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1-Iodo-3,5-dimethylbenzene

Product Name
1-Iodo-3,5-dimethylbenzene
CAS No.
22445-41-6
Chemical Name
1-Iodo-3,5-dimethylbenzene
Synonyms
5-IODO-M-XYLENE;5-Iodo-m-xylene,99%;1-Iodo-3,5-dimethyL;3,5-DIMETHYLIODOBENZENE;3,5-Dinethyliodobenzene;3,5-dimethylphenyl iodide;5-Iodo-M-xylene, 99% 25ML;3,5-diMethyl-1-iodobenzene;1-IODO-3,5-DIMETHYLBENZENE;1,3-DIMETHYL-5-IODOBENZENE
CBNumber
CB2135658
Molecular Formula
C8H9I
Formula Weight
232.06
MOL File
22445-41-6.mol
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1-Iodo-3,5-dimethylbenzene Property

Melting point:
-2.9°C (estimate)
Boiling point:
92-94 °C3 mm Hg(lit.)
Density 
1.608 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.594(lit.)
Flash point:
>230 °F
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Sparingly soluble (0.014 g/L) (25°C), Calc.
form 
Liquid
Specific Gravity
1.608
color 
Clear light yellow
Sensitive 
Light Sensitive
BRN 
2039353
InChIKey
ZLMKEENUYIUKKC-UHFFFAOYSA-N
CAS DataBase Reference
22445-41-6(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1-iodo-3,5-dimethyl-(22445-41-6)
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Safety

Hazard Codes 
Xi,C
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
3
Hazard Note 
Irritant
HS Code 
29039990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
392510
Product name
1-Iodo-3,5-dimethylbenzene
Purity
99%
Packaging
5ml
Price
$23.96
Updated
2024/03/01
Sigma-Aldrich
Product number
392510
Product name
1-Iodo-3,5-dimethylbenzene
Purity
99%
Packaging
25ml
Price
$77.4
Updated
2024/03/01
TCI Chemical
Product number
I0548
Product name
5-Iodo-m-xylene
Packaging
5G
Price
$60
Updated
2024/03/01
TCI Chemical
Product number
I0548
Product name
5-Iodo-m-xylene
Packaging
25G
Price
$180
Updated
2024/03/01
Alfa Aesar
Product number
A18413
Product name
5-Iodo-m-xylene, 97%
Packaging
10g
Price
$46.65
Updated
2024/03/01
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1-Iodo-3,5-dimethylbenzene Chemical Properties,Usage,Production

Chemical Properties

clear light yellow liquid

Uses

suzuki reaction

Uses

1-Iodo-3,5-dimethylbenzene (5-iodo-m-xylene) is suitable for use in the synthesis of N-(3,5-xylyl)-N-ethyl aniline, an aryl amine, It is also used in the following studies; α-Arylation of ketones, Copper-catalyzed N-arylation of imidazoles, Cyanation of 5-iodo-m-xylene to form 3,5-dimethylbenzonitrile, synthesis of 1,3-Dimethyl-5-phenoxybenzene by nano-CuFe2O4 catalyzed C-O cross-coupling with phenol, CuBr-catalyzed amination of 1-iodo-3,5-dimethylbenzene to form N-Allyl-3,5-dimethylbenzenamine, copper-catalyzed C-S bond-formation between 5-iodo-m-xylene and thiophenol. It is also employed as a starting material in the synthesis of biphenyl-3,3?,5,5?-tetracarboxylic acid, radical bromination of 5-iodo-m-xylene by N-bromosuccinimide to form 1,3-bis(bromomethyl)-5-iodobenzene.

Uses

1-Iodo-3,5-dimethylbenzene (5-iodo-m-xylene) is suitable for use in the synthesis of N-(3,5-xylyl)-N-ethylaniline, an arylamine.
It may be used in the following studies:

  • α-Arylation of ketones.
  • Copper-catalyzed N-arylation of imidazoles.
  • Cyanation of 5-iodo-m-xylene to form 3,5-dimethylbenzonitrile.
  • Synthesis of 1,3-Dimethyl-5-phenoxybenzene by nano-CuFe2O4 catalyzed C-O cross-coupling with phenol.
  • CuBr-catalyzed amination of 1-iodo-3,5-dimethylbenzene to form N-Allyl-3,5-dimethylbenzenamine.
  • Copper-catalyzed C-S bond-formation between 5-iodo-m-xylene and thiophenol.
  • As a starting material in the synthesis of biphenyl-3,3′,5,5′-tetracarboxylic acid.
  • Radical bromination of 5-iodo-m-xylene by N-bromosuccinimide to form 1,3-bis(bromomethyl)-5-iodobenzene.

General Description

1-Iodo-3,5-dimethylbenzene (5-Iodo-m-xylene) is an aryl halide. It can be obtained from 5-bromo-m-xylene, via copper-catalyzed halogen exchange reaction, in the presence of NaI or KI in n-BuOH or DMF (solvents). It undergoes reaction with phenol in the presence of CuFe2O4 nano powder as a recyclable catalyst to afford 1,3-dimethyl-5-phenoxybenzene.

1-Iodo-3,5-dimethylbenzene Preparation Products And Raw materials

Raw materials

Preparation Products

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1-Iodo-3,5-dimethylbenzene Suppliers

Americas 1 Belgium 1 China 197 Europe 1 Germany 2 India 5 Japan 3 Switzerland 1 The Netherlands 1 United Kingdom 9 United States 17 Global 238
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
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76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
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62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
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TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
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Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
Advantage
56
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18207
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66
Shanghai Sinch Parmaceuticals Tech. Co. Ltd.
Tel
+86-21-54098501
Fax
+86-21-54096319
Email
sales@sinch.com.cn
Country
China
ProdList
11598
Advantage
64
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9513
Advantage
66
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11655
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View Lastest Price from 1-Iodo-3,5-dimethylbenzene manufacturers

Speranza Chemical Co., Ltd.
Product
1-iodo-3,5-dimethylbenzene 22445-41-6
Price
US $460.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
300MT/year
Release date
2019-12-24
Hebei Weibang Biotechnology Co., Ltd
Product
1-Iodo-3,5-dimethylbenzene 22445-41-6
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-12-02
Shaanxi Dideu Medichem Co. Ltd
Product
1-Iodo-3,5-dimethylbenzene 22445-41-6
Price
US $0.10/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
1000 tons
Release date
2020-01-06

22445-41-6, 1-Iodo-3,5-dimethylbenzeneRelated Search:

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  • 1-Iodo-3,5-dimethylbenzene ISO 9001：2015 REACH
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