Water peak Application
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Chloroform-d

Water peak Application
Product Name
Chloroform-d
CAS No.
865-49-6
Chemical Name
Chloroform-d
Synonyms
deuterated chloroform;CHLOROFORM-D1;Deuteriochloroform;Deuterotrichloromethane;Methane-d, trichloro-;Chloroform-d, 99.8 atom % D, anhydrous;CHLOROFORM-D, 99.8 ATOM % D(CONTAINS 1%V/V TMS);Chloroform-d,for NMR,100.0 atom % D, packagedin 0.50 ml ampules;oroform-d;d,ChloroforM
CBNumber
CB2103569
Molecular Formula
CCl3D
Formula Weight
120.38
MOL File
865-49-6.mol
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Chloroform-d Property

Melting point:
−64 °C(lit.)
Boiling point:
60.9 °C(lit.)
Density 
1.500 g/mL at 25 °C(lit.)
vapor pressure 
211 hPa (20 °C)
refractive index 
n20/D 1.444(lit.)
Flash point:
62°C
storage temp. 
Store at +2°C to +8°C.
solubility 
Miscible with organic solvents, ethyl acetate and acetone.
form 
Liquid
Specific Gravity
1.505
color 
White to beige
Sensitive 
Moisture Sensitive
BRN 
1697633
Exposure limits
ACGIH: TWA 10 ppm
OSHA: Ceiling 50 ppm(240 mg/m3)
NIOSH: IDLH 500 ppm; STEL 2 ppm(9.78 mg/m3)
Stability:
Stable. Incompatible with strong bases, alkali metals, aluminium, magnesium, strong oxidizing agents.
InChIKey
HEDRZPFGACZZDS-MICDWDOJSA-N
LogP
1.5-1.6 at 20-23℃ and pH9
Surface tension
72.3mN/m at 998.5mg/L and 20℃
CAS DataBase Reference
865-49-6(CAS DataBase Reference)
EPA Substance Registry System
Chloroform-d (865-49-6)
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Safety

Hazard Codes 
Xn,T
Risk Statements 
22-38-40-48/20/22-48/20-36/38-20/22-63
Safety Statements 
36/37
RIDADR 
UN 1888 6.1/PG 3
WGK Germany 
2
HazardClass 
6.1
PackingGroup 
III
HS Code 
28459000
Toxicity
LD50 orally in Rabbit: 695 mg/kg LD50 dermal Rabbit > 3980 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H331Toxic if inhaled

H336May cause drowsiness or dizziness

H351Suspected of causing cancer

H372Causes damage to organs through prolonged or repeated exposure

Precautionary statements

P201Obtain special instructions before use.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
151823
Product name
Chloroform-d
Purity
99.8 atom % D
Packaging
10x0.6ml
Price
$38.4
Updated
2024/03/01
Sigma-Aldrich
Product number
151823
Product name
Chloroform-d
Purity
99.8 atom % D
Packaging
10x0.75ml
Price
$40.2
Updated
2024/03/01
Sigma-Aldrich
Product number
1.03420
Product name
Chloroform-D1
Purity
deuteration degree min. 99.8% for NMR spectroscopy (stabilized with silver) MagniSolv?
Packaging
25mL
Price
$43.4
Updated
2024/03/01
Sigma-Aldrich
Product number
1.03420
Product name
Chloroform-D1
Purity
deuteration degree min. 99.8% for NMR spectroscopy (stabilized with silver) MagniSolv?
Packaging
100mL
Price
$109
Updated
2024/03/01
Sigma-Aldrich
Product number
1.03420
Product name
Chloroform-D1
Purity
deuteration degree min. 99.8% for NMR spectroscopy (stabilized with silver) MagniSolv?
Packaging
500mL
Price
$449
Updated
2024/03/01
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Chloroform-d Chemical Properties,Usage,Production

Water peak

The position of the water peak in different deuterated reagents is not the same. The water peak of heavy water is about 4.67 ppm. There is a trend that the more water the low field.
Chloroform-D is less soluble with water and the water content is low, so its water peak near 1.59 ppm. Deuterated acetone is about 2.8 ppm and the deuterated dimethylsulfoxide has a water peak of about 3.4 ppm. If water is added to deuterated acetone, the water peak will gradually move to a low field and eventually stop at about 4.7 ppm.

Application

Reagents for nuclear magnetic instruments

Chemical Properties

colourless liquid

Uses

Chloroform-d is widely used in the organic solvent for the NMR analysis.

Uses

Chloroform-d may be used in the synthesis of dichlorofluoromethane-d (DCFM).

Uses

Labelled Chloroform, generally in trimethylsilane solution, used in NMR spectroscopy as a solvent. Unlabelled chloroform has been used an an anaesthetic due to its action on the central nervous system .

Definition

ChEBI: Deuterated chloroform is a deuterated compound that is an isotopologue of chloroform in which the hydrogen atom is replaced with deuterium. Commonly used as a solvent in proton NMR spectroscopy. It has a role as a non-polar solvent, a NMR solvent and a NMR chemical shift reference compound. It is a deuterated compound and a member of chloromethanes.

General Description

Chloroform-d (Deuterochloroform, CDCl3), deuterated chloroform, is a 100% isotopically enriched NMR (Nuclear Magnetic Resonance) solvent. It is widely employed in high resolution NMR studies due to its high chemical and isotopic purity. Quantitaive infrared spectral investigations of carbon-deuterium stretching bands of chloroform-d in various organic solvents have been reported. Raman difference spectroscopic studies of mixtures of chloroform-d and liquid chloroform have been conducted to evaluate frequency shifts in the in the ν1 and ν2 bands of CHCl3 and CDCl3.

Chloroform-d Preparation Products And Raw materials

Raw materials

Preparation Products

4-AMINO-3-FORMYLPYRIDINE
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Chloroform-d Suppliers

Americas 1 Belgium 1 Canada 3 China 155 Europe 4 France 3 Germany 4 India 8 Japan 4 Switzerland 1 United Kingdom 7 United States 18 Global 209
Ningbo cuiying chemical technology co. LTD
Tel
4008-608250 18957423231
Email
2317559463@qq.com
Country
China
ProdList
223
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58
Nanjing Haolv Biotechnology Co.,Ltd
Tel
025-84622273 02584622273;
Email
kexin.zhou@haolvbiotech.com
Country
China
ProdList
3021
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58
Shanghai Jizhi Biochemical Technology Co. Ltd.
Tel
400-400-400-9004166 18616739031
Email
3007523370@qq.com
Country
China
ProdList
52712
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58
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
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62
Wuhan eastop Technology Co., ltd.6
Tel
027-027-87382885 18086641195
Fax
027-87382885
Email
service@isotopechina.com
Country
China
ProdList
155
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58
Qingdao Tenglong microwave technology co., LTD.
Tel
0532-83818797 18561885118
Email
market@tlwb.com.cn
Country
China
ProdList
3946
Advantage
58
Shanghai Maclean Biochemical Technology Co., LTD
Tel
021-50706066 15221275939
Email
shenlinxing@macklin.cn
Country
China
ProdList
29803
Advantage
58
Changzhou Xuanming Pharmaceutical Technology Co., Ltd.
Tel
0519-85525329 15995069468
Fax
0519-85190960
Email
29526743@qq.com
Country
China
ProdList
312
Advantage
58
Shanghai isotope chemical co.,ltd
Tel
021-021-51600108 13062666369
Email
sales@chinaisotope.com
Country
China
ProdList
4272
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94838
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76
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View Lastest Price from Chloroform-d manufacturers

Henan Fengda Chemical Co., Ltd
Product
Chloroform-d 865-49-6
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-23
Hebei Duling International Trade Co. LTD
Product
Chloroform-d 865-49-6
Price
US $30.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 tons
Release date
2023-03-30
Hangzhou ICH Biofarm Co., Ltd
Product
Chloroform-D 865-49-6
Price
US $0.00/kg
Min. Order
200kg
Purity
99%
Supply Ability
plenty of stock
Release date
2023-07-05

865-49-6, Chloroform-dRelated Search:

Ethyl (2,4,6-trimethylbenzoyl) phenylphosphinate 5α-Cholestane NMR REF STD, 0.0485M TRIPHENYLPHOSPHATE IN CHLOROFORM-D, 99.9 ATOM % D,NMR REF STD, 0.0485M TRIPHENYLPHOSPHATEIN CHLOROFORM-D,99.8 ATOM % D PHENOL:CHLOROFORM:ISOAMYLALCOHOL 49.5:49 .5:1,PHENOL:CHLOROFORM:ISOAMYL ALC. 125:24:1, FOR MOL. BIOLOGY BETA-SITOSTEROL 1X1ML CHLOROFORM 100UG/M L Dichloromethane 100 MG/ML CHOLESTERYL ACETATE IN CHLOROFORM-D Chloroform Chloroform-d DICHLOROMETHANE D CHLOROFORM-D + 1% TMS (V/V) ACETONE-D6 ACETONE CHLOROFORM HEMIHYDRATE DAB, PH. EUR., B.P., N. F., PH. FRANC. TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM(0) CHLOROFORM ADDUCT 98+% METHANE (D1) DEUTERIUM HYDRIDE 0.1% ETHYLBENZENE IN CHLOROFORM-D (540 PP TUBE) 30% MENTHOL IN CHLOROFORM-D

  • Deuterotrichloromethane
  • Trichloro(2H)methane
  • trichloro-deuterio-methane
  • CHLOROFORM-D >99.95 (ATOM % D) STAB.
  • CHLOROFORM-D, "100" (MIN. 99.96 ATOM % D)(1PK=10 X 0.75ML)
  • CHLOROFORM-D, "100" (MIN. 99.96 ATOM % D)(1PK=10 X 0.25ML)
  • Chloroform-d, 99.8 atom % D, anhydrous
  • CHLOROFORM-D, 99.8 ATOM % D(CONTAINS 1%V/V TMS)
  • CHLOROFORM-D, 99.8 ATOM % D, STABILIZEDWITH 0.5 WT% SILVER FOIL (CONTAINS 0.03%(
  • CHLOROFORM-D, "100" (MIN. 99.96 ATOM % D) CONTAINS 0.03% V/V TMS(1PK=10 X 0.75ML
  • CHLOROFORM-D, 99.9 ATOM % D (CONTAINS 0.03% V/V TMS)
  • CHLOROFORM-D, 99.8 ATOM % D (CONTAINS 0.03% V/V TMS)
  • CHLOROFORM-D, "100" (MIN. 99.96 ATOM % D) CONTAINS 0.03% V/V TMS
  • Chloroform-D,IsotopicPurity>99Atom%D
  • Chloroform-d, isotopic purity
  • Chloroform-d,100%D(Isotopic),contains0.03%v/vTMS
  • Chloroform-d,99.8%(Isotopic),contains0.03%v/vTMS
  • Chloroform-d, 100 atom % D, packaged in 0.75 ml ampules, for NMR
  • Chloroform-d, 100.0 atom % D, for NMR
  • Chloroform-d, 100.0 atom % D, packaged in 0.50 ml ampules, for NMR
  • Chloroform-d, 99.6+ atom % D, for NMR
  • Chloroform-d, 99.8 atom % D, contains 1 v/v% TMS, for NMR
  • Chloroform-d, 99.8 atom % D, for NMR
  • Chloroform-d, 99.8 atom % D, packaged in 0.75 ml ampules, for NMR
  • Chloroform-d, 99.8 atom % D, packaged in 1 ml ampules, for NMR
  • Chloroform-d, 99.8 atom % D, stabilized with silver foil, for NMR
  • Chloroform-d, 99.8% D, stabilized with silver foil, 1 v/v% TMS, for NMR
  • Chloroform-d, 99.8+ atom % D, contains 0.03 v/v% TMS, for NMR
  • Chloroform-d, 99.8+% D, stab. with silver foil, 0.03 v/v% TMS, for NMR
  • ChloroformD>99.96%10x0.75ml
  • ChloroformD>99.96%+0.03%tms
  • ChloroformD>99.8%+0.03%tms
  • ChloroformD>99.8%10x0.75ml
  • ChloroformD>99.8%5x10ml
  • ChloroformD>99.96%10x0.6ml
  • ChloroformD>99.96%
  • ChloroformD>99.96%10x0.75ml(+0.03%tms)
  • Chloroform-d,for NMR,100.0 atom % D, packagedin 0.50 ml ampules
  • Chloroform-d,for NMR,99.8+ atom % D, contains0.03 v/v% TMS
  • Chloroform-d,for NMR,contains 0.03 v/v% TMS,99.8+ atom % D
  • Chloroform-d,for NMR,99.8 atom % D
  • Chloroform-d,for NMR,99.6+ atom % D
  • Chloroform-d,for NMR,99.8 atom % D, contains1 v/v% TMS
  • Chloroform-d,for NMR,99.8% D, stabilized withsilver foil, 1 v/v% TMS
  • Chloroform-d,for NMR,100 atom % D, packaged in 0.75 ml ampules
  • Chloroform-d,for NMR,99.8 atom % D, packagedin 1 ml ampules
  • Chloroform-d,for NMR,99.8+% D, stab. with silver foil, 0.03 v/v% TMS
  • Chloroform-d,for NMR,99.8 atom % D, packagedin 0.75 ml ampules
  • Chloroform-d,for NMR,99.8 atom % D, stabilized with silver foil
  • Chloroform-d,Deuterochloroform
  • Chloroform-d "100%" - DELETED
  • Chloroform-d, (D99.8%)+TMS(0.03%)
  • Chloroform-d, 100 atom % D, packaged in 0.75 ml ampoules, for NMR
  • Chloroform-d, 99.8 atom % D, packaged in 0.75 ml ampoules, for NMR
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  • Chloroform-d, 99.8 atom % D, AcroSeal, for NMR
  • ChloroforM-d, for NMR, 99.8 atoM % D, packaged in 1 Ml aMpoules
  • ChloroforM-d, for NMR, 100 atoM % D, packaged in 0.75 Ml aMpoules