Ethyl ziram Property

Melting point:

178-181 °C (lit.)

Boiling point:

330.6°C (estimate)

Density 

1,48 g/cm³

vapor pressure 

0.007Pa at 25℃

Flash point:

204°(400°F)

storage temp. 

under inert gas (nitrogen or Argon) at 2-8°C

solubility 

DMSO (Sparingly), Methanol (Slightly, Heated, Sonicated)

form 

solid

Specific Gravity

1.48

color 

White

Water Solubility 

Insoluble in water. Soluble in benzene carbon disulfide and organic liquids.

Hydrolytic Sensitivity

4: no reaction with water under neutral conditions

InChIKey

RKQOSDAEEGPRER-UHFFFAOYSA-L

LogP

3.11

CAS DataBase Reference

14324-55-1(CAS DataBase Reference)

NIST Chemistry Reference

Bis(diethyldithiocarbamate)zinc complex(14324-55-1)

EPA Substance Registry System

Ethyl ziram (14324-55-1)

Safety

Hazard Codes 

Xn,N

Risk Statements 

22-36/37/38-43-50/53

Safety Statements 

24-37-60-61

RIDADR 

UN 3077 9/PG 3

WGK Germany 

3

RTECS 

ZH0350000

TSCA 

Yes

HazardClass 

6.1

PackingGroup 

III

HS Code 

29302000

Hazardous Substances Data

14324-55-1(Hazardous Substances Data)

Toxicity

LD50 orl-rat: 3340 mg/kg 28ZPAK -,11,72

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H335May cause respiratory irritation

H373May cause damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P314Get medical advice/attention if you feel unwell.

Ethyl ziram Chemical Properties,Usage,Production

Chemical Properties

White powder. Soluble in carbon disulfide, benzene, and chloroform; insoluble in water.

Uses

Rubber vulcanization accelerator, especially for latex foam; heat stabilizer for polyethylene.

Uses

Diethyldithiocarbamate zinc is a rubber component used as a vulcanization accelerator. It can be responsible for rubber dermatitis in healthcare personnel. It was contained in the "carba-mix".

Uses

Zinc diethyldithiocarbamate is a chelating ligand. It is used as a common accelerator to latex. A fast curing primary or secondary effective ultra-accelerator for natural and synthetic latex compounds.

Definition

ChEBI: Zinc diethyldithiocarbamate is a dithiocarbamate salt that is the zinc salt of diethyldithiocarbamic acid. It is an accelerator and activator for natural rubber. It has a role as an antifungal agrochemical. It is a dithiocarbamate salt and a zinc molecular entity. It contains a diethyldithiocarbamate and a zinc(2+). It is functionally related to a diethyldithiocarbamic acid.

Hazard

Strong irritant to eyes and mucous membranes.

Flammability and Explosibility

Not classified

Contact allergens

Diethyldithiocarbamate zinc is a rubber component used as a vulcanization accelerator. Oxidation of this carbamate leads to tetraethylthiuram disulfide. It can be responsible for rubber dermatitis in health personnel. It was contained in “carba-mix.”

Safety Profile

Poison by intraperitoneal route.Moderately toxic by ingestion and subcutaneous routes.Severe irritant to eyes, nose, and throat. Questionablecarcinogen with experimental carcinogenic andtumorigenic data. Mutation data reported. When heated todecompos

Purification Methods

Crystallise this herbicide several times from hot toluene or from hot CHCl3 by addition of EtOH. It also crystallises from xylene, m 180o. [Beilstein 4 II 613.] TOXIC.