3-Bromobenzyl alcohol
- Product Name
- 3-Bromobenzyl alcohol
- CAS No.
- 15852-73-0
- Chemical Name
- 3-Bromobenzyl alcohol
- Synonyms
- (3-Bromophenyl)methanol;RARECHEM AL BD 0052;M-BROMOBENZYL ALCOHOL;3-BROMOBENZYL ALCOHOL;3-Bromobenzenemethanol;Benzenemethanol, 3-bromo-;3-Bromobenzyl alcohol,99%;3-Bromobenzyl alcohol 98%;3-Bromobenzyl Alcohol >3-BroMobenzyl Alcohol, 97+%
- CBNumber
- CB1466508
- Molecular Formula
- C7H7BrO
- Formula Weight
- 187.03
- MOL File
- 15852-73-0.mol
3-Bromobenzyl alcohol Property
- Melting point:
- 110-112
- Boiling point:
- 165 °C16 mm Hg(lit.)
- Density
- 1.56 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.584(lit.)
- Flash point:
- >230 °F
- storage temp.
- Sealed in dry,Room Temperature
- Water Solubility
- Slightly soluble in water
- form
- clear liquid
- pka
- 14.28±0.10(Predicted)
- color
- Colorless to Light yellow to Light orange
- Specific Gravity
- 1.560
- BRN
- 2242512
- InChI
- InChI=1S/C7H7BrO/c8-7-3-1-2-6(4-7)5-9/h1-4,9H,5H2
- InChIKey
- FSWNRRSWFBXQCL-UHFFFAOYSA-N
- SMILES
- C1(CO)=CC=CC(Br)=C1
- CAS DataBase Reference
- 15852-73-0(CAS DataBase Reference)
- NIST Chemistry Reference
- 3-Bromobenzyl alcohol(15852-73-0)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 187895
- Product name
- 3-Bromobenzyl alcohol
- Purity
- 99%
- Packaging
- 5g
- Price
- $57.6
- Updated
- 2023/01/07
- Product number
- B1287
- Product name
- 3-Bromobenzyl Alcohol
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $33
- Updated
- 2025/07/31
- Product number
- B1287
- Product name
- 3-Bromobenzyl Alcohol
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $99
- Updated
- 2025/07/31
- Product number
- B680458
- Product name
- 3-Bromobenzyl alcohol
- Packaging
- 5g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- L493
- Product name
- 3-Bromobenzyl alcohol
- Packaging
- 5g
- Price
- $14
- Updated
- 2021/12/16
3-Bromobenzyl alcohol Chemical Properties,Usage,Production
Chemical Properties
CLEAR COLOURLESS TO LIGHT YELLOW LIQUID
Uses
3-Bromobenzyl alcohol was employed in the preparation of tert-butyl 3-(3-bromophenyl)-2-cyanopropanoate and silyl ether.
Synthesis Reference(s)
Synthetic Communications, 19, p. 1217, 1989 DOI: 10.1080/00397918908054526
Synthesis
3132-99-8
15852-73-0
Example 49: Synthesis of (3-bromophenyl)methanol Sodium borohydride (7.1 g, 186.1 mmol) was added in one batch to a solution of 3-bromobenzaldehyde (114.8 g, 620.4 mmol) in ethanol (650 mL) at 25 °C. The reaction mixture was stirred at room temperature for 1 hour. Upon completion of the reaction, the reaction was quenched with water (200 mL). After ethanol was removed by distillation under reduced pressure, the residue was dissolved in ethyl acetate (500 mL) and filtered. The filtrate was washed sequentially with water (150 mL) and brine (150 mL) and then dried over anhydrous sodium sulfate. After concentration under reduced pressure to remove the solvent, 115.8 g of 3-bromobenzyl alcohol was obtained in 99.8% yield.
References
[1] Patent: US2009/203657, 2009, A1. Location in patent: Page/Page column 54
[2] Patent: US2009/203677, 2009, A1. Location in patent: Page/Page column 57; 58
[3] Patent: US2009/197871, 2009, A1. Location in patent: Page/Page column 57
[4] Patent: WO2009/100169, 2009, A1. Location in patent: Page/Page column 138
[5] European Journal of Medicinal Chemistry, 2016, vol. 108, p. 564 - 576
3-Bromobenzyl alcohol Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 3-Bromobenzyl alcohol manufacturers
- Product
- 3-Bromobenzyl alcohol 15852-73-0
- Price
- US $6.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 2000KG/Month
- Release date
- 2024-08-05
- Product
- 3-Bromobenzyl alcohol 15852-73-0
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2024-10-28
- Product
- 3-Bromobenzyl alcohol 15852-73-0
- Price
- US $7.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20TONS
- Release date
- 2024-05-24