4-(Methylthio)phenylboronic acid

Product Name: 4-(Methylthio)phenylboronic acid
CAS No.: 98546-51-1
Chemical Name: 4-(Methylthio)phenylboronic acid
Synonyms: AKOS BRN-0127;RARECHEM AH PB 0130;4-BORONOTHIOANISOLE;4-(Methylthio)phenyl;4-THIOANISOLEBORONIC ACID;THIOANISOLE-4-BORONIC ACID;4-Methylthiopenylboronic Acid;4-THIOMETHYLPHENYLBORONIC ACID;P-(METHYLTHIO)PHENYLBORONIC ACID;4-(METHYLTHIO)PHENYLBORONIC ACID
CBNumber: CB1483149
Molecular Formula: C7H9BO2S
Formula Weight: 168.02
MOL File: 98546-51-1.mol

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4-(Methylthio)phenylboronic acid Property

Melting point:: 210-214 °C (lit.)
Boiling point:: 333.5±44.0 °C(Predicted)
Density: 1.22±0.1 g/cm3(Predicted)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: soluble in Methanol
pka: 8.56±0.10(Predicted)
form: Crystalline Powder
color: Off-white
BRN: 3247219
CAS DataBase Reference: 98546-51-1(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 37/39-26-36-7/9
WGK Germany: 3
TSCA: No
HazardClass: IRRITANT
HS Code: 29163990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 456802
Product name: 4-(Methylthio)phenylboronic acid
Purity: ≥95%
Packaging: 5g
Price: $42.36
Updated: 2024/03/01

Sigma-Aldrich

Product number: 456802
Product name: 4-(Methylthio)phenylboronic acid
Purity: ≥95%
Packaging: 1g
Price: $20
Updated: 2023/06/20

TCI Chemical

Product number: M1458
Product name: 4-(Methylthio)phenylboronic Acid (contains varying amounts of Anhydride)
Packaging: 1g
Price: $22
Updated: 2024/03/01

TCI Chemical

Product number: M1458
Product name: 4-(Methylthio)phenylboronic Acid (contains varying amounts of Anhydride)
Packaging: 5g
Price: $86
Updated: 2024/03/01

Alfa Aesar

Product number: B23454
Product name: 4-(Methylthio)benzeneboronic acid, 97%
Packaging: 1g
Price: $25.65
Updated: 2024/03/01

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4-(Methylthio)phenylboronic acid Chemical Properties,Usage,Production

Chemical Properties

Off-white crystalline powder

Uses

Reactant involved in:

Suzuki-Miyaura cross coupling reactions with 2-aryl-1-bromo-1-nitroethenes or alkynyl bromides
Addition reactions with naphthyridine N-oxides
Oxyarylation of Heck reaction intermediates for synthesis of THF derivatives
Sulfoxidation reactions
Copper-catalyzed halogenation

4-(Methylthio)phenylboronic acid Preparation Products And Raw materials

Raw materials

Trimethyl borate 4-Bromothiophenol n-Butyllithium Dimethyl sulfate

Preparation Products

6-(4-METHYLSULFANYLPHENYL)PYRIDINE-2-CARBALDEHYDE

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4-(Methylthio)phenylboronic acid Suppliers

Americas 1 Belgium 3 China 159 Europe 4 France 2 Germany 12 India 9 Japan 5 Jordan 1 Russia 1 Slovakia 1 Sweden 1 Switzerland 2 Ukraine 1 United Kingdom 17 United States 66 Global 285

Toroma GmbH

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Email: info@toroma.eu
Country: Germany
ProdList: 195
Advantage: 58

Alfa Aesar, Thermo Fisher Scientific

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Email: es@alfa.com
Country: Germany
ProdList: 5123
Advantage: 58

CHEMOS GmbH & Co. KG

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Email: chemos@chemos.de
Country: Germany
ProdList: 6727
Advantage: 58

Porphyrin Systems

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Email: hombrecher@porphyrin-systems.de
Country: Germany
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Trigona oHG

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Country: Germany
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ABCR GmbH & CO. KG

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Country: Germany
ProdList: 6831
Advantage: 75

Service Chemical Inc.

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Country: Germany
ProdList: 6350
Advantage: 71

Rare Chemicals GmbH

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Email: sales@rarechem.de
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ProdList: 6297
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ChemCollect GmbH

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Country: Germany
ProdList: 6214
Advantage: 54

ACTIVATE SCIENTIFIC GmbH

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Email: info@activate-scientific.com
Country: Germany
ProdList: 2856
Advantage: 61

AKos Consulting & Solutions GmbH

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Email: akos@akosgmbh.de
Country: Germany
ProdList: 6717
Advantage: 72

Archimica

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Email: juergen.brockmann@clariant.com
Country: Germany
ProdList: 526
Advantage: 68

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View Lastest Price from 4-(Methylthio)phenylboronic acid manufacturers

Career Henan Chemical Co

Product: 4-(Methylthio)phenylboronic acid 98546-51-1
Price: US $1.00/g
Min. Order: 1g
Purity: 95%~99%
Supply Ability: per week 100kg
Release date: 2019-09-10

98546-51-1, 4-(Methylthio)phenylboronic acidRelated Search:

4-Tolylboronic acid Thioanisole 4-Methoxyphenylboronic acid Phenylboronic acid Phenethylboronic acid 4-Aminophenylboronic acid 4-Hydroxyphenylboronic acid PHENYLMERCURIC BORATE 4-Formylphenylboronic acid 4-ISOPROPYLTHIOPHENYLBORONIC ACID 4-ETHYLSULFINYLPHENYLBORONIC ACID 4-(ISOPROPYLSULFONYLPHENYL)BORONIC ACID 4-(METHANESULFINYL)BENZENEBORONIC ACID 4-(ETHYLTHIO)BENZENEBORONIC ACID 4-(ETHYLSULFONYL)PHENYLBORONIC ACID 4-(METHYLSULFONYL)PHENYLBORONIC ACID 4-(Methanesulfonyl)phenylboronic acid pinacol ester 3-(Methylthio)phenylboronic acid

(4-thiomethoxyphenyl)boronic acid

4-(Methylsulfanyl)phenylboronic acid, 95%, May contain varying aMounts of anhydride

Boronic acid, B-[4-(methylthio)phenyl]-

THIOANISOLE-4-BORONIC ACID

RARECHEM AH PB 0130

P-(METHYLTHIO)PHENYLBORONIC ACID

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4-(METHYLTHIO)PHENYLBORONIC ACID 97%

4-THIOMETHYLPHENYLBORONIC ACID

4-THIOANISOLEBORONIC ACID

4-(METHYLSULFANYL)PHENYLBORONIC ACID

4-METHYLSULFANYL-BENZENEBORONIC ACID

4-(METHYLTHIO)BENZENEBORONIC ACID

4-(METHYLTHIO)PHENYLBORONIC ACID

4-(METHYLMERCAPTO)BENZENEBORONIC ACID

4-BORONOTHIOANISOLE

AKOS BRN-0127

4-(Methylthio)phenylboronic Acid (contains varying amounts of Anhydride)

Boronic acid, [4-(methylthio)phenyl]-

4-(Methylthio)phenylboronic acid ,98%

4-(Methylthiophenyl)boronic acid, min. 97%

4-(Methylthio)phenylboronic acid,97%

4-(Methylthio)phenylboronic Acid&nbsp

4-(Methylthio)phenyl

4-(Methylsulfanyl)phenylboronic acid, May contain varying amounts of anhydride, 95%

[4-(methylthio)phenyl]boronic acid(SALTDATA: FREE)

98546-51-1

98456-51-1

BORONIC ACID

Boronic Acids and Derivatives

Aryl

Organometallic Reagents

Boronic Acids

B (Classes of Boron Compounds)

Aryl Boronic Acids

Boronic Acids and Derivatives

Chemical Synthesis

Monosubstituted Aryl Boronic Acids

B (Classes of Boron Compounds)

organic or inorganic borate

Boronic Acid

Azoles

blocks

BoronicAcids

Boric Acid

Aryl

Organoborons

Boronic acids

Organometallic Reagents

Boronate Ester

Potassium Trifluoroborate