Zineb

ChemicalBook > CAS DataBase List > Zineb

Product Name: Zineb
CAS No.: 12122-67-7
Chemical Name: Zineb
Synonyms: ZEB;cineb;zidan;Zineb;aspor;daisen;dipher;discon;funjeb;kypzin
CBNumber: CB1497049
Molecular Formula: C4H6N2S4Zn
Formula Weight: 275.75
MOL File: 12122-67-7.mol

Less

Zineb Property

Melting point:: 157°C (rough estimate)
vapor pressure: <1x l0^-5 at 20 °C
Flash point:: 90℃
storage temp.: 2-8°C
solubility: DMSO (Heated, Very Slightly)
Water Solubility: ca.10 mg l^-1 (room temperature)
Density: 1.74 g/cm3
form: Water-Insoluble Powder
Merck: 13,10220
BRN: 4165797
InChIKey: AMHNZOICSMBGDH-UHFFFAOYSA-L
CAS DataBase Reference: 12122-67-7(CAS DataBase Reference)
IARC: 3 (Vol. 12, Sup 7) 1987
EPA Substance Registry System: Zineb (12122-67-7)

Less

Safety

Hazard Codes: Xi
Risk Statements: 37-43
Safety Statements: 8-24/25-46
RIDADR: UN 3077 9 / PGIII
WGK Germany: 3
RTECS: ZH3325000
HazardClass: 6.1
PackingGroup: III
HS Code: 29309090
Hazardous Substances Data: 12122-67-7(Hazardous Substances Data)
Toxicity: LD50 orally in rats: >5000 mg/kg (Gaines)

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H317May cause an allergic skin reaction

H335May cause respiratory irritation

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 45707
Product name: Zineb
Purity: technical mixture
Packaging: 250mg
Price: $30.1
Updated: 2024/03/01

TRC

Product number: Z439975
Product name: Zineb
Packaging: 250mg
Price: $50
Updated: 2021/12/16

AK Scientific

Product number: S524
Product name: Zineb
Packaging: 250mg
Price: $80
Updated: 2021/12/16

Medical Isotopes, Inc.

Product number: 73033
Product name: Zineb
Packaging: 25g
Price: $675
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: AGR0000051
Product name: ZINEB
Purity: 95.00%
Packaging: 5G
Price: $909.56
Updated: 2021/12/16

Less

Zineb Chemical Properties,Usage,Production

Description

Zineb is a light-coloured powder/crystal and insoluble in water. Zineb is one of the nonsystemic (surface-acting) fungicides of the group ethylenebisdithiocarbamates (EBDCs). Zineb is a polymer of ethylene (bis)thiocarbamate units linked with zinc and used for the control and prevention of crop damage in the field and also to protect harvested crops from deterioration during storage or transport. Zineb was used to protect fruit and vegetable crops from a wide range of foliar and other diseases. It was available in the United States as wettable powder and dust formulations. Zineb can be formed by combining nabam and zinc sulphate in the spray tank.

Chemical Properties

Pure product is white crystal, industrial product is white to light yellow powder. Soluble in carbon disulfide and pyridine, insoluble in most organic solvents, insoluble in water (10mg/L). It is unstable to light, heat and humidity, and decomposes easily when it meets alkaline substances or copper. The decomposition products of zineb include ethylene thiourea, which is more toxic.

Uses

Zineb is a contact fungicide that provides protection against a wide variety of fungal diseases (including leaf spots, blights, rust, downy mildew, scab, etc.) in field crops, fruits, vines, vegetables, ornamentals, citrus and bananas.

Uses

Zineb is a light-colored powder or crystal. It is a polymer of ethylene (bis) thiocarbamate units linked with zinc. Zineb is used to prevent crop damage in the field and to protect harvested crops from deterioration during storage or transport. It was used to protect fruit and vegetable crops from a wide range of foliar and other diseases. It was available in the United States as wettable powder and dust formulations. Zineb can be formed by combining nabam and zinc sulfate in a spray tank.

Definition

ChEBI: Zineb is a polymeric complex of zinc with the ethylene bis(dithiocarbamate) anionic ligand. Formerly used as an agricultural fungicide for the control of downy mildews and rusts, its use is no longer permitted in the US or the EU. It has a role as an antifungal agrochemical. It is a macromolecule, a zinc coordination entity and a dithiocarbamate salt. It contains an ethylenebis(dithiocarbamate).

General Description

An off-white powder. Used as a fungicide.

Air & Water Reactions

Decomposes gradually, accelerated by exposure to air, moisture, and heat. Insoluble in water. Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids.

Reactivity Profile

Zineb is a zinc salt of a dithiocarbamic acid. May generate flammable gases with aldehydes, nitrides, and hydrides. Incompatible with acids, peroxides, and acid halides.

Hazard

Toxic by inhalation and ingestion; irritant to eyes and mucous membranes. Questionable carcinogen.

Fire Hazard

Flash point data for Zineb are not available, but Zineb is probably combustible.

Contact allergens

Zineb is a pesticide of the dithiocarbamate group. Sensitization can occur in gardeners and florists.

Metabolic pathway

Zineb and other alkylenebis( dithiocarbamate) fungicides are degraded and metabolised via a common pathway. The primary degradation reaction of zineb in water, soil, plants and animals involves the initial dissociation of the metal complex and decomposition to numerous degradation products including ethylenethiourea (ETU) and ethyleneurea (EU) as major products (Scheme 1).

Purification Methods

Crystallise this herbicide several times from hot toluene or from hot CHCl3 by addition of EtOH. It is a skin irritant. [Beilstein 4 III 149, 4 IV 234.]

Degradation

[¹⁴C-ethylene]Zineb(1) was decomposed mainly to ETU (2) in an aqueous suspension after 14 days via the 5,6-dihydro-3H-imidazo[2,1-c]-1,2,4- dithiazole-3-thione (3) intermediate (Vonk, 1976). In dilute alkaline solution and in the presence of light, heat and moisture, zineb decomposed rapidly to compound 3 (Marshall, 1978). ETU (2) in aqueous solutions was further converted into 2-imidazoline (4) and EU (5) (kaars Sijpesteijn and Vonk, 1974). Zineb decomposed in sterile marine culture medium to yield ETU (2) and compound 3. In the presence of copper, an additional degradation product, ethylene diisothiocyanate (6), was also observed (Hunter and Evans, 1991).

Toxicity evaluation

Zineb has a low mammalian toxicity however, it may cause adverse reproduction/developement effects if ingested. It is moderately toxic to most fauna and flora.

Zineb Preparation Products And Raw materials

Raw materials

FUMING SULFURIC ACID Ethylenediamine Zinc sulphate Water Carbon disulfide NABAM Sodium hydroxide Sulfuric acid Sodium carbonate

Preparation Products

Maneb

Less

Zineb Suppliers

China 124 France 1 Germany 2 India 3 Japan 3 South Korea 1 Switzerland 1 United Kingdom 1 United States 13 USA 1 Global 150

WUXI HONORSHINE CHEMICAL CO.,LTD.

Tel: 0510-83593312 13665125081
Fax: 0510-83574508
Email: sales@honorshinechem.com
Country: China
ProdList: 50
Advantage: 60

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 94838
Advantage: 76

3B Pharmachem (Wuhan) International Co.,Ltd.

Tel: 821-50328103-801 18930552037
Fax: 86-21-50328109
Email: 3bsc@sina.com
Country: China
ProdList: 15848
Advantage: 69

Dalian Meilun Biotech Co., Ltd.

Tel: 0411-62910999 13889544652
Email: sales@meilune.com
Country: China
ProdList: 4664
Advantage: 58

Nanjing Sunlida Biological Technology Co., Ltd.

Tel: 025-57798810
Fax: 025-57019371
Email: sales@sunlidabio.com
Country: China
ProdList: 3750
Advantage: 55

TargetMol Chemicals Inc.

Tel: 021-021-33632979 15002134094
Fax: 021-33632979
Email: marketing@targetmol.com
Country: China
ProdList: 7854
Advantage: 58

Shanghai Macklin Biochemical Co.,Ltd.

Tel: 15221275939 15221275939
Fax: 021-50706099
Email: shenlinxing@macklin.cn
Country: China
ProdList: 15878
Advantage: 55

Hubei Jusheng Technology Co.,Ltd

Tel: 027-59599241 18871490274
Fax: 027-59599241
Email: 1400878000@qq.com
Country: China
ProdList: 9972
Advantage: 58

Alta Scientific Co., Ltd.

Tel: 022-6537-8550 15522853686
Fax: 022-2532-9655
Email: sales@altasci.com.cn
Country: China
ProdList: 4515
Advantage: 55

Shanghai YuanYe Biotechnology Co., Ltd.

Tel: 021-61312847; 18021002903
Fax: QQ:3008007432
Email: 3008007409@qq.com
Country: China
ProdList: 27322
Advantage: 60

Shandong Xiya Chemical Co., Ltd.

Tel: 4009903999 13395398332
Fax: 0539-6365991
Email: sales@xiyashiji.com
Country: China
ProdList: 20810
Advantage: 60

Raw material medicin reagent co.,Ltd

Tel: 025-57798860
Email: sales@njromanme.com
Country: China
ProdList: 4534
Advantage: 58

Amadis Chemical Company Limited

Tel: 571-89925085
Fax: 0086-571-89925065
Email: sales@amadischem.com
Country: China
ProdList: 131981
Advantage: 58

Shanghai Orgchem Co.,Ltd.

Tel: +86-21-5877 1921
Fax: +86-21-5877 1925
Email: info@chemofchina.com
Country: China
ProdList: 9661
Advantage: 55

JinJin Le Chemical Co., Ltd

Tel: 10106090
Email: jjlchem2@163.com
Country: China
ProdList: 9986
Advantage: 58

Shandong Ono Chemical Co., Ltd.

Tel: 0539-6362799 20）
Fax: 0539-6362799（To 20）
Country: China
ProdList: 9998
Advantage: 58

Wuhan Netcom Electronic Commerce Limited

Tel: 18064670521
Fax: 0757-88210752
Email: 2355935187@ycphar.com
Country: China
ProdList: 4887
Advantage: 58

Aikon International Limited

Tel: 025-66113011 13155353615
Fax: (7)02557626880
Email: qzhang@aikonchem.com
Country: China
ProdList: 15396
Advantage: 58

Wuhan FengyaoTonghui Chemical Products Co., Ltd.

Tel: 027-87466105 15377573527
Email: 2678564200@qq.com
Country: China
ProdList: 17997
Advantage: 58

Foshan DaoQi Biological Co., Ltd.

Tel: 18062666947
Fax: 18062666959
Email: 2355880548@qq.com
Country: China
ProdList: 4229
Advantage: 58

Zhengzhou Acme Chemical Co., Ltd.

Tel: 0371-0371-63315541 13323832564
Fax: QQ:3001332135
Email: 3001332135@qq.com
Country: China
ProdList: 9998
Advantage: 58

Shaanxi Jiandu Pharmaceutical Chemical Co. Ltd.

Tel: 029-87576359 17691182729
Fax: 029-88380327
Email: 1018@dideu.com
Country: China
ProdList: 1985
Advantage: 58

Shenzhen Polymeri Biochemical Technology Co., Ltd.

Tel: +86-400-002-6226 13028896684
Email: sales@rrkchem.com
Country: China
ProdList: 55896
Advantage: 58

Henan Alfa Chemical Co., Ltd

Tel: +8618339805032
Email: alfa4@alfachem.cn
Country: China
ProdList: 12975
Advantage: 58

Hebei Mojin Biotechnology Co., Ltd

Tel: +8613288715578
Email: sales@hbmojin.com
Country: China
ProdList: 12471
Advantage: 58

Xi'an MC Biotech, Co., Ltd.

Tel: 029-89275612 +8618991951683
Fax: 8618991951683
Email: mcbio_sales@163.com
Country: China
ProdList: 2255
Advantage: 58

Hefei TNJ Chemical Industry Co.,Ltd.

Tel: 0551-65418671
Fax: 0551-65418697
Email: sales@tnjchem.com
Country: China
ProdList: 34572
Advantage: 58

Qiuxian Baitai New Material Co., LTD

Tel: +8618330912755
Fax: +8619932103556
Email: sale2@hbyalin.com
Country: China
ProdList: 1677
Advantage: 58

Chemwill Asia Co.,Ltd.

Tel: 86-21-51086038
Fax: 86-21-51861608
Email: chemwill_asia@126.com
Country: CHINA
ProdList: 23931
Advantage: 58

Hubei Jusheng Technology Co.,Ltd.

Tel: 18871490254
Fax: 027-59599243
Email: linda@hubeijusheng.com
Country: CHINA
ProdList: 28180
Advantage: 58

Hebei Guanlang Biotechnology Co., Ltd.

Tel: +86-19930503282
Fax: whatapp+8619930503282
Email: alice@crovellbio.com
Country: China
ProdList: 8822
Advantage: 58

Guangdong Wengjiang Chemical Reagent Co., Ltd.

Tel: 0751-2886766 13927870850
Fax: 0751-2886756
Email: 3001267247@qq.com
Country: China
ProdList: 9999
Advantage: 58

Shandong chuangyingchemical Co., Ltd.

Tel: 18853181302
Email: sale@chuangyingchem.com
Country: CHINA
ProdList: 5909
Advantage: 58

Chongqing Chemdad Co., Ltd

Tel: +86-023-61398051 +8613650506873
Email: sales@chemdad.com
Country: China
ProdList: 39916
Advantage: 58

Nanjing Bermuda Biotechnology Co., Ltd.

Tel: 027-1734052141618086404407 17340521416
Fax: 17340521416
Email: 1757224788@qq.com
Country: China
ProdList: 2010
Advantage: 58

Wuhan Rongcan Biotechnology Co., Ltd

Tel: 18327024450
Fax: 183-27024450
Email: 2130026275@qq.com
Country: China
ProdList: 4592
Advantage: 58

CONIER CHEM AND PHARMA LIMITED

Tel: +8618523575427
Email: sales@conier.com
Country: China
ProdList: 49391
Advantage: 58

ShangHai Anpel Co, Ltd.

Tel: 18501792038; 18501792038
Email: shanpel@anpel.com.cn
Country: China
ProdList: 9614
Advantage: 58

Wuhan lanabai Pharmaceutical Chemical Co., Ltd

Tel: 15307151931
Fax: QQ-2355680
Email: 2355680@qq.com
Country: China
ProdList: 8224
Advantage: 58

Shanghai Haohong Pharmaceutical Co., Ltd.

Tel: 4008210725 4008210725
Email: malulu@leyan.com
Country: China
ProdList: 55023
Advantage: 58

Shanghai Sig Biotechnology Co., LTD

Tel: 021-57810052 18930344717
Fax: 021-57810052
Email: 2089316240@qq.com
Country: China
ProdList: 9396
Advantage: 58

Hubei MAX Fine Chemical Technology Co., Ltd.

Tel: 13026126800 13027176014
Fax: QQ1652805836
Email: hbmaxkj@163.com
Country: China
ProdList: 4730
Advantage: 58

Wuhan Hongde Yuexin Pharmaceutical Technology Co., Ltd

Tel: 02783850058 15377551550
Fax: 027-83850058
Email: whhdyxchem027@sina.com
Country: China
ProdList: 2440
Advantage: 58

Chongqing Yuanyuanxiang Technology Development Co. LTD

Tel: 023-55703781 15320534687
Fax: 023-55703781
Email: 2022434087@qq.com
Country: China
ProdList: 4129
Advantage: 58

Energy Chemical

Tel: 021-58432009 400-005-6266
Fax: 021-58436166
Email: marketing1@energy-chemical.com
Country: China
ProdList: 44843
Advantage: 58

Wuhan Yanzhe Technology Co., Ltd

Tel: 15527250409
Fax: QQ：2692360204
Email: wenhaotian12@163.com
Country: China
ProdList: 4576
Advantage: 58

Lingyuan Bebiansen Biological Technology Co., Ltd

Tel: 18642120371
Email: 2837458851@qq.com
Country: China
ProdList: 9925
Advantage: 58

NORANA GROUP

Tel: 027-027-59209883 17386169806
Fax: 027-59209883
Email: service@nornachem.com
Country: China
ProdList: 4604
Advantage: 58

Hubei yongkuo Technology Co., Ltd

Tel: 027-59223108 15972152991
Fax: 027-59223108
Email: 1248580099@qq.com
Country: China
ProdList: 10011
Advantage: 58

Hubei Xinkang Pharmaceutical Chemical Co., Ltd

Tel: 027-027-59308705 18871579363
Fax: 027-59308705
Email: 1248680011@qq.com
Country: China
ProdList: 9984
Advantage: 58

Less

View Lastest Price from Zineb manufacturers

Hebei Duling International Trade Co. LTD

Product: Zineb 12122-67-7
Price: US $9.90/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000kg
Release date: 2022-10-17

Hebei Mojin Biotechnology Co., Ltd

Product: Zineb 12122-67-7
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20tons
Release date: 2023-09-01

WUXI HONOR SHINE CHEMICAL CO.,LTD

Product: Zineb 12122-67-7
Price: US $0.00/kg
Min. Order: 25kg
Purity: 90%&95%
Supply Ability: 20tons
Release date: 2022-06-10

12122-67-7, ZinebRelated Search:

N-Aminothiourea Zinc phosphate Phenyl chlorothionocarbonate 4-Aminobenzoic acid Thiobenzoic acid Dithiooxamide Zinc oxide ZINC FORMATE Chlorophacinone maneb-zineb-komple Anthranilic acid Zineb PARZATE ZINEB(R),ZINEB (TM) Propineb Zineb+Thiram,W.P.(65%) ZINEB-ETHYLENETHIURAMDISULPHIDEADDUCT

asporum

bercema

blightox

blizene

carbadine

carbamodithioicacid,1,2-ethanediylbis,zincsalt

caswellnumber930

chemzineb

((1,2-ethanediylbis(carbamodithioato))(2-))-zin

cineb

crystalzineb

cynkotox

daisen

deikusol

devizeb

dipher

discon

dithane65

dithanez

ditiamina

ent14,874

fitodith80

fungo-pulvit

funjeb

kupratsin

kypzin

lipotan

lirotan

lodacol

lonacol(discontinued)

lonocol

micide

micide55

novosirn

novozinn50

novozir

novozirn

novozirn50

pamosol2forte

parzatec

parzatezineb

perosin

perosin75b

perozin

perozine

perozine75b

pilzolsz

polyramz

shaughnessynumber014506

sperlox-z

taloberg

tanazon

thiodow

thionicm

tiazin

tiezene

Zineb68%+Hexaconazol4% WP

Zinc, [N-[2-[(dithiocarboxy)amino]ethyl]carbamodithioato(2-)-κS,κS']-