ChemicalBook > CAS DataBase List > 1-Bromo-2-(2-methoxyethoxy)ethane

1-Bromo-2-(2-methoxyethoxy)ethane

Product Name
1-Bromo-2-(2-methoxyethoxy)ethane
CAS No.
54149-17-6
Chemical Name
1-Bromo-2-(2-methoxyethoxy)ethane
Synonyms
DK815;mPEG2-Br;CAS_54149-17-6;Methyl-PEG2-bromide;1-bromo-3,6-dioxaheptane;MONO METHOXY PEG BROMIDE;1-BROMO-(2-METHOXYETHOXY)ETHANE;2-(2-Methoxyethoxy)ethyl bromide;1-BROMO-2-(2-METHOXYETHOXY)ETHANE;1-(2-Bromoethoxy)-2-methoxyethane
CBNumber
CB2216300
Molecular Formula
C5H11BrO2
Formula Weight
183.04
MOL File
54149-17-6.mol
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1-Bromo-2-(2-methoxyethoxy)ethane Property

Boiling point:
156 °C (lit.) 37-40 °C/0.01 mmHg (lit.)
Density 
1.3600 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.455(lit.)
Flash point:
163 °F
storage temp. 
2-8°C
form 
Liquid
color 
Clear colorless to pale yellow
Water Solubility 
Not miscible in water.
Sensitive 
Light Sensitive
BRN 
2069579
InChI
InChI=1S/C5H11BrO2/c1-7-4-5-8-3-2-6/h2-5H2,1H3
InChIKey
HUXJXNSHCKHFIL-UHFFFAOYSA-N
SMILES
C(OCCBr)COC
CAS DataBase Reference
54149-17-6(CAS DataBase Reference)
NIST Chemistry Reference
1-Bromo-2-(2-methoxyethoxy)ethane(54149-17-6)
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Safety

Risk Statements 
36/37/38
Safety Statements 
24/25
WGK Germany 
3
HS Code 
29091990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

Precautionary statements

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
639842
Product name
1-Bromo-2-(2-methoxyethoxy)ethane
Purity
95%
Packaging
10g
Price
$281
Updated
2024/03/01
Sigma-Aldrich
Product number
456195
Product name
1-Bromo-2-(2-methoxyethoxy)ethane
Purity
90%
Packaging
10g
Price
$99
Updated
2024/03/01
TCI Chemical
Product number
B4736
Product name
1-Bromo-2-(2-methoxyethoxy)ethane (stabilized with Na2CO3)
Purity
>90.0%(GC)
Packaging
5g
Price
$48
Updated
2024/03/01
TCI Chemical
Product number
B4736
Product name
1-Bromo-2-(2-methoxyethoxy)ethane (stabilized with Na2CO3)
Purity
>90.0%(GC)
Packaging
25g
Price
$185
Updated
2024/03/01
Alfa Aesar
Product number
L05406
Product name
1-Bromo-2-(2-methoxyethoxy)ethane, tech. 90%, stab. with sodium carbonate
Packaging
5g
Price
$55.65
Updated
2024/03/01
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1-Bromo-2-(2-methoxyethoxy)ethane Chemical Properties,Usage,Production

Chemical Properties

clear colorless to pale yellow liquid

Uses

1-Bromo-2-(2-methoxyethoxy)ethane is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff.

Synthesis

 General Procedure for Preparation of 1-Bromo-2-(2-methoxyethoxy)ethane: Into a 25-mL round bottomed flask equipped with magnetic stir bar, addition funnel and positive flow of nitrogen were placed 15.60 mmol of a ethyleneglycol monomethyl ether. The solution was stirred for 15 min in an ice bath before the dropwise addition of phosphorous tribromide (7.81 mmol) over a 10 min period. The solution was allowed to gradually warm and stir at room temperature (rt) for 14 hrs. The solution was then heated in a 90 °C oil bath for 1 hr, at which time the solution turned yellow. The solution was allowed to cool to rt, poured onto 30 g of ice/water mixture, and made slightly basic with addition of a 10% solution of NaHCO3 (~6 mL). Subsequent extraction with diethyl ether (Et2O) (3 x 30 mL), followed by drying over MgSO4 and concentration under reduced pressure afforded a colorless oil in sufficient purity for use in subsequent reactions.

1-Bromo-2-(2-methoxyethoxy)ethane Preparation Products And Raw materials

Raw materials

Preparation Products

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1-Bromo-2-(2-methoxyethoxy)ethane Suppliers

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View Lastest Price from 1-Bromo-2-(2-methoxyethoxy)ethane manufacturers

Hebei Xinsheng New Material Technology Co., LTD.
Product
1-Bromo-2-(2-methoxyethoxy)ethane 54149-17-6
Price
US $35.00-25.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 Ton
Release date
2023-11-10
WUHAN FORTUNA CHEMICAL CO., LTD
Product
1-Bromo-2-(2-methoxyethoxy)ethane 54149-17-6
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-21
Career Henan Chemical Co
Product
1-Bromo-2-(2-methoxyethoxy)ethane 54149-17-6
Price
US $1.00/g
Min. Order
1g
Purity
99%
Supply Ability
1000KGS
Release date
2019-12-20

54149-17-6, 1-Bromo-2-(2-methoxyethoxy)ethaneRelated Search:


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  • HALOGEN
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