ChemicalBook > CAS DataBase List > 1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole, Tognis Reagent
1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole, Tognis Reagent
Description Reference- Product Name
- 1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole, Tognis Reagent
- CAS No.
- 887144-97-0
- Chemical Name
- 1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole, Tognis Reagent
- Synonyms
- Togni Reagent;3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole;Togni's Reagent;1-Trifluoromethyl-3,3-dimethyl-1,2-benziodoxole;togni's reagent;3,3-DMethyl-1-(trifluoroMethyl)-1,2-benziodoxole;3,3-Dimethyl-1-(trifluoromethyl)-1,2-benzodioxole;1,2-Benziodoxole,3,3-dimethyl-1-(trifluoromethyl)-;1,3-Dihydro-3,3-diMethyl-1-(trifluoroMethyl)-1,2-b;3,3-dimethyl-1-(trifluoromethyl)-1λ3,2-benziodoxole
- CBNumber
- CB22101080
- Molecular Formula
- C10H10F3IO
- Formula Weight
- 330.09
- MOL File
- 887144-97-0.mol
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1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole, Tognis Reagent Property
- Melting point:
- 75-79 °C
- storage temp.
- 2-8°C
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- form
- powder
- color
- white to off-white
- Stability:
- Moisture Sensitive
- InChIKey
- HVAPLSNCVYXFDQ-UHFFFAOYSA-N
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H228Flammable solid
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 696641
- Product name
- 3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole
- Purity
- 95%
- Packaging
- 5g
- Price
- $342
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 696641
- Product name
- 3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole
- Purity
- 95%
- Packaging
- 1g
- Price
- $442
- Updated
- 2024/03/01
TCI Chemical
- Product number
- T2624
- Product name
- 1-Trifluoromethyl-3,3-dimethyl-1,2-benziodoxole
- Purity
- >97.0%(HPLC)
- Packaging
- 1g
- Price
- $221
- Updated
- 2024/03/01
TCI Chemical
- Product number
- T2624
- Product name
- 1-Trifluoromethyl-3,3-dimethyl-1,2-benziodoxole
- Purity
- >97.0%(HPLC)
- Packaging
- 5g
- Price
- $767
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 696641
- Product name
- 3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole
- Purity
- 95%
- Packaging
- 250mg
- Price
- $71.4
- Updated
- 2024/03/01
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1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole, Tognis Reagent Chemical Properties,Usage,Production
Description
1,3-dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole is in the form of colorless, white solid. It is soluble in all common organic solvents. It is used as effective and very versatile reagent for trifluoromethylation reactions of a variety of compounds including secondary and primary aryland alkylphospines, phenols, peptides containing cysteine residues by SPPS and electrophilic S-trifluoromethylation, arenes and N-heterocycles, and electrophilic N-trifluoromethylation of arozoles.
Reference
J. Charpentier, N. Früh, A. Togni, Electrophilic Trifluoromethylation by use of hypervalent iodine reagents, Chemical Reviews, 2015, vol. 115, pp. 650-682
Chemical Properties
White to light yellow solid
Uses
Mild, electrophilic, hypervalent iodine CF3 reagent effective for the trifluoromethylation of a wide range of substrates.
Uses
Togni’s Reagent is used in trifluoromethylation reactions.
1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole, Tognis Reagent Preparation Products And Raw materials
Raw materials
Preparation Products
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1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole, Tognis Reagent Suppliers
- Tel
- 03-36680489
- Fax
- 03-3668-0520
- Sales-JP@TCIchemicals.com
- Country
- Japan
- ProdList
- 28398
- Advantage
- 80
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View Lastest Price from 1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole, Tognis Reagent manufacturers
Henan Aochuang Chemical Co.,Ltd.
- Product
- 1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole, Tognis Reagent 887144-97-0
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-10-09
Zhuozhou Wenxi import and Export Co., Ltd
- Product
- 1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole, Tognis Reagent 887144-97-0
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
- Product
- 1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole, Tognis Reagent 887144-97-0
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-09
887144-97-0, 1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole, Tognis ReagentRelated Search:
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1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole, Tognis Reagent