Tris(triphenylphosphine)rhodiu

Reactions

Product Name: Tris(triphenylphosphine)rhodiu
CAS No.: 14694-95-2
Chemical Name: Tris(triphenylphosphine)rhodiu
Synonyms: Wilkinson;WILKINSON CATALYST;WILKINSON'S CATALYST;TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CHLORIDE;Tris(triphenylphosphine)rhodium chloride;Tetrakis(triphenlphosphine)palladium;TRIS(TRIPHENYLPHOSPHINE)CHLORORHODIUM;DECARBON;NSC 124140;Tris(triphenyL
CBNumber: CB1494341
Molecular Formula: C54H45ClP3Rh
Formula Weight: 925.21
MOL File: 14694-95-2.mol

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Tris(triphenylphosphine)rhodiu Property

Melting point:: 245-250 °C (dec.)
Boiling point:: >170°C
Density: 1.363; d 1.379
vapor pressure: 0Pa at 25℃
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
solubility: Soluble in most solvents (e.g. benzene, ethanol, chloroform, dichloromethane) but with phosphine dissociation. Reacts with O{2} in solution
form: Crystalline Powder
color: Red-brown to maroon
Water Solubility: insoluble
Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions
Sensitive: air sensitive
Merck: 14,9758
BRN: 4581440
Exposure limits: ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
InChIKey: QEYYHUJFSQCTAE-UHFFFAOYSA-M
LogP: 5.69 at 20℃
CAS DataBase Reference: 14694-95-2(CAS DataBase Reference)
NIST Chemistry Reference: chlorotris(triphenylphosphine)rhodium(14694-95-2)
EPA Substance Registry System: Rhodium, chlorotris(triphenylphosphine)-, (SP-4-2)- (14694-95-2)

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Safety

Hazard Codes: C,Xi
Risk Statements: 34-36/38
Safety Statements: 22-24/25-37/39-28A-26-15-45-36/37/39
RIDADR: 1759
WGK Germany: 1
F: 8-10-23
TSCA: Yes
HS Code: 28439090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H317May cause an allergic skin reaction

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 199982
Product name: Tris(triphenylphosphine)rhodium(I) chloride
Packaging: 1g
Price: $260
Updated: 2024/03/01

Sigma-Aldrich

Product number: 199982
Product name: Tris(triphenylphosphine)rhodium(I) chloride
Packaging: 5g
Price: $1200
Updated: 2024/03/01

TCI Chemical

Product number: T0931
Product name: Tris(triphenylphosphine)rhodium(I) Chloride
Purity: >98.0%(T)
Packaging: 1g
Price: $159
Updated: 2024/03/01

TCI Chemical

Product number: T0931
Product name: Tris(triphenylphosphine)rhodium(I) Chloride
Purity: >98.0%(T)
Packaging: 5g
Price: $363
Updated: 2021/12/16

Alfa Aesar

Product number: 010468
Product name: Chlorotris(triphenylphosphine)rhodium(I), 97%
Packaging: 1g
Price: $264
Updated: 2023/06/20

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Tris(triphenylphosphine)rhodiu Chemical Properties,Usage,Production

Reactions

A homogeneous hydrogenation catalyst which operates under mild conditions.
Catalyst for the decarbonylation of aldehydes.
Catalyst for regio- and stereoselective allylic substitution reactions.
Alkyne hydro-phosphorylation
Heck-type reaction with α,β-unsaturated esters.
Alkyne arylation
Allylic alcohol-olefin coupling.
Terminal alkenes from ketones.
Rh-catalyzed isomerization of α-aryl propargyl alcohols to indanones.
Reductive deprotection of silyl groups.

Chemical Properties

magenta crystals

Uses

suzuki reaction

Uses

Tris(triphenylphosphine)rhodiu is also known as Wilkinson's catalyst and is commonly used to catalyze the hydrogenation of alkenes. Tris(triphenylphosphine)rhodiu is also used in the catalytic hydroboration of alkenes with catecholborane and pinacolborane and the selective 1,4-reduction of α, β-unsaturated carbonyl compounds.

Uses

Homogeneous hydrogenation catalyst.

Flammability and Explosibility

Non flammable

Purification Methods

It forms dark burgundy crystals from hot EtOH after refluxing for 30minutes. When the solution is heated for only 5minutes, orange crystals are formed. Heating the orange crystals in EtOH yields red crystals. Crystallisation from Me2CO gives the orange crystals. The two forms have similar IR spectra, but the X-ray diffraction patterns are slighly different. [Osborne et al. J Chem Soc (A) 1711 1966, Osborne & Wilkinson Inorg Synth X 67 1967, Bennett & Donaldson Inorg Chem 16 655 1977.] The solubilities are as follows: in CH2Cl2 ~2% (25o), in toluene 0.2% (25o), and less soluble in Me2CO, MeOH, BuOH and AcOH, but insoluble in pet ethers and cyclohexane. It reacts with donor solvents such as pyridine, DMSO and MeCN.

Tris(triphenylphosphine)rhodiu Preparation Products And Raw materials

Raw materials

Preparation Products

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Tris(triphenylphosphine)rhodiu Suppliers

Australia 1 Belgium 4 Canada 2 CHINA 304 France 2 Germany 11 India 22 Japan 7 Singapore 1 Switzerland 4 The Netherlands 1 United Kingdom 11 United States 54 Global 424

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View Lastest Price from Tris(triphenylphosphine)rhodiu manufacturers

Shanghai UCHEM Inc.

Product: Tris(triphenylphosphine)rhodium(I) chloride 14694-95-2
Price: US $52.00-806.00/g
Min. Order: 1g
Purity: 0.98
Supply Ability: 10kg
Release date: 2023-12-14

Hangzhou ICH Biofarm Co., Ltd

Product: Tris(triphenylphosphine)chlororhodium 14694-95-2
Price: US $0.00-0.00/g
Min. Order: 0.10000000149011612g
Purity: 11.1%Rh
Supply Ability: 10kg
Release date: 2023-06-09

Weifang Wehibest Supply Chain Co.,Ltd

Product: Tris(triphenylphosphine)rhodiu 14694-95-2
Price: US $0.00-0.00/g
Min. Order: 1g
Purity: 0.99
Supply Ability: 100kg
Release date: 2023-08-14

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