ChemicalBook > CAS DataBase List > (S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE

(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE

Product Name
(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE
CAS No.
132873-57-5
Chemical Name
(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE
Synonyms
(S)-NITRESOLVE;(S)-(+)-1-(4-NITROPHENYL)-ETHYLAMINE HCL;(S)-alpha-methyl-4-nitrobenzenemethanamine;(S)-(+)-ALPHA-METHYL-4-NITROBENZYLAMINE HCL;(S)-α-Methyl-4-nitrobenzylamineHydrochloride;(S)-4-NITROPHENYL-1-ETHYLAMINE HYDROCHLORIDE;1-(S)-4-Nitrophenyl ethylamine hydrochloride;(S)-4-Nitro-α-methylbenzylamine hydrochloride;(S)-1-(4-Nitrophenyl)ethanaMine hydrochloride;(S)-α-Methyl-4-nitrobenzylamine Hydrochloride
CBNumber
CB1467176
Molecular Formula
C8H11ClN2O2
Formula Weight
202.64
MOL File
132873-57-5.mol
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(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE Property

Melting point:
248-250 °C(lit.)
refractive index 
-7.2 ° (C=1, 0.05mol/L NaOH)
storage temp. 
Inert atmosphere,Room Temperature
form 
powder to crystal
color 
White to Light yellow
optical activity
[α]25/D 6.5°, c = 1 in 0.05 M NaOH
Water Solubility 
faint turbidity
CAS DataBase Reference
132873-57-5(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
3-10
HS Code 
29214990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
339822
Product name
(S)-α-Methyl-4-nitrobenzylamine hydrochloride
Purity
97%
Packaging
1g
Price
$49.6
Updated
2024/03/01
TCI Chemical
Product number
N0543
Product name
(S)-alpha-Methyl-4-nitrobenzylamine Hydrochloride
Purity
>99.0%(T)
Packaging
1g
Price
$57
Updated
2024/03/01
TRC
Product number
N545280
Product name
(S)-1-(4-Nitrophenyl)ethanamineHydrochloride
Packaging
50mg
Price
$60
Updated
2021/12/16
Chem-Impex
Product number
37513
Product name
(S)-α-Methyl-4-nitrobenzylaminehydrochloride,99%(T)
Purity
99%(T)
Packaging
1G
Price
$60.48
Updated
2021/12/16
ChemScene
Product number
CS-M0682
Product name
(S)-1-(4-nitrophenyl)ethanamineHydrochloride
Purity
>99.0%
Packaging
25g
Price
$110
Updated
2021/12/16
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(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE Chemical Properties,Usage,Production

Uses

(S)-α-Methyl-4-nitrobenzylamine hydrochloride can be used as:

  • A fluorescence-quenching guest in the determination of chiral recognition capabilities of binaphthocrown ether and polythiophene complex.
  • A starting material in the synthesis of chiral cyclopalladated complexes with applications in the resolution of racemic compounds.

Purification Methods

To ensure dryness, the hydrochloride (ca 175 g) is extracted with EtOH (3x100mL) and evaporated to dryness (any residual H2O increases the solubility in EtOH and lowers the yield). The hydrochloride residue is triturated with absolute EtOH and dried in vacuo. The product is further purified by refluxing with absolute EtOH (200 mL for 83g) for 1hour, and cool to 10o to give 76.6g of hydrochloride m 243-245o(dec). The free base is prepared by dissolving in N NaOH, extracting with CH2Cl2 (3 x 500mL), drying (Na2CO3), filtering, evaporating and distilling it. It has m 27o, b 119-120o/0.5mm (105-107o/0.5mm, 157-159o/9mm, d 1.1764, n 1.5688, [] ±17.7o (neat) [Perry et al. Synthesis 492 1977,ORD: Nerdel & Liebig Justus Liebigs Ann Chem 621 142 1959]. [Beilstein 12 IV 2451.]

(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE Suppliers

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View Lastest Price from (S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE manufacturers

Career Henan Chemical Co
Product
(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE 132873-57-5
Price
US $1.00/g
Min. Order
1g
Purity
99%
Supply Ability
200kg
Release date
2020-01-14
Career Henan Chemical Co
Product
(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE 132873-57-5
Price
US $1.00/g
Min. Order
1g
Purity
99%
Supply Ability
200kg
Release date
2020-01-14

132873-57-5, (S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDERelated Search:


  • (S)-(+)-1-(4-NITROPHENYL)-ETHYLAMINE HCL
  • (S)-1-(4-NITROPHENYL)-METHYLAMIN HYDROCHLORIDE
  • (S)-4-NITROPHENYL-1-ETHYLAMINE HYDROCHLORIDE
  • (S)-NITRESOLVE
  • (S)-(+)-ALPHA-METHYL-4-NITROBENZYLAMINE HCL
  • (S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE
  • (S)-ALPHA-METHYL-4-NITROBENZYLAMMONIUM CHLORIDE
  • (S)-(+)-ALPHA-METHYL-P-NITROBENZYLAMINE HYDROCHLORIDE
  • (S)-(-)-A-METHYL 4-NITROBENZYLAMINE HYDROCHLORIDE
  • (S)-α-Methyl-4-nitrobenzylamineHydrochloride
  • (S)-4-Nitro-α-methylbenzylamine hydrochloride
  • (S)-(+)-α-Methyl-p-nitrobenzylamine Hydrochloride
  • (S)-alpha-methyl-4-nitrobenzenemethanamine
  • (s)-alpha-Methyl-4-nitroitrobenzylaMine Hydrochloride
  • (S)-1-(4-Nitrophenyl)ethanaMine hydrochloride
  • (S)-Nitresolve (S)-1-(4-Nitrophenyl)ethylamine Hydrochloride
  • (S)-alpha-Methyl-4-nitrobenzeneMethanaMine HCL
  • (S)-alpha-Methyl-4-nitrobenzylamine hydrochloride 97%
  • 1-(S)-4-Nitrophenyl ethylamine hydrochloride
  • (S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE 99+%
  • (S)-α-Methyl-4-nitrobenzylamineHydrochloride&gt
  • Benzenemethanamine, α-methyl-4-nitro-, hydrochloride (1:1), (αS)-
  • (S)-α-Methyl-4-nitrobenzylamine Hydrochloride
  • 132873-57-5
  • O2NC6H4CHCH3NH2HCl
  • Asymmetric Synthesis
  • Chiral Resolution Reagents
  • Optical Resolution
  • for Resolution of Acids
  • Chiral Resolving Reagents
  • chiral
  • for Resolution of Acids
  • Optical Resolution
  • Synthetic Organic Chemistry
  • 1