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4-(bromomethyl)benzaldehyde

Product Name
4-(bromomethyl)benzaldehyde
CAS No.
51359-78-5
Chemical Name
4-(bromomethyl)benzaldehyde
Synonyms
α-Bromo-p-Tolualdehyde;4-(BROMOMETHYL)BENZALDEHYDE;Benzaldehyde,4-(broMoMethyl)-;4-(Bromomethyl)benzaldehyde97%;4-(Bromomethyl)benzaldehyde 97%;4-Formylbenzyl bromide, alpha-Bromo-4-formyltoluene
CBNumber
CB1708152
Molecular Formula
C8H7BrO
Formula Weight
199.04
MOL File
51359-78-5.mol
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4-(bromomethyl)benzaldehyde Property

Melting point:
99 °C
Boiling point:
277.9±15.0 °C(Predicted)
Density 
1.524±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
crystalline powder
color 
Pale lemon
CAS DataBase Reference
51359-78-5
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Safety

Hazard Codes 
C
Safety Statements 
24/25
Hazard Note 
Corrosive
HS Code 
29142990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

TRC
Product number
B694635
Product name
4-(Bromomethyl)benzaldehyde
Packaging
100mg
Price
$45
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB10749
Product name
4-(Bromomethyl)benzaldehyde
Packaging
100mg
Price
$50
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB10749
Product name
4-(Bromomethyl)benzaldehyde
Packaging
250mg
Price
$80
Updated
2021/12/16
Apolloscientific
Product number
OR9193
Product name
4-(Bromomethyl)benzaldehyde
Purity
97%
Packaging
1g
Price
$87
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB10749
Product name
4-(Bromomethyl)benzaldehyde
Packaging
500mg
Price
$130
Updated
2021/12/16
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4-(bromomethyl)benzaldehyde Chemical Properties,Usage,Production

Synthesis

4-(bromomethyl) benzonitrile (1 g, 5.1 mmol) was dissolved in 10 mL of dry toluene and cooled at 0 oC and a portion of 1.08 M DIBALH in hexane (2 equiv.) was added dropwise under nitrogen atmosphere. The solution was stirred for 1 h at 0 oC. The reaction mixture was first diluted with chloroform (15 mL) followed by 34 mL of 10% HCl, and the solution was stirred at room temperature for another 1 h. The organic layer separated was washed with distilled water and dried over anhydrous Na2SO4. The solvent was almost completely removed from the filtrate under reduced pressure, and the residue was washed with ice-cold n-hexane and dried at 50 oC under vacuum to afford 4-(bromomethyl)benzaldehyde. Yield: 70%; 1 H NMR (300 MHz, CDCl3, TMS): δ = 10.02 (s, 1H), 7.86 (m, 2H), 7.57 (m, 2H), 4.52 (s, 2H) ppm[1].

References

[1] Sandeep, Anjamkudy et al. “Supercoiled fibres of self-sorted donor–acceptor stacks: a turn-off/turn-on platform for sensing volatile aromatic compounds?.” Chemical Science 7 (2016): 4460–4467.

4-(bromomethyl)benzaldehyde Preparation Products And Raw materials

Raw materials

Preparation Products

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4-(bromomethyl)benzaldehyde Suppliers

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View Lastest Price from 4-(bromomethyl)benzaldehyde manufacturers

henan kanbei chemical co.,ltd
Product
4-bromomethylbenzaldehyde 51359-78-5
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000kg
Release date
2022-09-19
Career Henan Chemical Co
Product
4-(BROMOMETHYL)BENZALDEHYDE 51359-78-5
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2019-12-26

51359-78-5, 4-(bromomethyl)benzaldehydeRelated Search:

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  • 4-(BROMOMETHYL)BENZALDEHYDE
  • 4-(Bromomethyl)benzaldehyde 97%
  • Benzaldehyde,4-(broMoMethyl)-
  • 4-(Bromomethyl)benzaldehyde97%
  • α-Bromo-p-Tolualdehyde
  • 4-Formylbenzyl bromide, alpha-Bromo-4-formyltoluene
  • 51359-78-5
  • pharmacetical
  • Methyl Halides
  • Phenyls & Phenyl-Het
  • Methyl Halides
  • Phenyls & Phenyl-Het