ChemicalBook > CAS DataBase List > 1-(5-Bromo-2-nitro-phenyl)-ethanone

1-(5-Bromo-2-nitro-phenyl)-ethanone

Product Name
1-(5-Bromo-2-nitro-phenyl)-ethanone
CAS No.
41877-24-1
Chemical Name
1-(5-Bromo-2-nitro-phenyl)-ethanone
Synonyms
1-(5-Bromo-2-nitrophenyl)ethan-1-one;1-(5-Bromo-2-nitrophenyl);5'-Bromo-2'-nitroacetophenone;1-(5-Bromo-2-nitro-phenyl)-ethano;1-(5-Bromo-2-nitro-phenyl)-ethanone;Ethanone, 1-(5-bromo-2-nitrophenyl)-;5-BroMo-2-nitroacetophenone (1-(5-broMo-2-nitrophenyl)-ethanone)
CBNumber
CB72103913
Molecular Formula
C8H6BrNO3
Formula Weight
244.04
MOL File
41877-24-1.mol
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1-(5-Bromo-2-nitro-phenyl)-ethanone Property

Melting point:
92-94 °C
Boiling point:
345.6±27.0 °C(Predicted)
Density 
1.637±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
Appearance
Off-white to yellow Solid
InChI
InChI=1S/C8H6BrNO3/c1-5(11)7-4-6(9)2-3-8(7)10(12)13/h2-4H,1H3
InChIKey
AFDAUYYWZNNSFV-UHFFFAOYSA-N
SMILES
C(=O)(C1=CC(Br)=CC=C1[N+]([O-])=O)C
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Safety

HS Code 
2914790090
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC
Product number
B686603
Product name
1-(5-Bromo-2-nitrophenyl)ethanone
Packaging
50mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
J50896
Product name
1-(5-Bromo-2-nitrophenyl)ethanone
Packaging
1g
Price
$49
Updated
2021/12/16
SynQuest Laboratories
Product number
4654-9-08
Product name
1-(5-Bromo-2-nitrophenyl)ethan-1-one
Purity
98.0%
Packaging
250mg
Price
$50
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB32876
Product name
1-(5-Bromo-2-nitrophenyl)ethanone
Packaging
250mg
Price
$60
Updated
2021/12/16
AK Scientific
Product number
W6201
Product name
1-(5-Bromo-2-nitrophenyl)ethanone
Packaging
1g
Price
$67
Updated
2021/12/16
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1-(5-Bromo-2-nitro-phenyl)-ethanone Chemical Properties,Usage,Production

Synthesis

2142-63-4

41877-24-1

General procedure for the synthesis of 1-(5-bromo-2-nitrophenyl)ethanone from 3'-bromoacetophenone: 100 g of 3'-bromoacetophenone was slowly added dropwise to 500 ml of a mixture of sulfuric acid and nitric acid (1:7, v/v), pre-cooled to -20°C, kept the reaction temperature at -20°C and stirred overnight. Upon completion of the reaction, the reaction mixture was quenched by pouring it into ice water, and the precipitate was collected by filtration to give 107 g of 2-nitro-5-bromoacetophenone, the product was a yellow solid in 87% yield.

References

[1] Patent: CN102898374, 2016, B. Location in patent: Paragraph 0027-0029
[2] Chemical Communications, 2015, vol. 52, # 2, p. 331 - 334
[3] Bioorganic and Medicinal Chemistry, 2016, vol. 24, # 11, p. 2504 - 2518
[4] Journal of the American Chemical Society, 1996, vol. 118, # 34, p. 8127 - 8135

1-(5-Bromo-2-nitro-phenyl)-ethanone Preparation Products And Raw materials

Raw materials

Preparation Products

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1-(5-Bromo-2-nitro-phenyl)-ethanone Suppliers

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41877-24-1, 1-(5-Bromo-2-nitro-phenyl)-ethanoneRelated Search:


  • 1-(5-Bromo-2-nitro-phenyl)-ethanone
  • 5'-Bromo-2'-nitroacetophenone
  • 5-BroMo-2-nitroacetophenone (1-(5-broMo-2-nitrophenyl)-ethanone)
  • 1-(5-Bromo-2-nitrophenyl)ethan-1-one
  • 1-(5-Bromo-2-nitrophenyl)
  • Ethanone, 1-(5-bromo-2-nitrophenyl)-
  • 1-(5-Bromo-2-nitro-phenyl)-ethano
  • 41877-24-1