= 8.2 Hz, 2.0 Hz), 7.86 (IH, d, J= 8.2Hz), 3.01 (2H, q, J= 7.1Hz), 1.25 (3H, t, J= 7.1Hz) ppm; LC-MS (ESI): m/z 244.0 (M+H)+.

4'-Bromo-3'-nitroacetophenone Preparation Products And Raw materials

Raw materials

Preparation Products

4-Acetyl-2-fluorobiphenyl 1-(2-amino[1,1'-biphenyl]-4-yl)ethan-1-one 1-(2-NITRO-BIPHENYL-4-YL)-ETHANONE
More
Less

4'-Bromo-3'-nitroacetophenone Suppliers

Americas 1 Belgium 3 China 106 Europe 3 France 1 Germany 4 India 35 Japan 3 Slovakia 1 Switzerland 2 United Kingdom 11 United States 28 Global 198
Lianyungang City and Rui Technology Co., Ltd.
Tel
015162260526; 15162260526
Fax
051885593298
Email
sales@henrychem.com
Country
China
ProdList
300
Advantage
58
Haimen DsHare Pharmaceutical Technology Co., Ltd.
Tel
+86-0513-68050136 13962878782
Fax
0513-68050130
Email
zhuwdsh@126.com
Country
China
ProdList
157
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44733
Advantage
61
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12984
Advantage
57
Tianjin Jinyuda Chemical Co., Ltd.
Tel
022-58013646 13011382049
Fax
022-23854368
Email
sales@jinyudachem.com
Country
China
ProdList
1889
Advantage
55
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17770
Advantage
75
Shanghai Topbiochem Technology Co., Ltd
Tel
021-58170097
Email
info@topbiochem.com
Country
China
ProdList
9484
Advantage
58
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66099280 17798518460
Fax
(1)02557626880
Email
cfzhang@aikonchem.com
Country
China
ProdList
19915
Advantage
55
9ding chemical ( Shanghai) Limited
Tel
4009209199
Fax
86-021-52271987
Email
sales@9dingchem.com
Country
China
ProdList
18209
Advantage
56
Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
400-6206333 1316706386
Fax
021-50323701
Email
anhua.mao@aladdin-e.com
Country
China
ProdList
25003
Advantage
65
Suli Pharmaceutical Technology Co., Ltd.
Tel
021-58086325-8060 13636568474
Fax
021-51972827
Email
yingjie.zhang@suli.com
Country
China
ProdList
110
Advantage
58
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
41457
Advantage
60
Shanghai Xingui Biotechnology Co., Ltd.
Tel
17501653713
Email
xingui2022@126.com
Country
China
ProdList
9986
Advantage
58
Shanghai HuanChuan Industry Co.,Ltd.
Tel
021-61478794
Fax
021-61478794
Email
sales@hcshhai.com
Country
China
ProdList
9793
Advantage
50
Shanghai Na Qian Chemical Technology Co. Ltd.
Tel
0373-7129549; 13598610367
Fax
QQ:2468833170
Email
2841375912@qq.com
Country
China
ProdList
2728
Advantage
52
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51456
Advantage
80
Giant chemicals
Tel
028-85434334 18108076537
Fax
QQ：245797092
Email
market@gianthx.com
Country
China
ProdList
4505
Advantage
56
Henan CoreyChem Co., Ltd
Tel
0371-86658258
Fax
0371-60996044
Email
info@coreychem.com
Country
China
ProdList
10453
Advantage
58
Nanjing XiLang Chemical Products Co., Ltd.
Tel
18936048580
Email
chemxilang@163.com
Country
China
ProdList
3960
Advantage
58
Shanghai QianYan Bio-technology Co., Ltd
Tel
02781293128
Email
orders@biochemsafebuy.com
Country
China
ProdList
9923
Advantage
55
Chengdu Dianchun Technology Co., Ltd
Tel
400-1166-196 18502815961
Fax
QQ：800101999
Email
cdhxsj@163.com
Country
China
ProdList
14603
Advantage
60
Amadis Chemical Company Limited
Tel
571-89925085
Fax
0086-571-89925065
Email
sales@amadischem.com
Country
China
ProdList
131957
Advantage
58
Zhengzhou Huiju Chemical Co., Ltd.
Tel
0371-55900031 18137872243
Fax
QQ：2853979815
Email
2853979815@qq.com
Country
China
ProdList
9994
Advantage
55
Dalian lichuang Chemical Co., Ltd
Tel
0411-0411-00000000 13644282108
Fax
-
Email
3500508746@qq.com
Country
China
ProdList
2791
Advantage
55
9ding chemical ( Shanghai) Limited
Tel
021-021-52271985 17721149837
Fax
+86 (21) 52271987
Email
sales@9dingchem.com
Country
China
ProdList
19800
Advantage
60
LinkChem Co.,Ltd.
Tel
021-021-58950110 13124863828
Fax
021-20922272
Email
sales@linkchem.cn
Country
China
ProdList
3001
Advantage
58
Shanghai BaiShun Biological Technology Co., Ltd
Tel
021-37581181
Fax
021-57456066
Email
sales@chem-mall.com
Country
China
ProdList
10330
Advantage
58
Shanghai QiQiao Biological Technology Co., Ltd.
Tel
021-37653318; 15221675714
Email
515366396@qq.com
Country
China
ProdList
2089
Advantage
58
SHANGHAI FDC-CHEMICAL CO.,LTD
Tel
021-61469567 13482353728
Fax
021-61161605
Email
sales@fdc-chemical.com
Country
China
ProdList
15368
Advantage
58
Shanghai Haohong Pharmaceutical Co., Ltd.
Tel
400-8210725 18016230971
Fax
021-58955996
Email
malulu@leyan.com
Country
China
ProdList
24973
Advantage
58
Zhengzhou Ruke Biological Co., Ltd.
Tel
15981811963
Fax
QQ：1410472904
Email
1410472904@qq.com
Country
China
ProdList
5825
Advantage
58
Tianjin heowns Biochemical Technology Co., Ltd.
Tel
400-6387771-6039 18920564737
Email
sales@heowns.com
Country
China
ProdList
23388
Advantage
60
Zhengzhou Acme Chemical Co., Ltd.
Tel
0371-037163312495,13303845143 13303845143
Fax
QQ3001379618
Email
3001379618@qq.com
Country
China
ProdList
10354
Advantage
58
yxinchem
Tel
+86-0710-4323688 +86-18071785587
Fax
15502706050
Email
market@yxinchem.com
Country
China
ProdList
1022
Advantage
58
Cool Pharm, Ltd
Tel
18019463053
Fax
021-50966098
Email
sales@coolpharm.com
Country
China
ProdList
13010
Advantage
58
Shanghai zhigan biotechnology co., LTD
Tel
Email
zhiqianbio@126.com
Country
China
ProdList
19778
Advantage
58
Hangzhou Xinbaisi Biomedical Co., Ltd.
Tel
13325818654
Fax
057188737015
Email
sales@synbestech.com
Country
China
ProdList
240
Advantage
58
Xinyi Kaiwu Chemical Technology Co., Ltd.
Tel
0516-0516-88997009 18651776937
Email
4164357@qq.com
Country
China
ProdList
3223
Advantage
58
Hefei TNJ Chemical Industry Co.,Ltd.
Tel
+86-0551-65418671 +8618949823763
Fax
0551-65418697
Email
sales@tnjchem.com
Country
China
ProdList
34563
Advantage
58
Labnetwork lnc.
Tel
+86-27-50766799 +8618062016861
Email
contact@labnetwork.com
Country
China
ProdList
19987
Advantage
58
sgtlifesciences pvt ltd
Tel
+8617013299288
Email
dj@sgtlifesciences.com
Country
China
ProdList
12373
Advantage
58
CD Chemical Group Limited
Tel
+8615986615575
Fax
0086-13651442114
Email
info@codchem.com
Country
China
ProdList
20342
Advantage
58
Shaanxi Dideu Medichem Co. Ltd
Tel
+86-029-89586680 +86-18192503167
Fax
+86-29-88380327
Email
1026@dideu.com
Country
China
ProdList
7722
Advantage
58
Blocksynth Pharmaceutical Technology Co.,Ltd
Tel
0086-19817745290; +8619817745290
Email
bd@blocksynth.com
Country
China
ProdList
5660
Advantage
58
HUNAN CHEMFISH SCIENTIFIC CO.,LTD
Tel
+86-0731-85567275 18932438858
Fax
QQ:3554193828
Email
sales05@chemfish.com
Country
China
ProdList
6548
Advantage
58
Changzhou Luowan Biological Technology Co., Ltd.
Tel
13646143635
Email
617837247@qq.com
Country
China
ProdList
144
Advantage
58
More
Less

View Lastest Price from 4'-Bromo-3'-nitroacetophenone manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
4′-Bromo-3′-nitroacetophenone 18640-58-9
Price
US $0.00-0.00/KG
Min. Order
100g
Purity
99.0%+
Supply Ability
100 tons
Release date
2020-01-19
Career Henan Chemical Co
Product
4'-BROMO-3'-NITROACETOPHENONE 18640-58-9
Price
US $7.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-02-13

18640-58-9, 4'-Bromo-3'-nitroacetophenoneRelated Search:

4'-Fluoro-3'-nitroacetophenone 4'-Bromoacetophenone 3-Nitrophenacylbromide 2-Bromo-4'-nitroacetophenone 2-BROMO-2'-NITROACETOPHENONE,-Bromo-2'-Nitroacetophenone 4'-BROMO-3'-NITROACETOPHENONE 3-nitro-4-bromopropiophenone 2-BROMO-5-NITROACETOPHENONE 5'-Bromo-2'-nitroacetophenone 3'-Bromo-4'-nitroacetophenone 4-BROMO-3'-NITROBENZOPHENONE A-BROMO-4-NITROACETOPHENONE HEXAMINE,α-Bromo-4-nitroacetophenone hexamine 2-Fluoro-3-Bromio-5-Nitro acetophenone Α-BROMO-P-NITROACETOPHENONE 2'-Bromo-α-nitroacetophenone 2-bromo-1-(4-bromo-3-nitrophenyl)ethanone 3-(4-bromo-3-nitrophenyl)-3-oxopropanenitrile 4-BROMO-3,5-DINITROBENZOPHENONE

  • 4-BROMO-3-NITROACETOPHENONE
  • 1-(4-BROMO-3-NITROPHENYL)ETHAN-1-ONE
  • 1-(4-BROMO-3-NITROPHENYL)ETHANONE
  • 3-Nitro-4-bromoacetophenone
  • NSC 111656
  • 4'-Bromo-3'-nitroacetophenone 97%
  • Acetophenone, 4'-bromo-3'-nitro-
  • Ethanone, 1-(4-bromo-3-nitrophenyl)-
  • 4'-Bromo-3'-nitroacetophenone, 99+%
  • 4'-bromo-3'-nitroacetophenone,1-(4-bromo-3-nitrophenyl)ethanone
  • JRH-08504, 1-(4-Bromo-3-nitrophenyl)ethanone, 97%
  • 2,4,6-trichloro-N-[(diphenylmethylene)amino]aniline
  • 4'-Bromo-3'-nitroacetophenone &gt
  • 4'-BROMO-3'-NITROACETOPHENONE USP/EP/BP
  • 4'-Bromo-3'-nitroacetophenone
  • 4-bromo-3'-nitroacetophenone
  • 18640-58-9
  • 18640-59-9
  • BrC6H3NO2COCH3
  • Organic Building Blocks
  • Ketones
  • C7 to C8
  • Carbonyl Compounds
  • Building Blocks
  • C7 to C8
  • Carbonyl Compounds
  • Ketones
  • Aromatic Ketones (substituted)