4-(5,5-Dimethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde

Product Name: 4-(5,5-Dimethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde
CAS No.: 128376-65-8
Chemical Name: 4-(5,5-Dimethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde
Synonyms: 2-(4-FOR;AKOS BRN-0004;2-(4-FORMYLPHENYL)-5,5-DIMETHYL-1,3,2-DIOXABORANE;4-(5,5-Dimethyl-1,3,2-dioxaborin-2-yl)benzaldehyde;4-Formylbenzeneboronic acid, neopentyl glycol ester;4-(5,5-Dimethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde;4-(5,5-DIMETHYL-1,3,2-DIOXABORINAN-2-YL)BENZALDEHYDE;4-(4,4-dimethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde;Benzaldehyde, 4-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)-;4-FORMYLPHENYLBORONIC ACID, NEOPENTYL GLYCOL CYCLIC ESTER
CBNumber: CB6226442
Molecular Formula: C12H15BO3
Formula Weight: 218.06
MOL File: 128376-65-8.mol

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4-(5,5-Dimethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde Property

Melting point:: 58-60 °C
Boiling point:: 350.5±25.0 °C(Predicted)
Density: 1.08±0.1 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
CAS DataBase Reference: 128376-65-8(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Hazard Note: Irritant
HS Code: 2931900090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: D479898
Product name: 4-(5,5-Dimethyl-1,3,2-dioxaborinan-2-yl)benzaldehyde
Packaging: 100mg
Price: $45
Updated: 2021/12/16

TRC

Product number: D479898
Product name: 4-(5,5-Dimethyl-1,3,2-dioxaborinan-2-yl)benzaldehyde
Packaging: 500mg
Price: $65
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FD151405
Product name: 4-(5,5-Dimethyl-1,3,2-dioxaborinan-2-yl)benzaldehyde
Packaging: 1g
Price: $83
Updated: 2021/12/16

SynQuest Laboratories

Product number: 6H60-1-18
Product name: 4-Formylbenzeneboronic acid, neopentyl glycol ester
Purity: 98%
Packaging: 5G
Price: $112
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FD151405
Product name: 4-(5,5-Dimethyl-1,3,2-dioxaborinan-2-yl)benzaldehyde
Packaging: 2g
Price: $144
Updated: 2021/12/16

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4-(5,5-Dimethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde Chemical Properties,Usage,Production

Synthesis

87199-17-5

126-30-7

128376-65-8

GENERAL STEPS: 4-Formylphenylboronic acid (4.11 g, 27.4 mmol) was dissolved in anhydrous tetrahydrofuran (40 mL) under nitrogen protection. To this solution was added 2,2-dimethyl-1,3-propanediol (neopentyl glycol, 3.14 g, 30.1 mmol) and the reaction was stirred for 2 hours at room temperature. After completion of the reaction, the solvent was removed by rotary evaporator. The crude product obtained was dissolved in dichloromethane (120 mL) and the organic phase was washed sequentially with water (80 mL x 3). The organic phases were combined, dried with anhydrous sodium sulfate, filtered and concentrated under reduced pressure to give 4-(5,5-dimethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde (5.66 g, 95% yield) as a white solid.

References

[1] Inorganic Chemistry, 2001, vol. 40, # 22, p. 5507 - 5517
[2] Synthesis, 1999, # 12, p. 2041 - 2044
[3] Tetrahedron, 2010, vol. 66, # 3, p. 583 - 590
[4] Patent: WO2006/67216, 2006, A2. Location in patent: Page/Page column 13
[5] Advanced Synthesis and Catalysis, 2014, vol. 356, # 7, p. 1527 - 1532

4-(5,5-Dimethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde Preparation Products And Raw materials

Raw materials

Preparation Products

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4-(5,5-Dimethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde Suppliers

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View Lastest Price from 4-(5,5-Dimethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde manufacturers

Career Henan Chemical Co

Product: 4-(5,5-Dimethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde 128376-65-8
Price: US $0.01/KG
Min. Order: 1KG
Purity: 98%； 99%
Supply Ability: 1kg; 5kg; 10kg；25kg
Release date: 2020-01-07

128376-65-8, 4-(5,5-Dimethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde Related Search:

N,N-Dimethylformamide Methoxydiethylborane o-Carborane 2-Methyl-2,4-pentanediol Benzaldehyde Dimethyl fumarate 2-Butoxyethanol Dimethyl sulfoxide Dimethyl disulfide ETHANE 4-Dimethylaminobenzaldehyde Borane-methyl sulfide complex Dacthal Dimethyl ether (+)-Diisopinocampheyl chloroborane 1,4-Butanediol Borane-pyridine complex Dimethyl sulfate

AKOS BRN-0004

4-(5,5-Dimethyl-1,3,2-dioxaborin-2-yl)benzaldehyde

4-(5,5-Dimethyl-1,3,2-dioxaborinan-2-yl)benzaldehyde, 5,5-Dimethyl-2-(4-formylphenyl)-1,3,2-dioxaborinane

4-Formylbenzeneboronic acid, neopentyl glycol ester

4-(5,5-Dimethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde 4-Formylphenylboronic acid neopentyl glycol cyclic ester

4-(5,5-DIMETHYL-1,3,2-DIOXABORINAN-2-YL)BENZALDEHYDE

4-(5,5-Dimethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde

4-FORMYLPHENYLBORONIC ACID, NEOPENTYL GLYCOL CYCLIC ESTER

4-FORMYLBENZENEBORONIC ACID 2,2-DIMETHYLPROPANEDIOL-1,3 CYCLIC ESTER

2-(4-FORMYLPHENYL)-5,5-DIMETHYL-1,3,2-DIOXABORANE

2-(4-FOR

4-(4,4-dimethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde

Benzaldehyde, 4-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)-

128376-65-8

C12H15BO3