2-Chloro-1-propanol
- Product Name
- 2-Chloro-1-propanol
- CAS No.
- 78-89-7
- Chemical Name
- 2-Chloro-1-propanol
- Synonyms
- VPM-4G;Nsc122672;2-Chloropropanol;2-chloro-1-propano;MONOCHLOROPROPANOL;2-Chloro-1-propanol;2-chloropropan-1-ol;2-chloro-propan-1-ol;PROPYLENECHLORHYDRIN;2-chloropropylalcohol
- CBNumber
- CB1851586
- Molecular Formula
- C3H7ClO
- Formula Weight
- 94.54
- MOL File
- 78-89-7.mol
2-Chloro-1-propanol Property
- Melting point:
- <25 °C
- Boiling point:
- bp 133-134°
- Density
- d20 1.103
- refractive index
- nD20 1.4362
- storage temp.
- Refrigerator
- solubility
- Chloroform (Slightly), Methanol (Sparingly)
- pka
- 14.16±0.10(Predicted)
- form
- Oil
- color
- Colourless
- Odor
- pleasant odor
- Exposure limits
- No exposure limit is set. However, on the basis of its similar toxic properties to ethylene chlorohydrin, a TLV-TWA air 10 ppm (approximately 40 mg/m3) is recommended.
- LogP
- 0.268 (est)
- CAS DataBase Reference
- 78-89-7
- EPA Substance Registry System
- 2-Chloro-1-propanol (78-89-7)
Safety
- RIDADR
- 2611
- HazardClass
- 6.1(a)
- PackingGroup
- II
- Hazardous Substances Data
- 78-89-7(Hazardous Substances Data)
- Toxicity
- LD50 orally in rats: 0.22 ml/kg; by skin penetration in rabbits: 0.48 ml/kg, Smyth et al., Am. Ind. Hyg. Assoc. J. 30, 470 (1969)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H226Flammable liquid and vapour
H302Harmful if swallowed
H312Harmful in contact with skin
H319Causes serious eye irritation
H332Harmful if inhaled
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P312Call a POISON CENTER or doctor/physician if you feel unwell.
P322Specific measures (see …on this label).
P330Rinse mouth.
P363Wash contaminated clothing before reuse.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- FC146292
- Product name
- 2-Chloro-1-propanol
- Packaging
- 100mg
- Price
- $125
- Updated
- 2021/12/16
- Product number
- FC146292
- Product name
- 2-Chloro-1-propanol
- Packaging
- 250mg
- Price
- $250
- Updated
- 2021/12/16
- Product number
- FC146292
- Product name
- 2-Chloro-1-propanol
- Packaging
- 500mg
- Price
- $400
- Updated
- 2021/12/16
- Product number
- HCH0199099
- Product name
- 2-CHLORO-1-PROPANOL
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $496.2
- Updated
- 2021/12/16
- Product number
- FC146292
- Product name
- 2-Chloro-1-propanol
- Packaging
- 1g
- Price
- $600
- Updated
- 2021/12/16
2-Chloro-1-propanol Chemical Properties,Usage,Production
Chemical Properties
Propylene chlorohydrin is a colorless liquid.
Chemical Properties
Colorless liquid; mild, nonresidual odor. Soluble in water and alcohol.
Uses
In preparation of propylene oxide, q.v.
Uses
Propylene β-chlorohydrin is used in the pro duction of propylene oxide.
Uses
2-Chloropropanol is used as a solvent in the composition and method for removing a coating from a surface. 2-Chloropropanol is used as an organic solvent in liquid cleaner for the removal of post-etch residues from microsprocessors.
Synthesis Reference(s)
Journal of the American Chemical Society, 72, p. 4353, 1950 DOI: 10.1021/ja01166a005
General Description
Clear colorless liquid with a pleasant odor.
Air & Water Reactions
Water soluble.
Reactivity Profile
2-Chloro-1-propanol may be sensitive to prolonged exposure to light. 2-Chloro-1-propanol can react with oxidizing agents. .
Hazard
Moderate fire risk. Toxic by ingestion and skin absorption. Liver damage. Questionable car- cinogen.
Health Hazard
Propylene β-chlorohydrin is a moderatelytoxic compound having irritant actions onthe skin and eyes. Instilling 2.2 mg of liquidcaused severe eye irritation in rabbits. It cancause poisoning via ingestion, inhalation, andskin absorption. Exposure to 500 ppm for4 hours was lethal to rats. The lethal dosein dogs by oral intake was 200 mg/kg. Thetarget organs are the CNS, gastrointestinalsystem, liver, and kidney.
LD50 value, skin (rabbits): 529 mg/kg
Studies conducted to determine increasedrisks of pancreatic and lymphopoietic can cer among workers in ethylene and propylene chlorohydrin production remained inconclu sive and have given inconsistent findings(Olsen et al. 1997).
Fire Hazard
2-Chloro-1-propanol is flammable.
Safety Profile
Poison by ingestion. Moderately toxic by inhalation and skin contact. A skin and severe eye irritant. Flammable liquid when exposed to heat, flame, or powerful oxidizers. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits toxic fumes of Cl-.
Potential Exposure
This material is used in organic synthesis; to make other chemicals.
Shipping
UN2611Propylene chlorohydrin, Hazard class: 6.1; Labels: 6.1-Poisonous materials, 3-Flammable liquid.
Incompatibilities
Vapor may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Alcohols are sensitive to light and oxi- dation. It is unstable in solution. It undergoes hydrolysis in aqueous buffers. Contact with alkali metals, nitrides, and strong reducing agents may form flammable and/or toxic gases. May react with anhydrides forming acids and esters, generating noticeable heat, and also with oxoacids and carboxylic acids to form esters plus water, but the heat of reaction in the latter case typically is low. May initiate the polymerization of isocyanates and epoxides.
Waste Disposal
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.
2-Chloro-1-propanol Preparation Products And Raw materials
Raw materials
Preparation Products
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