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Tris(triphenylphosphine)rhodiu

Reactions
Product Name
Tris(triphenylphosphine)rhodiu
CAS No.
14694-95-2
Chemical Name
Tris(triphenylphosphine)rhodiu
Synonyms
Wilkinson;WILKINSON CATALYST;WILKINSON'S CATALYST;TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CHLORIDE;Tris(triphenylphosphine)rhodium chloride;Tetrakis(triphenlphosphine)palladium;TRIS(TRIPHENYLPHOSPHINE)CHLORORHODIUM;DECARBON;NSC 124140;Tris(triphenyL
CBNumber
CB1494341
Molecular Formula
C54H45ClP3Rh
Formula Weight
925.21
MOL File
14694-95-2.mol
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Tris(triphenylphosphine)rhodiu Property

Melting point:
245-250 °C (dec.)
Boiling point:
>170°C
Density 
1.363; d 1.379
vapor pressure 
0Pa at 25℃
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Soluble in most solvents (e.g. benzene, ethanol, chloroform, dichloromethane) but with phosphine dissociation. Reacts with O{2} in solution
form 
Crystalline Powder
color 
Red-brown to maroon
Water Solubility 
insoluble
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
Sensitive 
air sensitive
Merck 
14,9758
BRN 
4581440
Exposure limits
ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
InChIKey
QEYYHUJFSQCTAE-UHFFFAOYSA-M
LogP
5.69 at 20℃
CAS DataBase Reference
14694-95-2(CAS DataBase Reference)
NIST Chemistry Reference
chlorotris(triphenylphosphine)rhodium(14694-95-2)
EPA Substance Registry System
Rhodium, chlorotris(triphenylphosphine)-, (SP-4-2)- (14694-95-2)
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Safety

Hazard Codes 
C,Xi
Risk Statements 
34-36/38
Safety Statements 
22-24/25-37/39-28A-26-15-45-36/37/39
RIDADR 
1759
WGK Germany 
1
F 
8-10-23
TSCA 
Yes
HS Code 
28439090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H317May cause an allergic skin reaction

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
199982
Product name
Tris(triphenylphosphine)rhodium(I) chloride
Packaging
1g
Price
$260
Updated
2024/03/01
Sigma-Aldrich
Product number
199982
Product name
Tris(triphenylphosphine)rhodium(I) chloride
Packaging
5g
Price
$1200
Updated
2024/03/01
TCI Chemical
Product number
T0931
Product name
Tris(triphenylphosphine)rhodium(I) Chloride
Purity
>98.0%(T)
Packaging
1g
Price
$159
Updated
2024/03/01
TCI Chemical
Product number
T0931
Product name
Tris(triphenylphosphine)rhodium(I) Chloride
Purity
>98.0%(T)
Packaging
5g
Price
$363
Updated
2021/12/16
Alfa Aesar
Product number
010468
Product name
Chlorotris(triphenylphosphine)rhodium(I), 97%
Packaging
1g
Price
$264
Updated
2023/06/20
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Tris(triphenylphosphine)rhodiu Chemical Properties,Usage,Production

Reactions

  1. A homogeneous hydrogenation catalyst which operates under mild conditions.
  2. Catalyst for the decarbonylation of aldehydes.
  3. Catalyst for regio- and stereoselective allylic substitution reactions.
  4. Alkyne hydro-phosphorylation
  5. Heck-type reaction with α,β-unsaturated esters.
  6. Alkyne arylation
  7. Allylic alcohol-olefin coupling.
  8. Terminal alkenes from ketones.
  9. Rh-catalyzed isomerization of α-aryl propargyl alcohols to indanones.
  10. Reductive deprotection of silyl groups. 

Chemical Properties

magenta crystals

Uses

suzuki reaction

Uses

Tris(triphenylphosphine)rhodiu is also known as Wilkinson's catalyst and is commonly used to catalyze the hydrogenation of alkenes. Tris(triphenylphosphine)rhodiu is also used in the catalytic hydroboration of alkenes with catecholborane and pinacolborane and the selective 1,4-reduction of α, β-unsaturated carbonyl compounds.

Uses

Homogeneous hydrogenation catalyst.

Flammability and Explosibility

Non flammable

Purification Methods

It forms dark burgundy crystals from hot EtOH after refluxing for 30minutes. When the solution is heated for only 5minutes, orange crystals are formed. Heating the orange crystals in EtOH yields red crystals. Crystallisation from Me2CO gives the orange crystals. The two forms have similar IR spectra, but the X-ray diffraction patterns are slighly different. [Osborne et al. J Chem Soc (A) 1711 1966, Osborne & Wilkinson Inorg Synth X 67 1967, Bennett & Donaldson Inorg Chem 16 655 1977.] The solubilities are as follows: in CH2Cl2 ~2% (25o), in toluene 0.2% (25o), and less soluble in Me2CO, MeOH, BuOH and AcOH, but insoluble in pet ethers and cyclohexane. It reacts with donor solvents such as pyridine, DMSO and MeCN.

Tris(triphenylphosphine)rhodiu Preparation Products And Raw materials

Raw materials

Preparation Products

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Tris(triphenylphosphine)rhodiu Suppliers

Australia 1 Belgium 4 Canada 2 CHINA 304 France 2 Germany 11 India 22 Japan 7 Singapore 1 Switzerland 4 The Netherlands 1 United Kingdom 11 United States 54 Global 424
ASCHEM GmbH
Tel
--
Fax
--
Email
info@aschem.ch
Country
Switzerland
ProdList
897
Advantage
58
HetCat
Tel
--
Fax
--
Email
info@hetcat.com
Country
Switzerland
ProdList
555
Advantage
51
Metalor Technologies Group
Tel
--
Fax
--
Email
fredy.hiltmann@metalor.com
Country
Switzerland
ProdList
46
Advantage
76
SIGMA-RBI
Tel
--
Fax
--
Country
Switzerland
ProdList
6896
Advantage
91
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View Lastest Price from Tris(triphenylphosphine)rhodiu manufacturers

Shanghai UCHEM Inc.
Product
Tris(triphenylphosphine)rhodium(I) chloride 14694-95-2
Price
US $52.00-806.00/g
Min. Order
1g
Purity
0.98
Supply Ability
10kg
Release date
2023-12-14
Hangzhou ICH Biofarm Co., Ltd
Product
Tris(triphenylphosphine)chlororhodium 14694-95-2
Price
US $0.00-0.00/g
Min. Order
0.10000000149011612g
Purity
11.1%Rh
Supply Ability
10kg
Release date
2023-06-09
Weifang Wehibest Supply Chain Co.,Ltd
Product
Tris(triphenylphosphine)rhodiu 14694-95-2
Price
US $0.00-0.00/g
Min. Order
1g
Purity
0.99
Supply Ability
100kg
Release date
2023-08-14

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