1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate

Product Name: 1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
CAS No.: 35193-63-6
Chemical Name: 1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
Synonyms: BNDHP;(R)-(-)-BNP ACID;(R)-(-)-BPA;(R)-(-)-BNPA;(S)-(+)-BPA;(S)-(+)-BNPA;(S)-(+)-BNP ACID;Einecs 252-425-8;1,1'-Biphthyl-2,2'-diyl hydrogenphosphate;1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE
CBNumber: CB2107330
Molecular Formula: C20H13O4P
Formula Weight: 348.29
MOL File: 35193-63-6.mol

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1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Property

Melting point:: ≥300 °C
Boiling point:: 619.5±38.0 °C(Predicted)
Density: 1.49±0.1 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
pka: 1.14±0.20(Predicted)
form: Solid
color: White to Yellow to Orange
optical activity: Consistent with structure
Water Solubility: Extremely low soluble in water.
InChI: InChI=1S/C20H13O4P/c21-25(22)23-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)24-25/h1-12H,(H,21,22)
InChIKey: JEHUZVBIUCAMRZ-UHFFFAOYSA-N
SMILES: O1C2=CC=C3C(=C2C2=C4C(C=CC=C4)=CC=C2OP1(=O)O)C=CC=C3
CAS DataBase Reference: 35193-63-6(CAS DataBase Reference)

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 36/37/38-20/21/22
Safety Statements: 26-36-36/37/39-22
WGK Germany: 3
RTECS: RZ2475100
F: 10-23
HS Code: 2931499090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 292966
Product name: 1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate
Purity: 95%
Packaging: 5g
Price: $96.44
Updated: 2025/07/31

TCI Chemical

Product number: B2130
Product name: (+/-)-1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate
Purity: >98.0%(HPLC)(T)
Packaging: 5g
Price: $72
Updated: 2025/07/31

TCI Chemical

Product number: B2130
Product name: (+/-)-1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate
Purity: >98.0%(HPLC)(T)
Packaging: 25g
Price: $259
Updated: 2025/07/31

AK Scientific

Product number: O732
Product name: 1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate
Packaging: 1g
Price: $17
Updated: 2021/12/16

ChemScene

Product number: CS-0031445
Product name: 1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate
Purity: 99.88%
Packaging: 25g
Price: $62
Updated: 2021/12/16

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1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, is used as a chiral chemical compound, a chiral ligand used in hydrocarboxylation reactions. Complexes with rhodium and mediates the asymmetric dipolar cycloaddition of diazo compounds. A number of racemic amines which have proven difficult to separate have been resolved with this chiral acid. Palladium derivatives have been used in asymmetric hydrocarboxylations, and rhodium derivatives have been used in dipolar cycloadditions.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling

1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Preparation Products And Raw materials

Raw materials

Preparation Products

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1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Suppliers

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View Lastest Price from 1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: 1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate 35193-63-6
Price: US $0.10/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 1000 tons
Release date: 2025-09-11

Hebei Chuanghai Biotechnology Co., Ltd

Product: 1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate 35193-63-6
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-11-18

XINXIANG RUNYU MATERIAL CO., LTD.

Product: 1,1'-Binaphthyl-2,2'-diylhydrogenphosphate 35193-63-6
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 99%+
Supply Ability: 250kg
Release date: 2024-11-19

35193-63-6, 1,1'-Binaphthyl-2,2'-diyl hydrogenphosphateRelated Search:

naphthidine Iron oxide black Clindamycin phosphate SULPHOSUCCINIC ACID ESTER Zinc oxide NITRIC OXIDE Magnesium oxide (S)-(-)-1,1'-Bi-2-naphthol ETHYLENE OXIDE 1,1'-Bi-2-naphthol Iron oxide Rutile (Diethoxymethyl)diphenylphosphine oxide Water treatment agent POE NITROUS OXIDE (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate, min. 98%,(S)-(+)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE,S-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE (R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate 1,1'-BINAPHTHYL

(+/-)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE

1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE

(+/-)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE

2-HYDROXY-2LAMBDA5-DINAPHTHO[2,1-D:1,2-F][1,3,2]DIOXAPHOSPHEPIN-2-ONE

4-Hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin 4-oxide

(R)-(-)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE

(R)-4-HYDROXY DINAPHTHO[2,1-D:1',2'-F][1,3,2]-DIOXAPHOSPHEPIN-4-OXID

(R)-4-HYDROXYDINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE

R(-)-1,1'-BI-2-NAPHTHYL-2,2'-DIYL HYDROGEN PHOSPHATE

(R)-(-)-1,1'-BINAPHTHALENE-2,2'-DIYL-PHOSPHATE

(R)-(-)-1,1'-BINAPHTHALENE-2,2'-DIYL HYDROGEN PHOSPHATE

(S)-(+)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE

(S)-(+)-1,1'-BINAPHTHELENE-2,2'-DIYL-PHOSPHATE

S(+)-1,1'-BI-2-NAPHTHYL-2,2'-DIYL HYDROGEN PHOSPHATE

(S)-(-)-1,1'-BINAPHTHALENE-2,2'-DIYL HYDROGEN PHOSPHATE

S(+)-1,1'-BINAPHTHALENE-2,2'-DIYL HYDROGEN PHOSPHATE

(R)-(-)-BPA

(R)-(-)-BNP ACID

(R)-(-)-BNPA

(S)-4-HYDROXYDINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE

(S)-4-HYDROXY DINAPHTHO[2,1-D:1',2'-F][1,3,2]-DIOXAPHOPHEPIN-4-OXID

(S)-(+)-BPA

(S)-(+)-BNPA

(S)-(+)-BNP ACID

(+/-)-1,1-ALPHA'-BINAPHTHYL-2,2-ALPHA'-DIYL HYDROGENPHOSPHATE

(+/-)-1,1''-BINAPHTHYL-2,2''-DIYL HYDROGENPHOSPHATE 99%

Einecs 252-425-8

Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 4-hydroxy-, 4-oxide

Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-ol 4-oxide, BNDHP

BNDHP

1,1-Binaphthyl-2,2-diyl hydrogenphosphate≥ 99% (HPLC)

1,1'-Biphthyl-2,2'-diyl hydrogenphosphate

rac-1,1'-Binaphthyl-2,2'-diyl-hydrogenphosphate

(+/-)-1,1′-Binaphtyl-2,2′-diyl hydrogenphosphate

(+/-)-1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate &gt

1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 99%,

(±)-1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate

4-Hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

(±)-1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate

1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate, CAS 35193-63-6

(+/-)-1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate

4-Hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate - [B94047]

35193-63-6

C20H13O4P

for Resolution of Bases

e.e. / Absolute Conefiguration Determination (NMR)

Optical Resolution

Enantiomer Excess & Absolute Conefiguration Determination

Chiral Resolution Reagents

Catalysis and Inorganic Chemistry

Asymmetric Synthesis

Phosphorus Catalysts

Phosphorus Compounds

Chiral Resolving Reagents

Achiral Phosphine

Aryl Phosphine

Phosphorus Catalysts