ChemicalBook > CAS DataBase List > 1,4-Benzodioxane-2-carboxylic acid

1,4-Benzodioxane-2-carboxylic acid

Product Name
1,4-Benzodioxane-2-carboxylic acid
CAS No.
34385-93-8
Chemical Name
1,4-Benzodioxane-2-carboxylic acid
Synonyms
AKOS AUF2101;BUTTPARK 36\04-47;AKOS BBS-00006546;RARECHEM AL BO 1613;1,4-Benzodioxane-2-c;4-Benzodioxane-2-carboxylic acid;1,4-Benzodioxan-2-carboxilicacid;1,4-Benzodioxane-2-carboxilicacid;1,4-BENZODIOXANE-2-CARBOXYLIC ACID;1,4-Benzodioxan-2-carboxylic acid ,99%
CBNumber
CB2222956
Molecular Formula
C9H8O4
Formula Weight
180.16
MOL File
34385-93-8.mol
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1,4-Benzodioxane-2-carboxylic acid Property

Melting point:
126-130 °C(lit.)
CAS DataBase Reference
34385-93-8(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
WGK Germany 
3
HazardClass 
IRRITANT
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Hazard and Precautionary Statements (GHS)

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1,4-Benzodioxane-2-carboxylic acid Chemical Properties,Usage,Production

Uses

1,4-Benzodioxane-2-carboxylic Acid can be used in decarboxylative amination or fluorination reactions.

Purification Methods

1,4-Benzodioxane-2-carboxylic Acid has two isomeric forms, (S) and (R), which can be separated by crystalline salts. The diastereomeric N-1-phenylethylamides of (S)- and (R)-1,4-benzodioxane-2-carboxylic Acid differ significantly in melting and solubility, and can therefore be efficiently discriminated by precipitation of the less soluble diastereoisomers (>98%de), whereas chromatographic purification of the unprecipitated portion results in the soluble diastereoisomers (>99%de). Overall, recoveries were 95% for the former and 80% for the latter. Hydrolysis of the two catabolic amides gave the two acid enantiomers and the catabolic amine in quantitative yields with no change in stereoisomer purity.

1,4-Benzodioxane-2-carboxylic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 1,4-Benzodioxane-2-carboxylic acid manufacturers

Career Henan Chemical Co
Product
1,4-Benzodioxane-2-carboxylic acid 34385-93-8
Price
US $1.00/KG
Min. Order
1KG
Purity
98% HPLC
Supply Ability
10 tons
Release date
2020-02-14
Career Henan Chemical Co
Product
1,4-Benzodioxane-2-carboxylic acid 34385-93-8
Price
US $1.00/KG
Min. Order
1KG
Purity
98
Supply Ability
10t
Release date
2019-12-18

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