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Palladium(II) oxide

Product Name
Palladium(II) oxide
CAS No.
1314-08-5
Chemical Name
Palladium(II) oxide
Synonyms
CL067;oxopalladium;PaladiumOxide;PALLADIUM OXIDE;Pallasium(Ⅱ)Oxide;PALLADIUM(Ⅱ)OXIDE;PALLADIUM(+2)OXIDE;PALLADIUM MONOXIDE;PALLADIUM(II) OXIDE;palladiumoxide(pdo)
CBNumber
CB2131887
Molecular Formula
OPd
Formula Weight
122.42
MOL File
1314-08-5.mol
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Palladium(II) oxide Property

Melting point:
870 °C(lit.)
Density 
8.7 g/mL at 25 °C(lit.)
RTECS 
RT3592900
storage temp. 
Store below +30°C.
solubility 
insoluble in H2O, acid solutions; slightly soluble in aquaregia
form 
Viscous Liquid
Specific Gravity
8.7
color 
Gray to black
Odor
Odorless
Water Solubility 
practically insoluble
Merck 
14,6993
crystal system
square
Space group
P42/mmc
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.3030.3030.5339090900.0489
InChIKey
HBEQXAKJSGXAIQ-UHFFFAOYSA-N
CAS DataBase Reference
1314-08-5(CAS DataBase Reference)
NIST Chemistry Reference
Palladium oxide(1314-08-5)
EPA Substance Registry System
Palladium oxide (PdO) (1314-08-5)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
RIDADR 
1479
WGK Germany 
3
TSCA 
Yes
PackingGroup 
II
HS Code 
28439090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H272May intensify fire; oxidizer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P220Keep/Store away from clothing/…/combustible materials.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378In case of fire: Use … for extinction.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
520748
Product name
Palladium(II) oxide
Purity
99.97% trace metals basis
Packaging
1g
Price
$184
Updated
2024/03/01
Sigma-Aldrich
Product number
8.07107
Product name
Palladium(II) oxide (85% Pd)
Purity
hydrogenation catalyst for synthesis
Packaging
500mg
Price
$363
Updated
2024/03/01
Sigma-Aldrich
Product number
520748
Product name
Palladium(II) oxide
Purity
99.97% trace metals basis
Packaging
5g
Price
$732
Updated
2024/03/01
Sigma-Aldrich
Product number
8.07107
Product name
Palladium(II) oxide (85% Pd)
Purity
hydrogenation catalyst for synthesis
Packaging
1g
Price
$526
Updated
2023/01/07
Alfa Aesar
Product number
011040
Product name
Palladium(II) oxide, anhydrous, 99.9% (metals basis), Pd 85% min
Packaging
1g
Price
$261
Updated
2023/06/20
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Palladium(II) oxide Chemical Properties,Usage,Production

Chemical Properties

grey to black powder

Physical properties

Greenish black tetragonal crystals; density 8.3 g/cm3; decomposes to Pd metal at 750°C; insoluble in water and acids; slightly soluble in aqua regia.

Uses

Catalytic reduction, in organic synthesis.Palladium(II) oxide is used as a catalyst for reduction in organic synthesis. It is an excellent gas sensing material for carbon monoxide at low working temperatures. It is also used in the preparation of good optical quality films. It is involved in the preparation of LuPd2O4 , which is used in superconducting materials.

Uses

Palladium(II) oxide is used to prepare palladium catalyst for hydrogenation. The oxide is readily reduced by hydrogen to metal.

Uses

Reduction catalyst in synthesis of organic Compounds.

Preparation

Palladium(II) oxide is prepared by heating palladium sponge in oxygen at 350°C. The oxide is obtained as a black powder. The oxide also may be prepared specially for catalytic use by heating a mixture of palladium chloride and potassium nitrate at 600°C and then leaching out water-soluble residue. A hydrated form of the oxide, which is acid soluble can be prepared by precipitation from solution, for example, by hydrolysis of palladium nitrate. The brown hydrated oxide converts to black anhydrous oxide on heating. Its solubility in acids decreases with lowering of water content.

Flammability and Explosibility

Not classified

Palladium(II) oxide Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Palladium(II) oxide manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Palladium(II) oxide 1314-08-5
Price
US $99.00-35.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-08
Baoji Guokang Bio-Technology Co., Ltd.
Product
Palladium(II) oxide 1314-08-5
Price
US $1.00/g
Min. Order
1g
Purity
87.0%
Supply Ability
1kg
Release date
2023-10-31
Shanghai Daken Advanced Materials Co.,Ltd
Product
Palladium monoxide 1314-08-5
Price
US $0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100KG /month
Release date
2021-11-05

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