ChemicalBook > CAS DataBase List > 3,3',4,4'-Biphenyltetracarboxylic dianhydride

3,3',4,4'-Biphenyltetracarboxylic dianhydride

Product Name
3,3',4,4'-Biphenyltetracarboxylic dianhydride
CAS No.
2420-87-3
Chemical Name
3,3',4,4'-Biphenyltetracarboxylic dianhydride
Synonyms
BPDA;S-BPDA;Biphthalicanhydride;S-BDPA;4,4'-Biphthalic anhydrid;4,4'-BIPHTHALIC ANHYDRIDE;4,4'-Biphthalic anhydride;4,4''-Biphthalicanhydride;4,4'-biphthalic dianhydride;4,4'-biphthalic dianhydride
CBNumber
CB1763438
Molecular Formula
C16H6O6
Formula Weight
294.22
MOL File
2420-87-3.mol
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3,3',4,4'-Biphenyltetracarboxylic dianhydride Property

Melting point:
299-305 °C (lit.)
Boiling point:
614.9±48.0 °C(Predicted)
Density 
1.625±0.06 g/cm3(Predicted)
vapor pressure 
0Pa at 20℃
storage temp. 
Inert atmosphere,Room Temperature
solubility 
almost transparency in hot DMF
form 
powder to crystal
color 
Off-white
λmax
300nm(lit.)
InChI
InChI=1S/C16H6O6/c17-13-9-3-1-7(5-11(9)15(19)21-13)8-2-4-10-12(6-8)16(20)22-14(10)18/h1-6H
InChIKey
WKDNYTOXBCRNPV-UHFFFAOYSA-N
SMILES
C1(=O)C2=C(C=C(C3C=CC4C(=O)OC(=O)C=4C=3)C=C2)C(=O)O1
LogP
3.91
CAS DataBase Reference
2420-87-3(CAS DataBase Reference)
NIST Chemistry Reference
3,3',4,4'-Biphenyltetracarboxylic acid dianhydride(2420-87-3)
EPA Substance Registry System
[5,5'-Biisobenzofuran]-1,1',3,3'-tetrone (2420-87-3)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
29173990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
463310
Product name
3,3′,4,4′-Biphenyltetracarboxylic dianhydride
Purity
97%
Packaging
25g
Price
$47.1
Updated
2024/03/01
TCI Chemical
Product number
B1326
Product name
4,4'-Biphthalic Anhydride
Purity
>98.0%(T)
Packaging
25g
Price
$21
Updated
2024/03/01
TCI Chemical
Product number
B4262
Product name
4,4'-Biphthalic Anhydride (purified by sublimation)
Purity
>98.0%(HPLC)
Packaging
5g
Price
$186
Updated
2024/03/01
TCI Chemical
Product number
B1326
Product name
4,4'-Biphthalic Anhydride
Purity
>98.0%(T)
Packaging
100g
Price
$59
Updated
2024/03/01
Biosynth Carbosynth
Product number
FB62603
Product name
4,4'-Biphthalic Anhydride
Packaging
50g
Price
$60
Updated
2021/12/16
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3,3',4,4'-Biphenyltetracarboxylic dianhydride Chemical Properties,Usage,Production

Chemical Properties

BPDA (3,3',4,4'-Biphenyltetracarboxylic dianhydride) is a raw material for the polyimide resin component of one of the super-engineering plastics. It is used for many important information and electronic technology products such as mobile phones and copying machines.

Uses

3,3',4,4'-biphenyltetracarboxylic dianhydride be used for the preparation of a polyimide material.

Uses

s-BPDA can be used in the synthesis of high molecular weight aromatic polyamide fibers. It can also be used in the formation of hybrid nanocomposite films.

Preparation

The preparation of 3,3',4,4'-Biphenyltetracarboxylic dianhydride is as follows:In a nitrogen atmosphere, add N-(3-N,N-dimethylamino-propyl)-4-chlorophthalimide (26.65g, 0.1moL),Zinc powder (3.25g, 0.05moL), anhydrous NiCl2 (127.5mg, 1mmoL),Triphenylphosphine (250mg, 1mmoL) and 70 mL of anhydrous DMAc were stirred at 50°C for 24 hours, and 55mL of solvent DMAc was recovered under reduced pressure. Add 80g of xylene to the system and reflux (recrystallize), filter out the inorganic matter, the clarified filtrate will be cooled and precipitated, filtered, and vacuum dried for 10 hours. 21.8g of 3,3',4,4'-biphenylbisimine was obtained with a yield of 94%. In a 100mL reaction flask, add 4.62g (0.01mol) of the above 3,3',4,4'-biphenylbisimine and 9g of 20% sodium hydroxide aqueous solution, and heat to reflux for 24 hours. Filter and adjust pH=1 with concentrated hydrochloric acid to obtain 3,3’,4,4’-biphenyltetracarboxylic acid. After filtering, wash with water three times and reflux with water with 20mL trimethylbenzene.2.85g of white 3,3′,4,4′-biphenyltetracarboxylic dianhydride was obtained, the yield was 97%.

Application

3,3′,4,4′-biphenyltetracarboxylic dianhydride (BPDA) and 3,3′- and 4,4′-diaminodiphenylsulfones enable to prepare homo- and copolyimides. 3,3',4,4'-Biphenyltetracarboxylic dianhydride is commonly employed to synthesized the aromatic polyimide fibers which is one member of high performance fibers with high strength, high modulus, high and low temperature resistance, and radiation resistance. BPDA could be used to synthesize a series of hyper-cross-linked polymers (HPB-s) with waste polystyrene (WPS) foam. HPB-s has promising potential in purifying dye wastewater[1-2].

General Description

3,3′,4,4′-Biphenyltetracarboxylic dianhydride (s-BPDA) is a rigid symmetric polyamide with a diamine having a long distance between amine groups and reactive endgaps.

Flammability and Explosibility

Non flammable

Advantages

1.Excellent thermal stability
2.Good chemical resistance
3.Stable mechanical properties
4.Polyimide does not require the addition of flame retardants to prevent combustion.

References

[1] Zhao M, et al. Porous Adsorbents Cross-Linked with Waste Polystyrene Foam and 3,3′,4,4′-Biphenyltetracarboxylic Acid Dianhydride for the Effective Removal and Enrichment of Cationic Dyes. ACS Applied Polymer Materials, 2023.
[2] Zhang Q, et al. Morphology of polyimide fibers derived from 3,3′,4,4′-biphenyltetracarboxylic dianhydride and 4,4′-oxydianiline. Journal of Applied Polymer Science, 2004; 93: 669-675.

3,3',4,4'-Biphenyltetracarboxylic dianhydride Preparation Products And Raw materials

Raw materials

Preparation Products

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3,3',4,4'-Biphenyltetracarboxylic dianhydride Suppliers

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View Lastest Price from 3,3',4,4'-Biphenyltetracarboxylic dianhydride manufacturers

Shanghai UCHEM Inc.
Product
3,3',4,4'-Biphenyltetracarboxylic dianhydride 2420-87-3
Price
US $156.00-3250.00/kg
Min. Order
1kg
Purity
0.98
Supply Ability
100kg
Release date
2023-10-13
Wuhan Circle Star Chem-medical Technology Co.,Ltd
Product
3,3',4,4'-Biphenyltetracarboxylic dianhydride 2420-87-3
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98
Supply Ability
1000
Release date
2025-01-21
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
4 Tert Butylcatechol 2420-87-3
Price
US $120.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10ton
Release date
2024-05-21

2420-87-3, 3,3',4,4'-Biphenyltetracarboxylic dianhydrideRelated Search:

MALEIC ANHYDRIDE 1,3-Acetonedicarboxylic acid Pyromellitic Dianhydride 4,4'-(Hexafluoroisopropylidene)diphthalic anhydride 3,4,9,10-Perylenetetracarboxylic dianhydride Potassium hydrogen phthalate 4,4'-Oxydiphthalic anhydride Bis(2-ethylhexyl) phthalate 2,5-PYRIDINEDICARBOXYLIC ACID Benzoic anhydride 4-PHENYLETHYNYLPHTHALIC ANHYDRIDE 2,3,3,4-biphenyl tetracarboxylic dianhydride 3'-FORMYL[1,1'-BIPHENYL]-3-CARBOXYLIC ACID 4,4'-Bis(hydroxymethyl)biphenyl 3-Phenylbenzaldehyde 4-Methylphthalic anhydride m,m'-Dicarboxybiphenyl 4'-METHYLBIPHENYL-4-CARBOXYLIC ACID

  • 3,3',4,4'-Biphenyl tetracarboxylic diandhydride
  • [1,1'-Biphenyl]-3,3',4,4'-tetracarboxylic3,4:3',4'-dianhydride
  • 3,4,3',4'-Biphenyltetracarboxylic acid dianhydride
  • 3,3',4,4'-Biphenyltetracarboxylic dianhydride 97%
  • 4,4'-Biphthalic Anhydride (purified by sublimation)
  • 3,3'4,4'-Biphenyl tetracarboxylic acid dianhydride(s-BPDA)
  • S-BDPA
  • S-BPDA
  • [5,5’-biisobenzofuran]-1,1’,3,3’-tetrone
  • [5,5'-Biisobenzofuran]-1,1',3,3'-tetrone
  • 5,5’-Biisobenzofuran-1,1’,3,3’-tetrone
  • 1,1'-Biphenyl-3,3',4,4'-tetracarboxylic acid-3,4:3',4'-dianhydride
  • 3,3',4,4'-Biphenyltetracarboxylic 3,4:3',4'-dianhydride
  • 5,5'-Bi(1,3-isobenzofurandione)
  • 5,5'-Bi[isobenzofuran-1,3(1H,3H)-dione]
  • 5,5'-Bi[isobenzofuran-1,3-dione]
  • 6,6'-Bi(1,3-isobenzofurandione)
  • 3,3'4,4'-Biphenyl tetracarboxylic acid dianhydride(BPDA)
  • 5-(1,3-diketoisobenzofuran-5-yl)isobenzofuran-1,3-quinone
  • 5-(1,3-dioxo-2-benzofuran-5-yl)-2-benzofuran-1,3-dione
  • 4,4'-biphthalic anhydride ,99%
  • 4-Biphenyltetracarboxylic dianhydride
  • BPDA, 3,3',4,4'-Biphenyltetracarboxylic dianhydride
  • 3,3',4,4'-Biphenyltetracarboxylic dianhydride (s-BPDA)
  • 3,3',4,4'-Biphenyltetracarboxylic dianhydride 2420-87-3
  • 4,4'-Biphthalic Anhydride 2420-87-3
  • s-BPDA/3,3',4,4'-Biphenyltetracarboxylic dianhydride
  • 5-(1,3-dioxoisobenzofuran-5-yl)isobenzofuran-1,3-dione
  • DIPHENYL-3,3',4,4'-TETRACARBOXYLIC DIANHYDRIDE
  • 4,4'-BIPHTHALIC ANHYDRIDE
  • 3,4:3',4'-BIPHENYLTETRACARBOXYLIC DIANHYDRIDE
  • 3,3',4,4'-BIPHENYLTETRACARBOXYLIC ACID DIANHYDRIDE
  • 3,3',4,4'-BIPHENYLTETRACARBOXYLIC DIANHYDRIDE
  • Biphthalicanhydride
  • 4,4'-biphthalic dianhydride
  • 3,3',4,4'-Biphenyltetracarboxylic
  • 3,3',4,4'-BIPHENYLTETRACARBOXYLIC ACID ANHYDRIDE
  • biphenyl-3,3',4,4'-tetracarboxylic acid dianhydride
  • 4,4'-Biphthalic anhydrid
  • 3,3'',4,4''-BIPHTHALIC ANHYDRIDE
  • 3,3'',4,4''-BIPHENYLTETRACARBOXYLIC DIANHYDRIDE (BPDA)
  • 4,4''-BIPHTHALIC ANHYDRIDE ---POWDER, PURITY 98%---
  • 3,4,3'',4''-TETRA CARBONIC DI ANHYDRIDE
  • 4,4'-Biphthalic Anhydride (purified by sublimation)&gt
  • 4,4'-Biphthalic Anhydride &gt
  • 3,3,4,4-Biphenyltetracarboxylic Dianhydride,>98%
  • Biphenyltetracarboxy lic dianhydride
  • 3,3',4,4'-BIPHENYLTETRACARBOXYLIC DIANHYDRIDE (S-BPDA)2420-87-3
  • BPDA
  • 3,3',4,4'-Biphenyltetracarboxylic dianhydride,NA
  • 3,3',4,4'-biphenyltetracarboxylic anhydride S-BPDA
  • 3,3',4,4'-Biphenyltetracarboxylic
  • 3,3',4,4'-Biphenyltetracarboxylic dianhydride (BPDA)
  • 3,3',4,4'-Biphenyltetracarboxylic dianhydride
  • 5,5'-Biisobenzofuran]-1,1',3,3'-tetraone
  • 4,4'-Biphthalic anhydride
  • 3,3',4,4'-biphenyltetracarboxylic anhydride
  • 4,4''-Biphthalicanhydride