ChemicalBook > CAS DataBase List > METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE

METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE

Product Name
METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE
CAS No.
185629-31-6
Chemical Name
METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE
Synonyms
METHYL 3-FLUORO-4-NITROBENZOATE;Methyl3-fluoro-4-nitrobenzoate98%;Methyl 3-fluoro-4-nitrobenzoate 98%;2-Fluoro-4-(methoxycarbonyl)nitrobenzene;METHYL 3-FLUORO-4-NITROBENZENECARBOXYLAT;METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE;3-Fluoro-4-nitrobenzoic acid methyl ester;Benzoic acid, 3-fluoro-4-nitro-, methyl ester;METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE ISO 9001：2015 REACH
CBNumber
CB2186968
Molecular Formula
C8H6FNO4
Formula Weight
199.14
MOL File
185629-31-6.mol
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METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE Property

Melting point:
59-61°
Boiling point:
314.6±32.0 °C(Predicted)
Density 
1.388±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
form 
Solid
Appearance
White to off-white Solid
InChI
InChI=1S/C8H6FNO4/c1-14-8(11)5-2-3-7(10(12)13)6(9)4-5/h2-4H,1H3
InChIKey
FKMZNQQOPCCUTD-UHFFFAOYSA-N
SMILES
C(OC)(=O)C1=CC=C([N+]([O-])=O)C(F)=C1
CAS DataBase Reference
185629-31-6(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
22
HazardClass 
IRRITANT
HS Code 
2916399090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC
Product number
M224148
Product name
Methyl3-Fluoro-4-nitrobenzoate
Packaging
1g
Price
$45
Updated
2021/12/16
TRC
Product number
M224148
Product name
Methyl3-Fluoro-4-nitrobenzoate
Packaging
10g
Price
$75
Updated
2021/12/16
Apolloscientific
Product number
PC7249
Product name
Methyl3-fluoro-4-nitrobenzoate
Purity
98%
Packaging
1g
Price
$10
Updated
2021/12/16
AK Scientific
Product number
W4013
Product name
Methyl3-fluoro-4-nitrobenzoate
Packaging
1g
Price
$14
Updated
2021/12/16
Apolloscientific
Product number
PC7249
Product name
Methyl3-fluoro-4-nitrobenzoate
Purity
98%
Packaging
5g
Price
$15
Updated
2021/12/16
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METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE Chemical Properties,Usage,Production

Chemical Properties

Light yellow powder

Uses

In chemical research, Methyl 3-fluoro-4-nitrobenzenecarboxylate can be used to explore its chemical properties and reactivity, especially in the study of fluorides and nitro compounds.

Synthesis

67-56-1

403-21-4

185629-31-6

General procedure for the synthesis of methyl 3-fluoro-4-nitrobenzoate from methanol and 3-fluoro-4-nitrobenzoic acid: 3-fluoro-4-nitrobenzoic acid (5.00 g, 27.0 mmol), methanol (40 mL), and an ether solution of 2N HCl were mixed and heated and refluxed for 16 hours. After completion of the reaction, the volatiles were evaporated under reduced pressure. The residue was diluted with ethyl acetate (150 mL), washed sequentially with saturated sodium bicarbonate solution and brine, and dried with anhydrous magnesium sulfate. The solvent was evaporated under reduced pressure to give the title compound methyl 3-fluoro-4-nitrobenzoate (5.18 g, 96% yield) as a light yellow solid.

References

[1] Bioorganic and Medicinal Chemistry, 2009, vol. 17, # 5, p. 2017 - 2029
[2] Patent: WO2005/80388, 2005, A1. Location in patent: Page/Page column 88-89
[3] Patent: WO2007/16392, 2007, A2. Location in patent: Page/Page column 47
[4] European Journal of Medicinal Chemistry, 2018, vol. 150, p. 156 - 175
[5] Bioorganic and Medicinal Chemistry Letters, 2007, vol. 17, # 4, p. 1043 - 1046

METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE manufacturers

Henan Fengda Chemical Co., Ltd
Product
METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE 185629-31-6
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-26
Shaanxi Dideu Medichem Co. Ltd
Product
Methyl 3-fluoro-4-nitrobenzenecarboxylate 185629-31-6
Price
US $0.00-0.00/Kg
Min. Order
1KG
Purity
99.0%
Supply Ability
100 tons
Release date
2020-01-10
Career Henan Chemical Co
Product
METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE 185629-31-6
Price
US $3.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100KG
Release date
2020-01-30

185629-31-6, METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATERelated Search:

Dimethyl carbonate methyl 2-fluoro-5-nitrobenzenecarboxylate Methyl 4-fluoro-3-nitrobenzoate METHYL 2-FLUORO-4-NITROBENZENECARBOXYLATE Methyl 4-fluoro-2-nitrobenzoate ETHYL 3-FLUORO-4-NITROBENZOATE 3-Fluoro-4-nitrobenzoic acid METHYL 2,5-DIFLUORO-4-NITROBENZENECARBOXYLATE 3-FLUORO-4-NITRO-BENZALDEHYDE TERT-BUTYL 3-FLUORO-4-NITROBENZOATE METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE

  • METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE
  • METHYL 3-FLUORO-4-NITROBENZOATE
  • Methyl 3-fluoro-4-nitrobenzoate 98%
  • Methyl3-fluoro-4-nitrobenzoate98%
  • 3-Fluoro-4-nitrobenzoic acid methyl ester
  • METHYL 3-FLUORO-4-NITROBENZENECARBOXYLAT
  • 2-Fluoro-4-(methoxycarbonyl)nitrobenzene
  • Benzoic acid, 3-fluoro-4-nitro-, methyl ester
  • METHYL 3-FLUORO-4-NITROBENZENECARBOXYLATE ISO 9001：2015 REACH
  • 185629-31-6
  • blocks
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