ChemicalBook > CAS DataBase List > (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a

(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a

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Product Name: (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
CAS No.: 252288-04-3
Chemical Name: (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
Synonyms: 3,4-a']dinaphthalen-4-yl)diethylamine;3,4-a'']dinaphthalen-4-yl)diethylamine;3,4-a']dinaphthalen-4-yl)diethylamine,97%;3,4-a']dinaphthalen-4-yl)diethylamine,min.97%;3,4-a']dinaphthalen-4-yl)diethylamine, min. 97%;(S)-N,N-Diethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine;(S)-N,N-Diethyldinaphtho[2,1-d:1',2'-f][1,3,2]-dioxaphosphepin-4-amine;(11bS)-N,N-Diethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine;Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N-diethyl-, (11bS)-;(11bS)-N,N-Diethyl-dinaphtho[2,1-d:1',2'-f][1,3,2] dioxaphosphepin-4-amine,99%e.e.
CBNumber: CB21180996
Molecular Formula: C24H22NO2P
Formula Weight: 387.41
MOL File: 252288-04-3.mol

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(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Property

Boiling point:: 566.4±33.0 °C(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
pka: 1.71±0.20(Predicted)
form: Powder
color: white
Sensitive: moisture sensitive

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Strem Chemicals

Product number: 15-1231
Product name: (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)diethylamine, min. 97%
Packaging: 250mg
Price: $68
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1231
Product name: (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)diethylamine, min. 97%
Packaging: 1g
Price: $200
Updated: 2024/03/01

Matrix Scientific

Product number: 093081
Product name: (S)-N,N-Diethyldinaphtho[2,1-d:1',2'-f][1,3,2]-dioxaphosphepin-4-amine
Purity: 95+%
Packaging: 250mg
Price: $167
Updated: 2021/12/16

Matrix Scientific

Product number: 093081
Product name: (S)-N,N-Diethyldinaphtho[2,1-d:1',2'-f][1,3,2]-dioxaphosphepin-4-amine
Purity: 95+%
Packaging: 1g
Price: $370
Updated: 2021/12/16

Matrix Scientific

Product number: 093081
Product name: (S)-N,N-Diethyldinaphtho[2,1-d:1',2'-f][1,3,2]-dioxaphosphepin-4-amine
Purity: 95+%
Packaging: 5g
Price: $1229
Updated: 2021/12/16

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(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Chemical Properties,Usage,Production

Reaction

Ligand used in the enantioselective rhodium catalyzed low pressure high activity hydrogenation of α–dehydroaminoesters, enamides, and dimethylitaconate.
Ligand used in enantioselective rhodium-catalyzed allylic C–H activation for addition to conjugated dienes.

(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Preparation Products And Raw materials

Raw materials

Preparation Products

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252288-04-3, (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-aRelated Search:

3,4-a']dinaphthalen-4-yl)dipropylaMine (11bS)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine (11bS)-8,9,10,11,12,13,14,15-octahydro-N,N-bis[(1S)-1-phenylethyl]-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-aMine N,N-diisopropyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (+)-N,N-BIS[(1R)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)

3,4-a']dinaphthalen-4-yl)diethylamine,min.97%

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A'']DINAPHTHALEN-4-YL)DIETHYLAMINE, MIN. 97%

(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)diethylamine

3,4-a']dinaphthalen-4-yl)diethylamine

3,4-a']dinaphthalen-4-yl)diethylamine, min. 97%

(S)-N,N-Diethyldinaphtho[2,1-d:1',2'-f][1,3,2]-dioxaphosphepin-4-amine

(11bS)-N,N-Diethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

(11bS)-N,N-Diethyl-dinaphtho[2,1-d:1',2'-f][1,3,2] dioxaphosphepin-4-amine,99%e.e.

3,4-a']dinaphthalen-4-yl)diethylamine,97%

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A;3,4-A']DINAPHTHALEN-4-YL)DIETHYLAMINE,MIN.97%

Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N-diethyl-, (11bS)-

3,4-a'']dinaphthalen-4-yl)diethylamine

(S)-N,N-Diethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

252288-04-3

Chiral Phosphine

CPN