(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE

ChemicalBook > CAS DataBase List > (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE

Product Name: (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE
CAS No.: 494227-37-1
Chemical Name: (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE
Synonyms: SL-M004-1;amino)(phenyL;MANDYPHOS SL-M004-1;Ferrocene Impurity 3;Deltamethrin Impurity 9;]-1,1'-bis[di(3,5-dimethyL;-(dimethylamino)benzyl]ferrocene;(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethyL;(R)-(S)-NMe2-P(3,5-Me-4-MeOPh)2-Mandyphos;(aR,aR)-1,1#-Bis[-(dimethylamino)benzyl]-(S,S)-2,2#-bis[bis(4-methoxy-3,5
CBNumber: CB1705267
Molecular Formula: C64H74FeN2O4P210*
Formula Weight: 1053.08
MOL File: 494227-37-1.mol

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(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE Property

alpha: -61.5° (c 1.0, CHCl3)
form: solid
color: yellow to orange-red
Stability:: store cold

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Safety

Risk Statements: 36/37/38
Safety Statements: 26-36/37/39
WGK Germany: 3
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 73469
Product name: (SP,S′P)-1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene
Purity: ≥97%
Packaging: 1g
Price: $718
Updated: 2024/03/01

Sigma-Aldrich

Product number: 73469
Product name: (SP,S′P)-1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene
Purity: ≥97%
Packaging: 5g
Price: $2370
Updated: 2023/01/07

Strem Chemicals

Product number: 26-0248
Product name: (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-dimethyl-4-methoxyphenyl)phosphino]ferrocene, min. 97%
Packaging: 100mg
Price: $74
Updated: 2021/12/16

Strem Chemicals

Product number: 26-0248
Product name: (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-dimethyl-4-methoxyphenyl)phosphino]ferrocene, min. 97%
Packaging: 500mg
Price: $278
Updated: 2021/12/16

Sigma-Aldrich

Product number: 73469
Product name: (SP,S′P)-1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene
Purity: ≥97%
Packaging: 100mg
Price: $96.8
Updated: 2024/03/01

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(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE Chemical Properties,Usage,Production

Chemical Properties

Orange powder

Uses

It may be used as a chiral ligand in the rhodium complex-catalyzed hydrogenation reaction, a key step during the synthesis of argatroban.

General Description

Mandyphos SL-M004-1 is a chiral ferrocenyl based diphosphine ligand belonging to the Mandyphos family.

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE Preparation Products And Raw materials

Raw materials

Preparation Products

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(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE Suppliers

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View Lastest Price from (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE manufacturers

Career Henan Chemical Co

Product: (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE 494227-37-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200kg
Release date: 2020-03-05

494227-37-1, (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENERelated Search:

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DIPHENYLPHOSPHINO)FERROCENE 1,1'-Bis(diphenylphosphino)ferrocene (+/-)-N,N-DIMETHYL-1-(2-DIPHENYLPHOSPHINO)FERROCENYLETHYLAMINE MONOHYDRATE (3-AMINOPROPYL)DIPHENYLPHOSPHINE N,N-Dimethylaminomethylferrocene (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE (R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE 1,1'-DIETHYLFERROCENE Ferrocene 1,1'-DIMETHYLFERROCENE (R)-(+)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE (+/-)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE BIS(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINE (R)-(S)-BPPFA (R)-(-)-ALPHA-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]BENZYLAMINE

MANDYPHOS SL-M004-1

(aR,aR)-1,1#-Bis[<alpha>-(dimethylamino)benzyl]-(S,S)-2,2#-bis[bis(4-methoxy-3,5

(S,S)-(-)-2,2'-Bis((R)-(N,N-dimethylamino)-(phenyl)methyl)-1,1'-di(bis(3,5-dimethyl-4-methoxyphenyl)phosphino)ferrocene

(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-dimethyl-4-methoxyphenyl)phosphino]ferrocene,min.97%

(r,r)-1,1'-bis[(r)-α-(dimethylamino)phenylmethyl]-2,2'-bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocene (acc to cas)

(αr,αr)-1,1'-bis[α-(dimethylamino)benzyl]-(s,s)-2,2'-bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocene

(SP,SμP)-1,1μ-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2μ-bis[(R)-α-(dimethylamino)benzyl]ferrocene

Mandyphos SL-M004-1, (1R,1μR)- 1,1μ-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2μ-bis[(R)-(dimethylamino)phenylmethyl]ferrocene (acc to CAS)

(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl) methyl]-1,1'-bis[di(3,5-dimethyl-4-methoxyphenyl)phosphino] ferrocene, min. 97%

(R)-(S)-NMe2-P(3,5-Me-4-MeOPh)2-Mandyphos

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE

(R,R)-1,1'-BIS[(R)-ALPHA-(DIMETHYLAMINO)PHENYLMETHYL]-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE

(S,S)-(-)-2,2'-BIS[(R)-(N,N-DIMETHYLAMINO)(PHENYL)METHYL]-1,1'-DI[BIS(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINO]FERROCENE

(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethyL

]-1,1'-bis[di(3,5-dimethyL

amino)(phenyL

(R,R)-1,1'-BIS[(R)-ALPHA-(DIMETHYLAMINO)PHENYLMETHYL]-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCE

(S,S)-(-)-2,2'-Bis[(R)-(N,N-diMethylaMino)(phenyl)Methyl]-1,1'-bis[di(3,5-diMethyl-4-Methoxyphenyl)phosphino]ferrocene

(aR,aR)-2,2'-Bis(α-N,N-dimethylaminophenylmethyl)-(S,S)-1,1'-bis[di-(3,5-dimethyl-4-methoxyphenyl)-phosphino]ferrocene

(SP,S'P)-1,1'-Bis[bis(4-Methoxy-3,5-diMethylphenyl)phosphino]-2,2'-bis[(R)-alpha-(diMethylaMino)benzyl]ferrocene >=97%

-(dimethylamino)benzyl]ferrocene

(1S)-1-[2-bis(4-methoxy-3,5-dimethylphenyl)phosphanylcyclopentyl]-N,N-dimethyl-1-phenylmethanamine

SL-M004-1

(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl) methyl]-1,1'-bis[di(3,5-dimethyl-4-methoxyphenyl)

(αR,αR)-2,2'-Bis(α-N,N-dimethylaminophenylmethyl)-(S,S)-1,1'-bis[di(3,5-dimethyl-4-methoxy-phenyl)phosphino]ferrocene

1,2,3,4,5-Cyclopentanepentayl,1-[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2-[(S)-(dimethylamino)phenylmethyl]-,ironsalt(2:1)

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE

Ferrocene Impurity 3

Deltamethrin Impurity 9

(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-dimethyl-4-methoxyphenyl)phosphino]ferrocene

(S,S)-(-)-2,2'-Bis[(R)-(N,N-diMethylaMino)(phenyl)Methyl]-1,1'-di[bis(3,5-diMethyl-4-Methoxyphenyl)phosphino]ferrocene

494227-37-1

Asymmetric Synthesis

Chiral Catalysts, Ligands, and Reagents

Privileged Ligands

Solvias Ligands

Chiral Phosphine

Ferrocene Series

Mandyphos Series