METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE
- Product Name
- METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE
- CAS No.
- 185629-31-6
- Chemical Name
- METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE
- Synonyms
- METHYL 3-FLUORO-4-NITROBENZOATE;Methyl3-fluoro-4-nitrobenzoate98%;Methyl 3-fluoro-4-nitrobenzoate 98%;2-Fluoro-4-(methoxycarbonyl)nitrobenzene;METHYL 3-FLUORO-4-NITROBENZENECARBOXYLAT;METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE;3-Fluoro-4-nitrobenzoic acid methyl ester;Benzoic acid, 3-fluoro-4-nitro-, methyl ester;METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE ISO 9001：2015 REACH
- CBNumber
- CB2186968
- Molecular Formula
- C8H6FNO4
- Formula Weight
- 199.14
- MOL File
- 185629-31-6.mol
METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE Property
- Melting point:
- 59-61°
- Boiling point:
- 314.6±32.0 °C(Predicted)
- Density
- 1.388±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- form
- Solid
- Appearance
- White to off-white Solid
- InChI
- InChI=1S/C8H6FNO4/c1-14-8(11)5-2-3-7(10(12)13)6(9)4-5/h2-4H,1H3
- InChIKey
- FKMZNQQOPCCUTD-UHFFFAOYSA-N
- SMILES
- C(OC)(=O)C1=CC=C([N+]([O-])=O)C(F)=C1
- CAS DataBase Reference
- 185629-31-6(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- M224148
- Product name
- Methyl3-Fluoro-4-nitrobenzoate
- Packaging
- 1g
- Price
- $45
- Updated
- 2021/12/16
- Product number
- M224148
- Product name
- Methyl3-Fluoro-4-nitrobenzoate
- Packaging
- 10g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- PC7249
- Product name
- Methyl3-fluoro-4-nitrobenzoate
- Purity
- 98%
- Packaging
- 1g
- Price
- $10
- Updated
- 2021/12/16
- Product number
- W4013
- Product name
- Methyl3-fluoro-4-nitrobenzoate
- Packaging
- 1g
- Price
- $14
- Updated
- 2021/12/16
- Product number
- PC7249
- Product name
- Methyl3-fluoro-4-nitrobenzoate
- Purity
- 98%
- Packaging
- 5g
- Price
- $15
- Updated
- 2021/12/16
METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE Chemical Properties,Usage,Production
Chemical Properties
Light yellow powder
Uses
In chemical research, Methyl 3-fluoro-4-nitrobenzenecarboxylate can be used to explore its chemical properties and reactivity, especially in the study of fluorides and nitro compounds.
Synthesis
67-56-1
403-21-4
185629-31-6
General procedure for the synthesis of methyl 3-fluoro-4-nitrobenzoate from methanol and 3-fluoro-4-nitrobenzoic acid: 3-fluoro-4-nitrobenzoic acid (5.00 g, 27.0 mmol), methanol (40 mL), and an ether solution of 2N HCl were mixed and heated and refluxed for 16 hours. After completion of the reaction, the volatiles were evaporated under reduced pressure. The residue was diluted with ethyl acetate (150 mL), washed sequentially with saturated sodium bicarbonate solution and brine, and dried with anhydrous magnesium sulfate. The solvent was evaporated under reduced pressure to give the title compound methyl 3-fluoro-4-nitrobenzoate (5.18 g, 96% yield) as a light yellow solid.
References
[1] Bioorganic and Medicinal Chemistry, 2009, vol. 17, # 5, p. 2017 - 2029
[2] Patent: WO2005/80388, 2005, A1. Location in patent: Page/Page column 88-89
[3] Patent: WO2007/16392, 2007, A2. Location in patent: Page/Page column 47
[4] European Journal of Medicinal Chemistry, 2018, vol. 150, p. 156 - 175
[5] Bioorganic and Medicinal Chemistry Letters, 2007, vol. 17, # 4, p. 1043 - 1046
METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE manufacturers
- Product
- METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE 185629-31-6
- Price
- US $100.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-26
- Product
- Methyl 3-fluoro-4-nitrobenzenecarboxylate 185629-31-6
- Price
- US $0.00-0.00/Kg
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 100 tons
- Release date
- 2020-01-10
- Product
- METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE 185629-31-6
- Price
- US $3.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 100KG
- Release date
- 2020-01-30