(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE

Product Name: (S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE
CAS No.: 132873-57-5
Chemical Name: (S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE
Synonyms: (S)-NITRESOLVE;(S)-(+)-1-(4-NITROPHENYL)-ETHYLAMINE HCL;(S)-alpha-methyl-4-nitrobenzenemethanamine;(S)-(+)-ALPHA-METHYL-4-NITROBENZYLAMINE HCL;(S)-α-Methyl-4-nitrobenzylamineHydrochloride;(S)-4-NITROPHENYL-1-ETHYLAMINE HYDROCHLORIDE;1-(S)-4-Nitrophenyl ethylamine hydrochloride;(S)-4-Nitro-α-methylbenzylamine hydrochloride;(S)-1-(4-Nitrophenyl)ethanaMine hydrochloride;(S)-α-Methyl-4-nitrobenzylamine Hydrochloride
CBNumber: CB1467176
Molecular Formula: C8H11ClN2O2
Formula Weight: 202.64
MOL File: 132873-57-5.mol

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(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE Property

Melting point:: 248-250 °C(lit.)
refractive index: -7.2 ° (C=1, 0.05mol/L NaOH)
storage temp.: Inert atmosphere,Room Temperature
form: powder to crystal
color: White to Light yellow
optical activity: [α]25/D 6.5°, c = 1 in 0.05 M NaOH
Water Solubility: faint turbidity
CAS DataBase Reference: 132873-57-5(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-37/39
WGK Germany: 3
F: 3-10
HS Code: 29214990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 339822
Product name: (S)-α-Methyl-4-nitrobenzylamine hydrochloride
Purity: 97%
Packaging: 1g
Price: $49.6
Updated: 2024/03/01

TCI Chemical

Product number: N0543
Product name: (S)-alpha-Methyl-4-nitrobenzylamine Hydrochloride
Purity: >99.0%(T)
Packaging: 1g
Price: $57
Updated: 2024/03/01

TRC

Product number: N545280
Product name: (S)-1-(4-Nitrophenyl)ethanamineHydrochloride
Packaging: 50mg
Price: $60
Updated: 2021/12/16

Chem-Impex

Product number: 37513
Product name: (S)-α-Methyl-4-nitrobenzylaminehydrochloride,99%(T)
Purity: 99%(T)
Packaging: 1G
Price: $60.48
Updated: 2021/12/16

ChemScene

Product number: CS-M0682
Product name: (S)-1-(4-nitrophenyl)ethanamineHydrochloride
Purity: >99.0%
Packaging: 25g
Price: $110
Updated: 2021/12/16

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(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE Chemical Properties,Usage,Production

Uses

(S)-α-Methyl-4-nitrobenzylamine hydrochloride can be used as:

A fluorescence-quenching guest in the determination of chiral recognition capabilities of binaphthocrown ether and polythiophene complex.
A starting material in the synthesis of chiral cyclopalladated complexes with applications in the resolution of racemic compounds.

Purification Methods

To ensure dryness, the hydrochloride (ca 175 g) is extracted with EtOH (3x100mL) and evaporated to dryness (any residual H2O increases the solubility in EtOH and lowers the yield). The hydrochloride residue is triturated with absolute EtOH and dried in vacuo. The product is further purified by refluxing with absolute EtOH (200 mL for 83g) for 1hour, and cool to 10o to give 76.6g of hydrochloride m 243-245o(dec). The free base is prepared by dissolving in N NaOH, extracting with CH2Cl2 (3 x 500mL), drying (Na2CO3), filtering, evaporating and distilling it. It has m 27o, b 119-120o/0.5mm (105-107o/0.5mm, 157-159o/9mm, d 1.1764, n 1.5688, [] ±17.7o (neat) [Perry et al. Synthesis 492 1977,ORD: Nerdel & Liebig Justus Liebigs Ann Chem 621 142 1959]. [Beilstein 12 IV 2451.]

(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE Suppliers

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View Lastest Price from (S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE manufacturers

Career Henan Chemical Co

Product: (S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE 132873-57-5
Price: US $1.00/g
Min. Order: 1g
Purity: 99%
Supply Ability: 200kg
Release date: 2020-01-14

Career Henan Chemical Co

Product: (S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE 132873-57-5
Price: US $1.00/g
Min. Order: 1g
Purity: 99%
Supply Ability: 200kg
Release date: 2020-01-14

132873-57-5, (S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDERelated Search:

Ammonium sulfate Ethylamine hydrochloride (R)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE S-(-)-a-Methyl-p-aminobenzylamine (S)-1-(4-NITROPHENYL)-ETHYLAMINE 4-Nitrobenzylamine hydrochloride ALFA-ALFA-DIMETHYL-P-NITRO-BENZYLAMINE HYDROCHLORIDE 4-(1-AMINO-ETHYL)-PHENYLAMINE (S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE (1R,2R)-(+)-1,2-Bis(4-nitrophenyl)ethylenediaminedihydrochloride,min.98%

(S)-(+)-1-(4-NITROPHENYL)-ETHYLAMINE HCL

(S)-1-(4-NITROPHENYL)-METHYLAMIN HYDROCHLORIDE

(S)-4-NITROPHENYL-1-ETHYLAMINE HYDROCHLORIDE

(S)-NITRESOLVE

(S)-(+)-ALPHA-METHYL-4-NITROBENZYLAMINE HCL

(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE

(S)-ALPHA-METHYL-4-NITROBENZYLAMMONIUM CHLORIDE

(S)-(+)-ALPHA-METHYL-P-NITROBENZYLAMINE HYDROCHLORIDE

(S)-(-)-A-METHYL 4-NITROBENZYLAMINE HYDROCHLORIDE

(S)-α-Methyl-4-nitrobenzylamineHydrochloride

(S)-4-Nitro-α-methylbenzylamine hydrochloride

(S)-(+)-α-Methyl-p-nitrobenzylamine Hydrochloride

(S)-alpha-methyl-4-nitrobenzenemethanamine

(s)-alpha-Methyl-4-nitroitrobenzylaMine Hydrochloride

(S)-1-(4-Nitrophenyl)ethanaMine hydrochloride

(S)-Nitresolve (S)-1-(4-Nitrophenyl)ethylamine Hydrochloride

(S)-alpha-Methyl-4-nitrobenzeneMethanaMine HCL

(S)-alpha-Methyl-4-nitrobenzylamine hydrochloride 97%

1-(S)-4-Nitrophenyl ethylamine hydrochloride

(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE 99+%

(S)-α-Methyl-4-nitrobenzylamineHydrochloride&gt

Benzenemethanamine, α-methyl-4-nitro-, hydrochloride (1:1), (αS)-

(S)-α-Methyl-4-nitrobenzylamine Hydrochloride

132873-57-5

O2NC6H4CHCH3NH2HCl

Asymmetric Synthesis

Chiral Resolution Reagents

Optical Resolution

for Resolution of Acids

Chiral Resolving Reagents

chiral

for Resolution of Acids

Optical Resolution

Synthetic Organic Chemistry

1