ChemicalBook > CAS DataBase List > MORPHOLIN-4-YL-ACETIC ACID

MORPHOLIN-4-YL-ACETIC ACID

Product Name
MORPHOLIN-4-YL-ACETIC ACID
CAS No.
3235-69-6
Chemical Name
MORPHOLIN-4-YL-ACETIC ACID
Synonyms
4-Morpholineacetic acid;4-Morpholinylacetic acid;EOS-60962;AKOS BBS-00002525;TIMTEC-BB SBB010303;RARECHEM AL BO 0383;MORPHOLINOACETIC ACID;4-MORPHOLINOACETIC ACID;Carfilzomib Impurity 22;4-Morpholine acetic acid
CBNumber
CB1495292
Molecular Formula
C6H11NO3
Formula Weight
145.16
MOL File
3235-69-6.mol
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MORPHOLIN-4-YL-ACETIC ACID Property

Melting point:
162-164℃
Boiling point:
272℃
Density 
1.202
Flash point:
118℃
storage temp. 
Sealed in dry,Room Temperature
solubility 
DMSO (Slightly), Methanol (Slightly)
form 
Solid
pka
2.25±0.10(Predicted)
color 
Off-White
InChI
InChI=1S/C6H11NO3/c8-6(9)5-7-1-3-10-4-2-7/h1-5H2,(H,8,9)
InChIKey
VIWZVFVJPXTXPA-UHFFFAOYSA-N
SMILES
N1(CC(O)=O)CCOCC1
CAS DataBase Reference
3235-69-6(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36
HazardClass 
IRRITANT
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H228Flammable solid

H250Catches fire spontaneously if exposed to air

H260In contact with water releases flammable gases which may ignite spontaneously

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P403Store in a well-ventilated place.

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N-Bromosuccinimide Price

TCI Chemical
Product number
M3601
Product name
2-Morpholinoacetic Acid
Purity
min. 95.0 %
Packaging
5G
Price
$99
Updated
2025/07/31
TRC
Product number
M723690
Product name
Morpholin-​4-​ylAceticAcid
Packaging
25g
Price
$355
Updated
2021/12/16
Matrix Scientific
Product number
027160
Product name
Morpholin-4-ylacetic acid
Packaging
25g
Price
$185
Updated
2021/12/16
AK Scientific
Product number
J94877
Product name
Morpholin-4-yl-aceticacid
Packaging
25g
Price
$125
Updated
2021/12/16
Matrix Scientific
Product number
027160
Product name
Morpholin-4-ylacetic acid
Packaging
5g
Price
$45
Updated
2021/12/16
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MORPHOLIN-4-YL-ACETIC ACID Chemical Properties,Usage,Production

Uses

Morpholin-?4-?yl Acetic Acid was used in preparation of pyrrolidine-fused fullerene multicarboxylates by photoreaction.

Definition

ChEBI: N-(2-Carboxymethyl)-morpholine is an alpha-amino acid.

Synthesis

3235-82-3

3235-69-6

b) Synthesis of 2-morpholinoacetic acid Ethyl 2-morpholinoacetate (1 g, 57.8 mmol, 1.0 eq.) was dissolved in 8N HCl and the reaction was stirred at 95°C for 16 hours. Upon completion of the reaction, the reaction mixture was concentrated, quenched, and extracted as in Intermediate Example 15(b). The solvent was removed by distillation to afford the target product 2-morpholinoacetic acid in 96.3% (0.8 g) yield. The product was analyzed by LC-MS (ESI): calculated mass: 145.16; measured mass: 146.3 [M + H]+ (retention time: 0.21 min).

References

[1] Patent: WO2013/53983, 2013, A1. Location in patent: Page/Page column 40
[2] Journal of Medicinal Chemistry, 2000, vol. 43, # 8, p. 1489 - 1494
[3] Liebigs Annalen der Chemie, 1983, # 6, p. 950 - 961
[4] Patent: US2015/11548, 2015, A1. Location in patent: Paragraph 0145
[5] Patent: WO2009/48559, 2009, A1. Location in patent: Page/Page column 70

MORPHOLIN-4-YL-ACETIC ACID Preparation Products And Raw materials

Raw materials

Sodium sulfate Sodium chloride Tetrahydrofuran Ethyl acetate Sodium bicarbonate tert-Butyl bromoacetate Morpholine Sulfuric acid

Preparation Products

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MORPHOLIN-4-YL-ACETIC ACID Suppliers

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View Lastest Price from MORPHOLIN-4-YL-ACETIC ACID manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
Morpholin-4-yl-acetic acid 3235-69-6
Price
US $8.80-2.20/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2025-06-27
Henan Aochuang Chemical Co.,Ltd.
Product
MORPHOLIN-4-YL-ACETIC ACID 3235-69-6
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1Ton
Release date
2022-10-13
ShenZhen H&D Pharmaceutical Technology Co., LTD
Product
Carfilzomib Impurity 22
Price
US $0.00-0.00/mg
Min. Order
10mg
Purity
98%
Supply Ability
500mg
Release date
2024-07-12

3235-69-6, MORPHOLIN-4-YL-ACETIC ACIDRelated Search:

3-Morpholinecarboxylic acid 3-morpholinylmethanol 4-Benzoylmorpholine Morpholin-3-ylMethanol hydrochloride 3-cyanoMorpholine methyl morpholine-2-carboxylate hydrochloride MORPHOLINOFORMAMIDINE HYDROBROMIDE chloromethyl morpholine-4-carboxylate MORPHOLINO(2-PIPERIDINYL)METHANONE HYDROCHLORIDE MORPHOLIN-4-YL-PIPERAZIN-1-YL-METHANONE Morpholine-2-carbonitrile METHYL N-MORPHOLINOACETATE mobecarb MORPHOLIN-4-YL-ACETIC ACID MORPHOLIN-4-YL-PHENYL-ACETIC ACID MORPHOLIN-2-YL-ACETIC ACID ETHYL ESTER MORPHOLIN-4-YL-ACETIC ACID,MORPHOLIN-4-YL-ACETIC ACID HYDROCHLORIDE,Morpholin-4-yl-acetic acid hydrochloride ,98% (4-CHLORO-PHENYL)-MORPHOLIN-4-YL-ACETIC ACID

  • Carfilzomib Impurity 22
  • AKOS BBS-00002525
  • 4-MORPHOLINOACETIC ACID
  • 2-(4-MORPHOLINYL)ACETIC ACID
  • MORPHOLINOACETIC ACID
  • MORPHOLIN-4-YL-ACETIC ACID
  • RARECHEM AL BO 0383
  • TIMTEC-BB SBB010303
  • Morpholin-4-ylacetic acid Morpholinoacetic acid
  • 4-Morpholine acetic acid
  • 4-Morpholineacetic acid
  • morpholin-4-ylacetic acid(SALTDATA: HCl)
  • 2-(Morpholino)acetic acid
  • N-(Carboxymethyl)morpholine
  • 2-morpholin-4-ium-4-ylacetate
  • 2-morpholin-4-ium-4-ylethanoate
  • 2-morpholin-4-ylethanoic acid
  • 2-(4-morpholin-4-iumyl)acetate
  • EOS-60962
  • 4-Morpholinylacetic acid
  • 2-morpholin-4-ylaceticaci
  • Morpholine-4-ylaceticacid
  • 3235-69-6
  • Carboxylic acid
  • Amino Acids and Derivatives