METHYL 4-BROMO-3-METHOXYBENZOATE

Product Name: METHYL 4-BROMO-3-METHOXYBENZOATE
CAS No.: 17100-63-9
Chemical Name: METHYL 4-BROMO-3-METHOXYBENZOATE
Synonyms: Methyl 4-broMo-2-hydroxbenzoate;METHYL 4-BROMO-3-METHOXYBENZOATE;2-Bromo-5-(methoxycarbonyl)anisole;4-BROMO-3-METHOXYBENZOIC ACID METHYL ESTER;3-methoxy-4-bromobenzoic acid methyl ester;Benzoic acid,4-broMo-3-Methoxy-, Methyl ester;2-Bromo-5-(methoxycarbonyl)anisole, Methyl 4-bromo-m-anisate
CBNumber: CB2197201
Molecular Formula: C9H9BrO3
Formula Weight: 245.07
MOL File: 17100-63-9.mol

More

Less

METHYL 4-BROMO-3-METHOXYBENZOATE Property

Melting point:: 58-61
Boiling point:: 172-173 °C
Density: 1.462±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
form: powder
color: Lemony cream
InChI: InChI=1S/C9H9BrO3/c1-12-8-5-6(9(11)13-2)3-4-7(8)10/h3-5H,1-2H3
InChIKey: XLKDKHRGIJWOSN-UHFFFAOYSA-N
SMILES: C(OC)(=O)C1=CC=C(Br)C(OC)=C1

More

Less

Safety

Hazard Codes: Xi
Hazard Note: Irritant/Keep Cold
HS Code: 2918999090

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

TRC

Product number: M296538
Product name: Methyl4-Bromo-3-methoxybenzoate
Packaging: 100mg
Price: $75
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2623-9-X9
Product name: Methyl 4-bromo-3-methoxybenzoate
Purity: 98%
Packaging: 5G
Price: $88
Updated: 2021/12/16

Apolloscientific

Product number: OR9540
Product name: Methyl4-bromo-3-methoxybenzoate
Purity: 98%
Packaging: 1g
Price: $15
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2623-9-X9
Product name: Methyl 4-bromo-3-methoxybenzoate
Purity: 98%
Packaging: 1g
Price: $26
Updated: 2021/12/16

Apolloscientific

Product number: OR9540
Product name: Methyl4-bromo-3-methoxybenzoate
Purity: 98%
Packaging: 25g
Price: $179
Updated: 2021/12/16

More

Less

METHYL 4-BROMO-3-METHOXYBENZOATE Chemical Properties,Usage,Production

Synthesis Reference(s)

Tetrahedron Letters, 10, p. 1623, 1969 DOI: 10.1017/S0009838800024678

Synthesis

106291-80-9

77-78-1

17100-63-9

Step B. Synthesis of methyl 4-bromo-3-methoxybenzoate Methyl 4-bromo-3-hydroxybenzoate (27 mmol), potassium carbonate (33 mmol) and dimethyl sulfate (32 mmol) obtained from Step A were dissolved in acetone (40 mL) under nitrogen protection. The reaction mixture was heated to reflux temperature and stirred for 3 hours. After completion of the reaction, the mixture was cooled and the reaction was quenched by slowly adding 5 mL of water. Subsequently, the acetone was removed by rotary evaporator and diluted by adding 30 mL of water. The product in the aqueous phase was extracted with dichloromethane (3 × 20 mL). The organic phases were combined, dried with anhydrous magnesium sulfate, filtered and concentrated under reduced pressure to afford the title compound methyl 4-bromo-3-methoxybenzoate (6.5 g, 99% yield) as a white crystalline solid.

References

[1] Patent: US2006/199806, 2006, A1. Location in patent: Page/Page column 23
[2] Patent: US2006/287522, 2006, A1. Location in patent: Page/Page column 24
[3] Beilstein Journal of Organic Chemistry, 2016, vol. 12, p. 2267 - 2273
[4] Yakugaku Zasshi, 1930, vol. 50, p. 224,227; dtsch. Ref. S. 26
[5] Chem.Abstr., 1930, p. 3513

METHYL 4-BROMO-3-METHOXYBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

METHYL 4-BROMO-3-METHOXYBENZOATE Suppliers

China 134 India 4 United Kingdom 1 United States 9 Global 148

Shanghai Harvest Chemical Industrial Co., Ltd.

Tel: 021-31038972,31038973 17321035817
Fax: +86-21-51385350
Email: sales@harvest-chem.com
Country: China
ProdList: 2816
Advantage: 64

Changzhou Anxuan Chemical, Co., Ltd.

Tel: 13912302692
Fax: 0519-88064678
Email: sales@anxuanchem.com
Country: China
ProdList: 4828
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006356688 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

ShangHai DEMO Chemical Co.,Ltd

Tel: 400-021-7337 2355568890
Fax: 0086-21-50182339
Email: sales@demochem.com
Country: China
ProdList: 2572
Advantage: 57

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Wuhan Chemwish Technology Co., Ltd

Tel: 86-027-67849912
Fax: 86-027-87531808
Email: sales@chemwish.com
Country: China
ProdList: 35896
Advantage: 56

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Country: China
ProdList: 18207
Advantage: 66

Jia Xing Isenchem Co.,Ltd

Tel: 0573-85285100 18627885956
Fax: 0573-85285100
Email: isenchem@163.com
Country: China
ProdList: 9310
Advantage: 66

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42934
Advantage: 64

More

Less

View Lastest Price from METHYL 4-BROMO-3-METHOXYBENZOATE manufacturers

Changzhou Anxuan Chemical Co., Ltd

Product: METHYL 4-BROMO-3-METHOXYBENZOATE 17100-63-9
Price: US $0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1ton
Release date: 2023-02-15

Career Henan Chemical Co

Product: METHYL 4-BROMO-3-METHOXYBENZOATE 17100-63-9
Price: US $1.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1000kg
Release date: 2019-04-09

17100-63-9, METHYL 4-BROMO-3-METHOXYBENZOATERelated Search:

Methyl 4-bromo-3-methylbenzoate METHYL 4-BROMO-3-HYDROXYBENZOATE Methyl 4-BroMo-5-chloro-2-furoate METHYL 4-BROMO-3-FLUOROBENZOATE 98 3-Methoxybenzoic acid Methyl 3-methoxybenzoate 4-Bromo-3-methoxybenzoic acid TERT-BUTYL 3-BENZYLOXY-4-BROMOBENZOATE TERT-BUTYL 4-BROMO-3-METHOXYBENZOATE 98 METHYL 3-(BENZYLOXY)-4-BROMOBENZOATE 98 METHYL 4-BROMO-3-METHOXYBENZOATE METHYL 2-BROMO-5-METHOXYBENZOATE Methyl 4-acetamido-5-bromo-2-methoxybenzoate METHYL 3-BROMO-4-METHOXYBENZOATE 98,METHYL 3-BROMO-4-METHOXYBENZOATE, PURISS, 98% METHYL 4-BROMO-2-METHOXYBENZOATE, PURISS,METHYL 4-BROMO-2-METHOXYBENZOATE 98 TERT-BUTYL 4-BROMO-3,5-DIMETHOXYBENZOATE 4-BROMO-3,5-DIMETHOXYBENZOIC ACID METHYL ESTER METHYL 4-BROMO-2-METHOXYBENZOATE

METHYL 4-BROMO-3-METHOXYBENZOATE

4-BROMO-3-METHOXYBENZOIC ACID METHYL ESTER

2-Bromo-5-(methoxycarbonyl)anisole

Methyl 4-broMo-2-hydroxbenzoate

2-Bromo-5-(methoxycarbonyl)anisole, Methyl 4-bromo-m-anisate

Benzoic acid,4-broMo-3-Methoxy-, Methyl ester

3-methoxy-4-bromobenzoic acid methyl ester

17100-63-9

blocks

Bromides

Carboxes