4-Formylphenylboronic acid

Product Name: 4-Formylphenylboronic acid
CAS No.: 87199-17-5
Chemical Name: 4-Formylphenylboronic acid
Synonyms: FPBA;4-FORMYLBENZENEBORONIC ACID;AKOS BRN-0111;TIMTEC-BB SBB004077;RARECHEM AH PB 0193;4-Formylboronic acid;4-BORONOBENZALDEHYDE;4-Formylphenylboroni;Metoprolol Impurity 34;Formylphenylboronic acid
CBNumber: CB1491072
Molecular Formula: C7H7BO3
Formula Weight: 149.94
MOL File: 87199-17-5.mol

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4-Formylphenylboronic acid Property

Melting point:: 237-242 °C (lit.)
Boiling point:: 347.6±44.0 °C(Predicted)
Density: 1.24±0.1 g/cm3(Predicted)
vapor pressure: 0Pa at 25℃
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: <10g/l
form: Liquid
pka: 7.34±0.10(Predicted)
color: Clear colorless to yellow-orange
PH: 5.5 (1g/l, H2O, 20℃)
Water Solubility: Slightly Soluble in water.
Sensitive: Air Sensitive
BRN: 3030770
InChIKey: VXWBQOJISHAKKM-UHFFFAOYSA-N
LogP: 1.36 at 20℃
CAS DataBase Reference: 87199-17-5(CAS DataBase Reference)
EPA Substance Registry System: Boronic acid, (4-formylphenyl)- (87199-17-5)

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Safety

Hazard Codes: C,Xi
Risk Statements: 34-36/37/38
Safety Statements: 22-26-36/37/39-45-37/39-36
RIDADR: UN 1759 8/PG 3
WGK Germany: 3
F: 10
Hazard Note: Irritant
TSCA: T
HazardClass: IRRITANT, AIR SENSITIVE
HS Code: 29163990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H317May cause an allergic skin reaction

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P272Contaminated work clothing should not be allowed out of the workplace.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 431966
Product name: 4-Formylphenylboronic acid
Purity: ≥95.0%
Packaging: 1g
Price: $35.4
Updated: 2024/03/01

Sigma-Aldrich

Product number: 431966
Product name: 4-Formylphenylboronic acid
Purity: ≥95.0%
Packaging: 5g
Price: $117
Updated: 2024/03/01

TCI Chemical

Product number: F0446
Product name: 4-Formylphenylboronic Acid (contains varying amounts of Anhydride)
Packaging: 1g
Price: $28
Updated: 2024/03/01

TCI Chemical

Product number: F0446
Product name: 4-Formylphenylboronic Acid (contains varying amounts of Anhydride)
Packaging: 5g
Price: $77
Updated: 2024/03/01

Alfa Aesar

Product number: B25199
Product name: 4-Formylbenzeneboronic acid, 97%
Packaging: 1g
Price: $33.65
Updated: 2024/03/01

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4-Formylphenylboronic acid Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powder

Uses

suzuki reaction

Uses

4-Formylbenzeneboronic acid acts as a reagent used for Palladium-catalyzed arylation Suzuki-Miyaura cross-coupling in water, copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, ligand-free copper-catalyzed coupling of nitro arenes with arylboronic acids, triethylamine-catalyzed three-component Hantzsch condensations, copper-catalyzed nitrations, oxidative mono-cleavage of dialkenes catalyzed by Trametes hirsuta, palladacycle-catalyzed cross-coupling of arylboronic acids with carboxylic anhydrides or acyl chlorides, palladium-catalyzed aerobic oxidative cross-coupling reactions. It acts as a reagent used in preparation of sensitizers with dithiafulvenyl unit as electron donor for high-efficiency dye-sensitized solar cells, a novel protein synthesis inhibitor active against Gram-positive bacteria.

Uses

4-Formylphenylboronic acid is a substrate for Suzuki cross-coupling reactions and it can be used as a reagent for:

Palladium-catalyzed Suzuki-Miyaura cross-coupling in water.
Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides.
Ligand-free copper-catalyzed coupling of nitro arenes with arylboronic acids.
Triethylamine-catalyzed three-component Hantzsch condensations.
Copper-catalyzed nitrations.
Oxidative mono-cleavage of dialkenes catalyzed by Trametes hirsuta.
Palladacycle-catalyzed cross-coupling of arylboronic acids with carboxylic anhydrides or acyl chlorides.
Palladium-catalyzed aerobic oxidative cross-coupling reactions.
The synthesis of sensitizers with dithiafulvenyl unit as electron donor for high-efficiency dye-sensitized solar cells.
The synthesis of a novel protein synthesis inhibitor active against Gram-positive bacteria.
The Suzuki aryl-aryl coupling of the upper rim of hexahomotrioxacalix[3]arene.
A rhodium-catalyzed cyclization, converting 1,5-enynes to cyclopentenes and spiro-cyclopentenes.

Flammability and Explosibility

Not classified

Synthesis

Potassium phenyltrifluoroborate (184 mg, 1.00 mmol) was added to a solution of iron trichloride (185 mg, 1.10 mmol) in 3 mL of 1:1 THF/water. The mixture was stirred at room temperature for 30 min. The reaction mixture was then passed through a short column containing neutral absorption alumina. The alumina was then washed with a mixture of ethyl acetate/hexanes (2:1) to obtain 4-Formylphenylboronic acid (105 mg, 86%). [The boronic acid products can also be isolated by simple extraction techniques.]

4-Formylphenylboronic acid Preparation Products And Raw materials

Raw materials

p-Toluenesulfonic acid Toluene Tetrahydrofuran Ethylene glycol 4-Bromobenzaldehyde n-Butyllithium

Preparation Products

3-THIOPHEN-2-YL-BENZALDEHYDE

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4-Formylphenylboronic acid Suppliers

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Apollo Scientific Ltd.

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VWR International

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View Lastest Price from 4-Formylphenylboronic acid manufacturers

HebeiShuoshengImportandExportco.,Ltd

Product: 4-Formylphenylboronic acid 87199-17-5
Price: US $6.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 2000KG/Month
Release date: 2024-08-09

Hebei Longbang Technology Co., Ltd

Product: 4-Formylphenylboronic acid 87199-17-5
Price: US $6.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20TONS
Release date: 2024-04-28

Hebei Zhuanglai Chemical Trading Co Ltd

Product: 4-Formylphenylboronic acid 87199-17-5
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20 ton
Release date: 2024-11-20

87199-17-5, 4-Formylphenylboronic acidRelated Search:

4-Tolylboronic acid Phenethylboronic acid 4-Hydroxyphenylboronic acid Phenylboronic acid 4-Aminophenylboronic acid Benzaldehyde 4-(Methylthio)phenylboronic acid 2-CHLORO-5-FORMYLPHENYLBORONIC ACID 2-Boronobenzaldehyde~2-Formylphenylboronic acid,2-FORMYLPHENYLBORONIC ACID 5-CHLORO-2-FORMYLPHENYLBORONIC ACID 4-ETHOXY-3-FORMYLPHENYLBORONIC ACID 4-(PIPERIDINE-1-CARBONYL)PHENYLBORONIC ACID 4-FORMYLPHENYLBORONIC ACID, NEOPENTYL GLYCOL CYCLIC ESTER 4-(N,N-DIMETHYLAMINOCARBONYL)PHENYLBORONIC ACID 4-(N,N-DIETHYLAMINOCARBONYL)PHENYLBORONIC ACID 4-FORMYLPHENYLBORONIC ACID PROPANEDIOL-1,3 CYCLIC ESTER 4-(N,O-DIMETHYLHYDROXYLAMINOCARBONYL)PHENYLBORONIC ACID 4-Carbamoylphenylboronic acid

RARECHEM AH PB 0193

TIMTEC-BB SBB004077

P-FORMYLPHENYLBORONIC ACID

AKOS BRN-0111

4-FORMYLBENZENEBORONIC ACID

4-FORMYLPHENYLBORONIC ACID

4-BORONOBENZALDEHYDE

4-(Dihydroxyboryl)benzaldehyde, 4-Boronobenzaldehyde

4-Formylboronic acid

4-Formylphenylboronic acid ,97%

4-Formylphenylboronic acid,4-(Dihydroxyboryl)benzaldehyde, 4-Boronobenzaldehyde

4-Formylphenylboroni

4-ForMylphenylboronic acid, 97% 1GR

Benzeneboronic acid, p-forMyl- (6CI,7CI)

4-ForMylphenylboronic acid >=95.0%

4-Formylphenylboronic acid 4-(Dihydroxyboryl)benzaldehyde

p-Formylbenzeneboronic acid

(4-methanoylphenyl)boronic acid

Boronic acid, (4-formylphenyl)-

Boronic acid, B-(4-formylphenyl)-

4-(dihydroxyboryl)benzaldehyde

BENZALDEHYDE-4-BORONIC ACID

4-Boronobenzaldehyde~4-Formylphenylboronic acid

4-Formylpenylboronic Acid

Boronic acid, (4-formylphenyl)- (9CI)

4-Formylbenzeneboronicacid,97%

4-Formylphenylboronic acid(FPBA)

2,4-DINITROTOLUENE,1X1ML, ACN 1000UG/ML

PARAFORMYLPHENYLBORONIC ACID

4-FORMYLPHENYLBORONIC ACID, 98+%

4-Formylphenlboronic acid

4-Formylphenylboronic Acid (contains varying amounts of Anhydride)

FPBA

4-Formylphenylboronic Acid extrapure, 95%

4-Formylphenylboronic acid (4-FPBA)

Metoprolol Impurity 34

Formylphenylboronic acid

87199-17-5

87199-17-2

Boronic Acids

B (Classes of Boron Compounds)

BORONIC ACID

Boronic Acids and Derivatives

Aryl

Organometallic Reagents

Substituted Boronic Acids

Boron, Nitrile, Thio,& TM-Cpds

Carbonyl Compounds

ALDEHYDE

Aldehydes

blocks

BoronicAcids

Boronic Acid series

Aryl

Organoborons

B (Classes of Boron Compounds)

CHIRAL CHEMICALS

Boronic Acids & Esters