ChemicalBook > CAS DataBase List > Ethyl (3-fluorobenzoyl)acetate

Ethyl (3-fluorobenzoyl)acetate

Product Name
Ethyl (3-fluorobenzoyl)acetate
CAS No.
33166-77-7
Chemical Name
Ethyl (3-fluorobenzoyl)acetate
Synonyms
Ethyl m-fluorobenzoyl acetate;Ethyl 2-3-fluorobenzoylacetate;ETHYL (3-FLUOROBENZOYL)ACETATE;Ethyl 3-fluoro-β-oxobenzenepropanoate;(m-Fluorobenzoyl)acetic acid ethyl ester;ETHYL 3-(3-FLUOROPHENYL)-3-OXOPROPANOATE;3-(3-Fluorophenyl)-3-oxopropanoic acid ethyl ester;Benzenepropanoic acid, 3-fluoro-β-oxo-, ethyl ester;Benzenepropanoic acid, 3-fluoro-β-oxo-, ethyl ester;3-（3-Fluoro-phenyl）-3-oxo-propionic acid ethyl bster
CBNumber
CB2148920
Molecular Formula
C11H11FO3
Formula Weight
210.2
MOL File
33166-77-7.mol
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Ethyl (3-fluorobenzoyl)acetate Property

Boiling point:
262-263 °C(lit.)
Density 
1.166 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.5172(lit.)
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
form 
Liquid
pka
10.10±0.46(Predicted)
color 
Colorless to orange
CAS DataBase Reference
33166-77-7(CAS DataBase Reference)
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Safety

WGK Germany 
3
TSCA 
Yes
HS Code 
2916399090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
559237
Product name
Ethyl (3-fluorobenzoyl)acetate
Packaging
1g
Price
$96.1
Updated
2023/06/20
Sigma-Aldrich
Product number
559237
Product name
Ethyl (3-fluorobenzoyl)acetate
Packaging
5g
Price
$230
Updated
2023/01/07
Alfa Aesar
Product number
H61315
Product name
Ethyl (3-fluorobenzoyl)acetate, 98%
Packaging
1g
Price
$80.65
Updated
2024/03/01
Alfa Aesar
Product number
H61315
Product name
Ethyl (3-fluorobenzoyl)acetate, 98%
Packaging
5g
Price
$274.65
Updated
2024/03/01
Alfa Aesar
Product number
H61315
Product name
Ethyl (3-fluorobenzoyl)acetate, 98%
Packaging
250mg
Price
$26.65
Updated
2024/03/01
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Ethyl (3-fluorobenzoyl)acetate Chemical Properties,Usage,Production

Uses

Reactant for:

  • Preparation of biologically active molecules

Synthesis

To a stirring suspension of NaH and CO(OEt)2 in toluene was added dropwise a solution of substituted acetophenone in toluene under reflux. The mixture was allowed to reflux and was stirred for 20 min after the addition was complete. When cooled to room temperature, the mixture was acidified with glacial HOAc. After ice-cold water was added, the mixture was extracted with toluene. The extract was then dried over anhydrous MgS04. After the toluene was evaporated in vacuo to give the corresponding substituted Ethyl (3-fluorobenzoyl)acetate.

Ethyl (3-fluorobenzoyl)acetate Preparation Products And Raw materials

Raw materials

Preparation Products

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Ethyl (3-fluorobenzoyl)acetate Suppliers

Canada 1 China 116 Germany 2 India 2 Switzerland 1 Ukraine 1 United Kingdom 4 United States 17 Global 144
UkrOrgSynthesis Ltd.
Tel
--
Fax
--
Email
y.barysheva@ukrorgsynth.com
Country
Ukraine
ProdList
6230
Advantage
38
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View Lastest Price from Ethyl (3-fluorobenzoyl)acetate manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
3-(3-FLUORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER 33166-77-7
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2023-02-08
Hebei Mojin Biotechnology Co., Ltd
Product
3-(3-FLUORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER 33166-77-7
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-07-28
Career Henan Chemical Co
Product
3-(3-FLUORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER 33166-77-7
Price
US $1.00/g
Min. Order
100EA
Purity
98%min
Supply Ability
G/KG/T
Release date
2019-12-23

33166-77-7, Ethyl (3-fluorobenzoyl)acetateRelated Search:

Ethyl 1-ethyl-6,7,8-trifluoro-1,4-dihydro-4-oxoquinoline-3-carboxylate 3-(4-FLUORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER ETHYL 1,4-DIHYDRO-8-FLUORO-4-OXOQUINOLINE-3-CARBOXYLATE 3-(3,4-DIFLUOROPHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER Ethyl 2,4,5-trifluorobenzoylacetate Ethyl 2,3,4,5-tetrafluorobenzoyl acetate 3-(2,4-DICHLORO-5-FLUORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER Ethyl (pentafluorobenzoyl)acetate 3-(2-FLUORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER 5,8-DIFLUORO-4-OXO-1,4-DIHYDRO-QUINOLINE-3-CARBOXYLIC ACID ETHYL ESTER 2-(2,4-DICHLORO-5-FLUORO-BENZOYL)-MALONIC ACID DIETHYL ESTER Ethyl 6,7,8-trifluoro-4-oxo-1,4-dihydroquinoline-3-carboxylate (Z)-3-CYCLOPROPYLAMINO-2-(2,4-DICHLORO-5-FLUORO-BENZOYL)-ACRYLIC ACID ETHYL ESTER 7-CHLORO-1-CYCLOPROPYL-6-FLUORO-4-OXO-1,4-DIHYDRO-QUINOLINE-3-CARBOXYLIC ACID ETHYL ESTER 2-CYANO-3-(2-FLUORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER AKOS 90576 5,6,7,8-TETRAFLUORO-2-METHYL-4-OXO-4H-CHROMENE-3-CARBOXYLIC ACID ETHYL ESTER AKOS 92524

  • 3-(3-FLUORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER
  • ETHYL 3-(3-FLUOROPHENYL)-3-OXOPROPANOATE
  • ETHYL (3-FLUOROBENZOYL)ACETATE
  • (m-Fluorobenzoyl)acetic acid ethyl ester
  • 3-(3-Fluorophenyl)-3-oxopropanoic acid ethyl ester
  • Ethyl 2-3-fluorobenzoylacetate
  • Ethyl 3-fluoro-β-oxobenzenepropanoate
  • Ethyl m-fluorobenzoyl acetate
  • Benzenepropanoic acid, 3-fluoro-β-oxo-, ethyl ester
  • 3-（3-Fluoro-phenyl）-3-oxo-propionic acid ethyl bster
  • Benzenepropanoic acid, 3-fluoro-β-oxo-, ethyl ester
  • 33166-77-7
  • FC6H4COCH2CO2C2H5
  • Esters
  • Organic Building Blocks
  • C10 to C11
  • Carbonyl Compounds
  • Building Blocks
  • C10 to C11
  • Carbonyl Compounds
  • Esters