ChemicalBook > CAS DataBase List > 2-Mercaptobenzoxazole

2-Mercaptobenzoxazole

Product Name
2-Mercaptobenzoxazole
CAS No.
2382-96-9
Chemical Name
2-Mercaptobenzoxazole
Synonyms
Mercaptobenzoxazole;BENZO[D]OXAZOLE-2-THIOL;benzo[d]oxazole-2(3H)-thione;2-BENZOXAZOLETHIOL;2QJBBWZ;benzoxazole-2-thiol;2-benzoxazolethione;2-benzoxazolylthiol;Benzoxazolinethione;2-Mercatobenzoxazole
CBNumber
CB2188290
Molecular Formula
C7H5NOS
Formula Weight
151.19
MOL File
2382-96-9.mol
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2-Mercaptobenzoxazole Property

Melting point:
192-195 °C(lit.)
Boiling point:
360°C (rough estimate)
Density 
1.2170 (rough estimate)
refractive index 
1.5500 (estimate)
storage temp. 
Sealed in dry,Room Temperature
pka
11.03±0.20(Predicted)
form 
Crystalline Powder
color 
Beige
PH
5 (5g/l, H2O, 20℃)
Water Solubility 
SLIGHTLY SOLUBLE
BRN 
119483
InChIKey
FLFWJIBUZQARMD-UHFFFAOYSA-N
CAS DataBase Reference
2382-96-9(CAS DataBase Reference)
NIST Chemistry Reference
2(3H)-Benzoxazolethione(2382-96-9)
EPA Substance Registry System
2-Mercaptobenzoxazole (2382-96-9)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
22-24/25-25-24-36-26
WGK Germany 
3
RTECS 
DM4882500
F 
13
TSCA 
Yes
HS Code 
29349990
Toxicity
mouse,LD50,intravenous,180mg/kg (180mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#04482,
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
M3507
Product name
2-Mercaptobenzoxazole
Purity
95%
Packaging
10g
Price
$33.4
Updated
2024/03/01
TCI Chemical
Product number
B0096
Product name
2-Mercaptobenzoxazole
Purity
>98.0%(GC)(T)
Packaging
25g
Price
$84
Updated
2024/03/01
TCI Chemical
Product number
B0096
Product name
2-Mercaptobenzoxazole
Purity
>98.0%(GC)(T)
Packaging
500g
Price
$694
Updated
2024/03/01
Alfa Aesar
Product number
A12346
Product name
2-Mercaptobenzoxazole, 98+%
Packaging
25g
Price
$40.65
Updated
2024/03/01
Alfa Aesar
Product number
A12346
Product name
2-Mercaptobenzoxazole, 98+%
Packaging
100g
Price
$115.65
Updated
2024/03/01
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2-Mercaptobenzoxazole Chemical Properties,Usage,Production

Chemical Properties

beige crystalline powder

Uses

2-Mercaptobenzoxazole is used in the surface treatment of materials. It is utilized for protection of metals from corrosion.

Preparation

2-Mercaptobenzoxazole has already been described in 1876 by Dunner (Ber. 9, (1876) page 465). 2-Mercaptobenzoxazole and its derivatives are prepared by processes which are based in principle on the reaction between o-aminophenol and alkali metal alkylxanthates. The alkali metal alkylxanthate here can either be employed as such, or it can be produced in the reaction mixture itself from an alkali, a lower alkanol and carbon disulphide.
https://patents.google.com/patent/US4677209A/en

Application

2-Mercaptobenzoxazole is a widely used organic scaffold in medicinal chemistry.
2-Mercaptobenzoxazole and their derivatives are known to posses several biological activities such as antibacterial, antifungal, antiinflammatory, insecticidal and herbicidal. 4-0xo-thiazolidines have also played an important activities as analgesic, anti-HIV, antitubercular, anthelmentic, dye-stuffs, fluorescent and as a photosensitizer. The incorporation of 4-oxothiazolidine and their 5-arylidene moieties in 2-mercaptobenzoxazole frame work has been found to enhance the activity.

Definition

ChEBI: 2-mercapto-1,3-benzoxazole is a benzoxazole.

Reactions

2-Mercaptobenzoxazole with ethyl chloroacetate and anhydrous K2C03 in the presence of dry acetone was refluxed on water bath to give ethyl-2-(mercaptobenzoxazolo)acetate.

2-Mercaptobenzoxazole Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 2-Mercaptobenzoxazole manufacturers

Hebei Guanlang Biotechnology Co., Ltd.
Product
2-Mercaptobenzoxazole 2382-96-9
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
5tons
Release date
2021-11-15
Ouhuang Engineering Materials (Hubei) Co., Ltd
Product
2-Benzoxazolethione 2382-96-9
Price
US $5.00/kg
Min. Order
1kg
Purity
99.92%
Supply Ability
50000tons
Release date
2024-04-26
Shanghai UCHEM Inc.
Product
2-Mercaptobenzoxazole 2382-96-9
Price
US $119.00/kg
Min. Order
1kg
Purity
0.98
Supply Ability
100kg
Release date
2024-04-12

2382-96-9, 2-MercaptobenzoxazoleRelated Search:

ISOXAFLUTOLE Isoxazole Sulfamethoxazole Fenoxaprop-P Benzoxazole Famoxadone 2-Hydroxybenzimidazole 2-Mercaptobenzimidazole 5-CHLORO-2-MERCAPTOBENZOXAZOLE 2-Methylthio Benzoxazole 7-CHLORO-2-MERCAPTOBENZOXAZOLE 97 4,5-DIPHENYL-2-MERCAPTOBENZOXAZOLE 6-CHLORO-2-BENZOXAZOLETHIOL 99%,6-CHLORO-2-MERCAPTOBENZOXAZOLE,6-CHLORO-2-BENZOXAZOLETHIOL 6-METHYL-1,3-BENZOXAZOLE-2-THIOL 2-MERCAPTO-5-PHENYLBENZOXAZOLE 6-NITRO-2-BENZOXAZOLETHIOL,6-Nitro-2-benzoxazolethiol 2-Benzoxazolethiol 2-Mercaptobenzoxazole ETHYL 2-[(5-CHLORO-1,3-BENZOXAZOL-2-YL)SULFANYL]ACETATE

  • benzoxazole-2-thiol
  • 2-Mercatobenzoxazole
  • 2-MERCAPTOBENZOXAZOLE 95%
  • 2-MERCAPTOBENZOXAZOLE, 98+%
  • 2-Mercaptobenzoxazole,>97%
  • BENZO[D]OXAZOLE-2-THIOL
  • BENZOXAZOLE-2-THIONE
  • BENZOOXAZOLE-2-THIOL
  • 2,3-Dihydrobenzoxazole-2-thione
  • Benzoxazole-2(3H)-thione
  • 2-Mercaptobenzoxazole,99%
  • 1,3-Benzoxazole-2-thiol, 2-Sulphanyl-1,3-benzoxazole, 2-Mercapto-1,3-benzoxazole
  • 2-Thio-1,3-benzoxazole
  • 2-Mercaptobenzoxazole, 99% 25GR
  • Mercaptobenzoxazole
  • benzo[d]oxazole-2(3H)-thione
  • 2 - Mercapto benzene and pbo
  • 1,3-Benzoxazole-2(3H)-thione
  • 2(3H)-Benzoxazolethione
  • 2-benzoxazolethione
  • 2-Benzoxazolinethione
  • 2-benzoxazolylthiol
  • 2-Mercapto-1,3-benzoxazole
  • 1,3-BENZOXAZOLE-2-THIOL
  • Benzoxazole, 2-mercapto-
  • Benzoxazolinethione
  • 2-BENZOXAZOLETHIOL
  • 2-MERCAPTOBENZOXAZOLE
  • 3H-1,3-benzoxazole-2-thione
  • 2-Mercaptobenzoxazole &gt
  • 2QJBBWZ
  • 2382-96-9
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