4-(Methylthio)phenylboronic acid

Product Name: 4-(Methylthio)phenylboronic acid
CAS No.: 98546-51-1
Chemical Name: 4-(Methylthio)phenylboronic acid
Synonyms: AKOS BRN-0127;RARECHEM AH PB 0130;4-BORONOTHIOANISOLE;4-(Methylthio)phenyl;4-THIOANISOLEBORONIC ACID;THIOANISOLE-4-BORONIC ACID;4-Methylthiopenylboronic Acid;4-THIOMETHYLPHENYLBORONIC ACID;P-(METHYLTHIO)PHENYLBORONIC ACID;4-(METHYLTHIO)PHENYLBORONIC ACID
CBNumber: CB1483149
Molecular Formula: C7H9BO2S
Formula Weight: 168.02
MOL File: 98546-51-1.mol

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4-(Methylthio)phenylboronic acid Property

Melting point:: 210-214 °C (lit.)
Boiling point:: 333.5±44.0 °C(Predicted)
Density: 1.22±0.1 g/cm3(Predicted)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: soluble in Methanol
pka: 8.56±0.10(Predicted)
form: Crystalline Powder
color: Off-white
BRN: 3247219
CAS DataBase Reference: 98546-51-1(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 37/39-26-36-7/9
WGK Germany: 3
TSCA: No
HazardClass: IRRITANT
HS Code: 29163990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 456802
Product name: 4-(Methylthio)phenylboronic acid
Purity: ≥95%
Packaging: 5g
Price: $42.36
Updated: 2024/03/01

Sigma-Aldrich

Product number: 456802
Product name: 4-(Methylthio)phenylboronic acid
Purity: ≥95%
Packaging: 1g
Price: $20
Updated: 2023/06/20

TCI Chemical

Product number: M1458
Product name: 4-(Methylthio)phenylboronic Acid (contains varying amounts of Anhydride)
Packaging: 1g
Price: $22
Updated: 2024/03/01

TCI Chemical

Product number: M1458
Product name: 4-(Methylthio)phenylboronic Acid (contains varying amounts of Anhydride)
Packaging: 5g
Price: $86
Updated: 2024/03/01

Alfa Aesar

Product number: B23454
Product name: 4-(Methylthio)benzeneboronic acid, 97%
Packaging: 1g
Price: $25.65
Updated: 2024/03/01

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4-(Methylthio)phenylboronic acid Chemical Properties,Usage,Production

Chemical Properties

Off-white crystalline powder

Uses

Reactant involved in:

Suzuki-Miyaura cross coupling reactions with 2-aryl-1-bromo-1-nitroethenes or alkynyl bromides
Addition reactions with naphthyridine N-oxides
Oxyarylation of Heck reaction intermediates for synthesis of THF derivatives
Sulfoxidation reactions
Copper-catalyzed halogenation

4-(Methylthio)phenylboronic acid Preparation Products And Raw materials

Raw materials

Trimethyl borate 4-Bromothiophenol n-Butyllithium Dimethyl sulfate

Preparation Products

6-(4-METHYLSULFANYLPHENYL)PYRIDINE-2-CARBALDEHYDE

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4-(Methylthio)phenylboronic acid Suppliers

Americas 1 Belgium 3 China 158 Europe 4 France 2 Germany 12 India 9 Japan 5 Jordan 1 Russia 1 Slovakia 1 Sweden 1 Switzerland 2 Ukraine 1 United Kingdom 17 United States 67 Global 285

J & K SCIENTIFIC LTD.

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Tel: 4006608290; 18621169109
Fax: 86-21-61259102
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Beijing Donghualituo Techonlogy Development Co.,Ltd.

Tel: 010-88425576
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Email: sales@dhltchem.com
Country: China
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Alfa Aesar

Tel: 400-6106006
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Email: saleschina@alfa-asia.com
Country: China
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TCI (Shanghai) Development Co., Ltd.

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Energy Chemical

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Beijing Ouhe Technology Co., Ltd

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Jia Xing Isenchem Co.,Ltd

Tel: 0573-85285100 18627885956
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Accela ChemBio Co.,Ltd.

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Fax: 021-50795055
Email: sales@accelachem.com
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ProdList: 11660
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View Lastest Price from 4-(Methylthio)phenylboronic acid manufacturers

Hebei Duling International Trade Co. LTD

Product: 4-(Methylthio)phenylboronic acid 98546-51-1
Price: US $43.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100000kg
Release date: 2023-01-09

Career Henan Chemical Co

Product: 4-(Methylthio)phenylboronic acid 98546-51-1
Price: US $1.00/g
Min. Order: 1g
Purity: 95%~99%
Supply Ability: per week 100kg
Release date: 2019-09-10

98546-51-1, 4-(Methylthio)phenylboronic acidRelated Search:

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Boronic acid, B-[4-(methylthio)phenyl]-

THIOANISOLE-4-BORONIC ACID

RARECHEM AH PB 0130

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4-THIOMETHYLPHENYLBORONIC ACID

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4-METHYLSULFANYL-BENZENEBORONIC ACID

4-(METHYLTHIO)BENZENEBORONIC ACID

4-(METHYLTHIO)PHENYLBORONIC ACID

4-(METHYLMERCAPTO)BENZENEBORONIC ACID

4-BORONOTHIOANISOLE

AKOS BRN-0127

4-(Methylthio)phenylboronic Acid (contains varying amounts of Anhydride)

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4-(Methylthio)phenylboronic Acid&nbsp

4-(Methylthio)phenyl

4-(Methylsulfanyl)phenylboronic acid, May contain varying amounts of anhydride, 95%

[4-(methylthio)phenyl]boronic acid(SALTDATA: FREE)

98546-51-1

98456-51-1

BORONIC ACID

Boronic Acids and Derivatives

Aryl

Organometallic Reagents

Boronic Acids

B (Classes of Boron Compounds)

Aryl Boronic Acids

Boronic Acids and Derivatives

Chemical Synthesis

Monosubstituted Aryl Boronic Acids

B (Classes of Boron Compounds)

organic or inorganic borate

Boronic Acid

Azoles

blocks

BoronicAcids

Boric Acid

Aryl

Organoborons

Boronic acids

Organometallic Reagents

Boronate Ester

Potassium Trifluoroborate